Abstract

A curve of growth method was used to measure the integrated intensity of the 1−1–11 rotational line of the ν2 fundamental band of H2O. All measurements were taken at a temperature of 523°K, with pressures varying between 0.2–5 atm. By neglecting vibration–rotation interaction, the total band intensity was derived for which a value of Sband = 220 ± 22 cm−2 atm−1 at NPT was found.

© 1966 Optical Society of America

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References

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  1. R. Goldstein, J. Quant. Spectry. Radiative Transfer 4, 343 (1964).
    [CrossRef]
  2. C. B. Ludwig, C. C. Ferriso, C. N. Abeyta, J. Quant. Spectry. Radiative Transfer 5, 281 (1965).
    [CrossRef]
  3. F. W. Dalby, H. H. Nielsen, J. Chem. Phys. 25, 934 (1956).
    [CrossRef]
  4. U. P. Oppenheim, Y. Ben–Aryeh, J. Opt. Soc. Am. 53, 344 (1963).
    [CrossRef]
  5. W. S. Benedict, R. C. Herman, G. E. Moore, S. Silverman, Can. J. Phys. 34, 830 (1956).
    [CrossRef]
  6. R. H. Schwendeman, V. W. Laurie, Table of Line Strengths for Rotational Transitions of Asymmetric Rotor Molecules (Pergamon Press, Inc., New York, 1958).
  7. W. S. Benedict, E. K. Plyler, J. Res. Nat. Bur. Std. 46, 246 (1951).
    [CrossRef]
  8. J. C. Breeze, C. C. Ferriso, C. B. Ludwig, W. Malkmus, J. Chem. Phys. 52, 402 (1965).
    [CrossRef]

1965 (2)

C. B. Ludwig, C. C. Ferriso, C. N. Abeyta, J. Quant. Spectry. Radiative Transfer 5, 281 (1965).
[CrossRef]

J. C. Breeze, C. C. Ferriso, C. B. Ludwig, W. Malkmus, J. Chem. Phys. 52, 402 (1965).
[CrossRef]

1964 (1)

R. Goldstein, J. Quant. Spectry. Radiative Transfer 4, 343 (1964).
[CrossRef]

1963 (1)

1956 (2)

W. S. Benedict, R. C. Herman, G. E. Moore, S. Silverman, Can. J. Phys. 34, 830 (1956).
[CrossRef]

F. W. Dalby, H. H. Nielsen, J. Chem. Phys. 25, 934 (1956).
[CrossRef]

1951 (1)

W. S. Benedict, E. K. Plyler, J. Res. Nat. Bur. Std. 46, 246 (1951).
[CrossRef]

Abeyta, C. N.

C. B. Ludwig, C. C. Ferriso, C. N. Abeyta, J. Quant. Spectry. Radiative Transfer 5, 281 (1965).
[CrossRef]

Ben–Aryeh, Y.

Benedict, W. S.

W. S. Benedict, R. C. Herman, G. E. Moore, S. Silverman, Can. J. Phys. 34, 830 (1956).
[CrossRef]

W. S. Benedict, E. K. Plyler, J. Res. Nat. Bur. Std. 46, 246 (1951).
[CrossRef]

Breeze, J. C.

J. C. Breeze, C. C. Ferriso, C. B. Ludwig, W. Malkmus, J. Chem. Phys. 52, 402 (1965).
[CrossRef]

Dalby, F. W.

F. W. Dalby, H. H. Nielsen, J. Chem. Phys. 25, 934 (1956).
[CrossRef]

Ferriso, C. C.

J. C. Breeze, C. C. Ferriso, C. B. Ludwig, W. Malkmus, J. Chem. Phys. 52, 402 (1965).
[CrossRef]

C. B. Ludwig, C. C. Ferriso, C. N. Abeyta, J. Quant. Spectry. Radiative Transfer 5, 281 (1965).
[CrossRef]

Goldstein, R.

R. Goldstein, J. Quant. Spectry. Radiative Transfer 4, 343 (1964).
[CrossRef]

Herman, R. C.

W. S. Benedict, R. C. Herman, G. E. Moore, S. Silverman, Can. J. Phys. 34, 830 (1956).
[CrossRef]

Laurie, V. W.

R. H. Schwendeman, V. W. Laurie, Table of Line Strengths for Rotational Transitions of Asymmetric Rotor Molecules (Pergamon Press, Inc., New York, 1958).

Ludwig, C. B.

C. B. Ludwig, C. C. Ferriso, C. N. Abeyta, J. Quant. Spectry. Radiative Transfer 5, 281 (1965).
[CrossRef]

J. C. Breeze, C. C. Ferriso, C. B. Ludwig, W. Malkmus, J. Chem. Phys. 52, 402 (1965).
[CrossRef]

Malkmus, W.

J. C. Breeze, C. C. Ferriso, C. B. Ludwig, W. Malkmus, J. Chem. Phys. 52, 402 (1965).
[CrossRef]

Moore, G. E.

W. S. Benedict, R. C. Herman, G. E. Moore, S. Silverman, Can. J. Phys. 34, 830 (1956).
[CrossRef]

Nielsen, H. H.

F. W. Dalby, H. H. Nielsen, J. Chem. Phys. 25, 934 (1956).
[CrossRef]

Oppenheim, U. P.

Plyler, E. K.

W. S. Benedict, E. K. Plyler, J. Res. Nat. Bur. Std. 46, 246 (1951).
[CrossRef]

Schwendeman, R. H.

R. H. Schwendeman, V. W. Laurie, Table of Line Strengths for Rotational Transitions of Asymmetric Rotor Molecules (Pergamon Press, Inc., New York, 1958).

Silverman, S.

W. S. Benedict, R. C. Herman, G. E. Moore, S. Silverman, Can. J. Phys. 34, 830 (1956).
[CrossRef]

Can. J. Phys. (1)

W. S. Benedict, R. C. Herman, G. E. Moore, S. Silverman, Can. J. Phys. 34, 830 (1956).
[CrossRef]

J. Chem. Phys. (2)

J. C. Breeze, C. C. Ferriso, C. B. Ludwig, W. Malkmus, J. Chem. Phys. 52, 402 (1965).
[CrossRef]

F. W. Dalby, H. H. Nielsen, J. Chem. Phys. 25, 934 (1956).
[CrossRef]

J. Opt. Soc. Am. (1)

J. Quant. Spectry. Radiative Transfer (2)

R. Goldstein, J. Quant. Spectry. Radiative Transfer 4, 343 (1964).
[CrossRef]

C. B. Ludwig, C. C. Ferriso, C. N. Abeyta, J. Quant. Spectry. Radiative Transfer 5, 281 (1965).
[CrossRef]

J. Res. Nat. Bur. Std. (1)

W. S. Benedict, E. K. Plyler, J. Res. Nat. Bur. Std. 46, 246 (1951).
[CrossRef]

Other (1)

R. H. Schwendeman, V. W. Laurie, Table of Line Strengths for Rotational Transitions of Asymmetric Rotor Molecules (Pergamon Press, Inc., New York, 1958).

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Equations (1)

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S ° line S ° band = ν L g exp [ - 1.439 E T ] ν ¯ Q ,

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