Abstract

A complete update of spectroscopic line parameters for the 10-μm bands of ozone is reported. The listing contains calculated positions, intensities, lower state energies, and air- and self-broadened halfwidths of more than 53,000 lines. The results have been generated using improved spectroscopic parameters obtained in a number of recent high resolution laboratory studies. A total of eighteen bands of 16O3 (sixteen hot bands plus the ν1 and ν3 fundamentals) are included along with the ν1 and ν3 fundamentals of both 16O16O18AO and 16O18AO16O. As shown by comparisons of line-by-line simulations with 0.003-cm−1 resolution balloon-borne stratospheric solar spectra, the new parameters greatly improve the accuracy of atmospheric calculations in the 10-μm region, especially for the isotopic 16O16O18AO and 16O18AO16O lines.

© 1990 Optical Society of America

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  1. A. Goldman, T. G. Kyle, D. G. Murcray, F. H. Murcray, W. J. Williams, “Long Path Atmospheric Ozone Absorption in the 9–10-μm Region Observed from a Balloon-Borne Spectrometer,” Appl. Opt. 9, 565–580 (1970).
    [CrossRef] [PubMed]
  2. E. E. Remsberg et al., “The Validation of NIMBUS 7 LIMS Measurements of Ozone,” J. Geophys. Res. 89, 5161–5178 (1984).
    [CrossRef]
  3. S. R. Drayson et al., “Spectroscopy and Transmittances for the LIMS Experiment,” J. Geophys. Res. 89, 5141–5146 (1984).
    [CrossRef]
  4. C. B. Farmer, G. C. Toon, P. W. Schaper, J.-F. Blavier, L. L. Lowes, “Stratospheric Trace Gases in the Spring 1986 Antarctic Atmosphere,” Nature London 329, 126–130 (1987).
    [CrossRef]
  5. C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, M. A. H. Smith, G. M. Stokes, “Identification of 18O-Isotopic Lines of Ozone in Infrared Ground-Based Solar Absorption Spectra,” J. Geophys. Res. 90, 10,719–10,725 (1985).
  6. A. Goldman et al., “Isotopic Abundances of Stratospheric Ozone from Balloon-Borne High Resolution Infrared Solar Spectra,” J. Geophys. Res. 94, 8467–8473 (1989).
    [CrossRef]
  7. V. Ramanathan, R. J. Cicerone, H. B. Singh, J. T. Kiehl, “Trace Gas Trends and Their Potential Role in Climate Change,” J. Geophys. Res. 90, 5547–5566 (1985).
    [CrossRef]
  8. R. E. Dickinson, R. J. Cicerone, “Future Global Warming from Atmospheric Trace Gases,” Nature London 319, 109–115 (1986).
    [CrossRef]
  9. D. P. Kratz, R. D. Cess, “Infrared Radiation Models for Atmospheric Ozone,” J. Geophys. Res. 93, 7047–7054 (1988).
    [CrossRef]
  10. L. S. Rothman et al., “The HITRAN Database: 1986 Edition,” Appl. Opt. 26, 4058–4097 (1987).
    [CrossRef] [PubMed]
  11. N. Husson et al., “The GEISA Spectroscopic Line Parameters Data Bank in 1984,” Ann. Geophys. 4, 185–190 (1986).
  12. J.-M. Flaud, C. Camy-Peyret, L. S. Rothman, “Improved Ozone Line Parameters in the 10- and 4.8-μm Regions,” Appl. Opt. 19, 655 (1980).
    [CrossRef] [PubMed]
  13. A. Barbe, C. Secroun, P. Jouve, C. Camy-Peyret, J.-M. Flaud, “High Resolution Infrared Spectrum of the ν2 + ν3 and ν1 + ν2 Bands of Ozone,” J. Mol. Spectrosc. 75, 103–110 (1979).
    [CrossRef]
  14. J.-M. Flaud, C. Camy-Peyret, A. Barbe, C. Secroun, P. Jouve, “Line Positions and Intensities for the 2ν3, ν1 + ν3, and 2ν1 Bands of Ozone,” J. Mol. Spectrosc. 80, 185–199 (1988).
    [CrossRef]
  15. J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O3: Line Positions and Intensities,” J. Mol. Spectrosc. 124, 209–217 (1987).
    [CrossRef]
  16. J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O18O16O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 334–344 (1986).
    [CrossRef]
  17. C. Camy-Peyret, J.-M. Flaud, A. Perrin, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The Hybrid-Type Bands ν1 and ν3 of 16O16O18O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 345–354 (1986).
    [CrossRef]
  18. V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, “Line Positions and Intensities for the ν1 + ν2 and ν2 + ν3 Bands of 16O3,” J. Mol. Spectrosc. 125, 174–183 (1987).
    [CrossRef]
  19. H. M. Pickett et al., “The Vibrational and Rotational Spectra of Ozone for the (0,1,0) and (0,2,0) States,” J. Mol. Spectrosc. 128, 151–171 (1988).
    [CrossRef]
  20. J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, “Line Parameters for 16O3 Bands in the 7-μm Region,” J. Mol. Spectrosc. 134, 106–112 (1989).
    [CrossRef]
  21. C. P. Rinsland, M. A. H. Smith, J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, “Line Positions and Intensities of the 2ν3, ν1 + ν3, and 2ν1 Bands of 16O3,” J. Mol. Spectrosc. 130, 204–212 (1988).
    [CrossRef]
  22. C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 2ν2 + ν3 and 2ν2 + ν1 Bands of 16O3 at 4.1 μm: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 343–352 (1990).
    [CrossRef]
  23. M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 3.6 μm Region of Ozone: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 171–181 (1989).
    [CrossRef]
  24. M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, D. C. Benner, K. B. Thakur, “Measurements of Air-Broadened and Nitrogen-Broadened Half-Widths and Shifts of Ozone Lines near 9 μm,” J. Opt. Soc. Am. B 5, 585–592 (1988).
    [CrossRef]
  25. M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, “Measurements of Self-Broadening of Ozone,” in Technical Digest, Forty-Fourth Symposium on Molecular Spectroscopy, Ohio State U., Columbus (1989), paper TE11.
  26. R. R. Gamache, L. S. Rothman, “Theoretical N2-Broadened Halfwidths of 16O3,” Appl. Opt. 24, 1651–1656 (1985).
    [CrossRef] [PubMed]
  27. A. Goldman et al., “New Spectral Features of Stratospheric Trace Gases Identified from High-Resolution Infrared Balloon-Borne and Laboratory Spectra,” J. Geophys. Res. 94, 14,945–14,955 (1989).
    [CrossRef]
  28. F. J. Murcray, J. J. Kosters, R. D. Blatherwick, J. Olson, D. G. Murcray, “High Resolution Solar Spectrometer System for Measuring Atmospheric Constituents,” Appl. Opt. 29, 1520–1525 (1990).
    [CrossRef] [PubMed]
  29. C. P. Rinsland, A. Goldman, F. J. Murcray, F. H. Murcray, D. G. Murcray, “Infrared Measurements of Atmospheric Gases Above Mauna Loa, Hawaii, in February 1987,” J. Geophys. Res. 93, 12,607–12,626 (1988).
    [CrossRef]
  30. M. R. Gunson et al., “Measurements of CH4, N2O, CO, H2O and O3 in the Middle Atmosphere by the ATMOS Experiment on Spacelab 3,” J. Geophys. Res., in press.

1990

C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 2ν2 + ν3 and 2ν2 + ν1 Bands of 16O3 at 4.1 μm: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 343–352 (1990).
[CrossRef]

F. J. Murcray, J. J. Kosters, R. D. Blatherwick, J. Olson, D. G. Murcray, “High Resolution Solar Spectrometer System for Measuring Atmospheric Constituents,” Appl. Opt. 29, 1520–1525 (1990).
[CrossRef] [PubMed]

1989

A. Goldman et al., “New Spectral Features of Stratospheric Trace Gases Identified from High-Resolution Infrared Balloon-Borne and Laboratory Spectra,” J. Geophys. Res. 94, 14,945–14,955 (1989).
[CrossRef]

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 3.6 μm Region of Ozone: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 171–181 (1989).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, “Line Parameters for 16O3 Bands in the 7-μm Region,” J. Mol. Spectrosc. 134, 106–112 (1989).
[CrossRef]

A. Goldman et al., “Isotopic Abundances of Stratospheric Ozone from Balloon-Borne High Resolution Infrared Solar Spectra,” J. Geophys. Res. 94, 8467–8473 (1989).
[CrossRef]

1988

D. P. Kratz, R. D. Cess, “Infrared Radiation Models for Atmospheric Ozone,” J. Geophys. Res. 93, 7047–7054 (1988).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, A. Barbe, C. Secroun, P. Jouve, “Line Positions and Intensities for the 2ν3, ν1 + ν3, and 2ν1 Bands of Ozone,” J. Mol. Spectrosc. 80, 185–199 (1988).
[CrossRef]

C. P. Rinsland, M. A. H. Smith, J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, “Line Positions and Intensities of the 2ν3, ν1 + ν3, and 2ν1 Bands of 16O3,” J. Mol. Spectrosc. 130, 204–212 (1988).
[CrossRef]

H. M. Pickett et al., “The Vibrational and Rotational Spectra of Ozone for the (0,1,0) and (0,2,0) States,” J. Mol. Spectrosc. 128, 151–171 (1988).
[CrossRef]

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, D. C. Benner, K. B. Thakur, “Measurements of Air-Broadened and Nitrogen-Broadened Half-Widths and Shifts of Ozone Lines near 9 μm,” J. Opt. Soc. Am. B 5, 585–592 (1988).
[CrossRef]

C. P. Rinsland, A. Goldman, F. J. Murcray, F. H. Murcray, D. G. Murcray, “Infrared Measurements of Atmospheric Gases Above Mauna Loa, Hawaii, in February 1987,” J. Geophys. Res. 93, 12,607–12,626 (1988).
[CrossRef]

1987

V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, “Line Positions and Intensities for the ν1 + ν2 and ν2 + ν3 Bands of 16O3,” J. Mol. Spectrosc. 125, 174–183 (1987).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O3: Line Positions and Intensities,” J. Mol. Spectrosc. 124, 209–217 (1987).
[CrossRef]

L. S. Rothman et al., “The HITRAN Database: 1986 Edition,” Appl. Opt. 26, 4058–4097 (1987).
[CrossRef] [PubMed]

C. B. Farmer, G. C. Toon, P. W. Schaper, J.-F. Blavier, L. L. Lowes, “Stratospheric Trace Gases in the Spring 1986 Antarctic Atmosphere,” Nature London 329, 126–130 (1987).
[CrossRef]

1986

R. E. Dickinson, R. J. Cicerone, “Future Global Warming from Atmospheric Trace Gases,” Nature London 319, 109–115 (1986).
[CrossRef]

N. Husson et al., “The GEISA Spectroscopic Line Parameters Data Bank in 1984,” Ann. Geophys. 4, 185–190 (1986).

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O18O16O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 334–344 (1986).
[CrossRef]

C. Camy-Peyret, J.-M. Flaud, A. Perrin, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The Hybrid-Type Bands ν1 and ν3 of 16O16O18O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 345–354 (1986).
[CrossRef]

1985

V. Ramanathan, R. J. Cicerone, H. B. Singh, J. T. Kiehl, “Trace Gas Trends and Their Potential Role in Climate Change,” J. Geophys. Res. 90, 5547–5566 (1985).
[CrossRef]

C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, M. A. H. Smith, G. M. Stokes, “Identification of 18O-Isotopic Lines of Ozone in Infrared Ground-Based Solar Absorption Spectra,” J. Geophys. Res. 90, 10,719–10,725 (1985).

R. R. Gamache, L. S. Rothman, “Theoretical N2-Broadened Halfwidths of 16O3,” Appl. Opt. 24, 1651–1656 (1985).
[CrossRef] [PubMed]

1984

E. E. Remsberg et al., “The Validation of NIMBUS 7 LIMS Measurements of Ozone,” J. Geophys. Res. 89, 5161–5178 (1984).
[CrossRef]

S. R. Drayson et al., “Spectroscopy and Transmittances for the LIMS Experiment,” J. Geophys. Res. 89, 5141–5146 (1984).
[CrossRef]

1980

1979

A. Barbe, C. Secroun, P. Jouve, C. Camy-Peyret, J.-M. Flaud, “High Resolution Infrared Spectrum of the ν2 + ν3 and ν1 + ν2 Bands of Ozone,” J. Mol. Spectrosc. 75, 103–110 (1979).
[CrossRef]

1970

Barbe, A.

J.-M. Flaud, C. Camy-Peyret, A. Barbe, C. Secroun, P. Jouve, “Line Positions and Intensities for the 2ν3, ν1 + ν3, and 2ν1 Bands of Ozone,” J. Mol. Spectrosc. 80, 185–199 (1988).
[CrossRef]

A. Barbe, C. Secroun, P. Jouve, C. Camy-Peyret, J.-M. Flaud, “High Resolution Infrared Spectrum of the ν2 + ν3 and ν1 + ν2 Bands of Ozone,” J. Mol. Spectrosc. 75, 103–110 (1979).
[CrossRef]

Benner, D. C.

Blatherwick, R. D.

Blavier, J.-F.

C. B. Farmer, G. C. Toon, P. W. Schaper, J.-F. Blavier, L. L. Lowes, “Stratospheric Trace Gases in the Spring 1986 Antarctic Atmosphere,” Nature London 329, 126–130 (1987).
[CrossRef]

Camy-Peyret, C.

C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 2ν2 + ν3 and 2ν2 + ν1 Bands of 16O3 at 4.1 μm: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 343–352 (1990).
[CrossRef]

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 3.6 μm Region of Ozone: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 171–181 (1989).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, “Line Parameters for 16O3 Bands in the 7-μm Region,” J. Mol. Spectrosc. 134, 106–112 (1989).
[CrossRef]

C. P. Rinsland, M. A. H. Smith, J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, “Line Positions and Intensities of the 2ν3, ν1 + ν3, and 2ν1 Bands of 16O3,” J. Mol. Spectrosc. 130, 204–212 (1988).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, A. Barbe, C. Secroun, P. Jouve, “Line Positions and Intensities for the 2ν3, ν1 + ν3, and 2ν1 Bands of Ozone,” J. Mol. Spectrosc. 80, 185–199 (1988).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O3: Line Positions and Intensities,” J. Mol. Spectrosc. 124, 209–217 (1987).
[CrossRef]

V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, “Line Positions and Intensities for the ν1 + ν2 and ν2 + ν3 Bands of 16O3,” J. Mol. Spectrosc. 125, 174–183 (1987).
[CrossRef]

C. Camy-Peyret, J.-M. Flaud, A. Perrin, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The Hybrid-Type Bands ν1 and ν3 of 16O16O18O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 345–354 (1986).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O18O16O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 334–344 (1986).
[CrossRef]

C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, M. A. H. Smith, G. M. Stokes, “Identification of 18O-Isotopic Lines of Ozone in Infrared Ground-Based Solar Absorption Spectra,” J. Geophys. Res. 90, 10,719–10,725 (1985).

J.-M. Flaud, C. Camy-Peyret, L. S. Rothman, “Improved Ozone Line Parameters in the 10- and 4.8-μm Regions,” Appl. Opt. 19, 655 (1980).
[CrossRef] [PubMed]

A. Barbe, C. Secroun, P. Jouve, C. Camy-Peyret, J.-M. Flaud, “High Resolution Infrared Spectrum of the ν2 + ν3 and ν1 + ν2 Bands of Ozone,” J. Mol. Spectrosc. 75, 103–110 (1979).
[CrossRef]

Cess, R. D.

D. P. Kratz, R. D. Cess, “Infrared Radiation Models for Atmospheric Ozone,” J. Geophys. Res. 93, 7047–7054 (1988).
[CrossRef]

Cicerone, R. J.

R. E. Dickinson, R. J. Cicerone, “Future Global Warming from Atmospheric Trace Gases,” Nature London 319, 109–115 (1986).
[CrossRef]

V. Ramanathan, R. J. Cicerone, H. B. Singh, J. T. Kiehl, “Trace Gas Trends and Their Potential Role in Climate Change,” J. Geophys. Res. 90, 5547–5566 (1985).
[CrossRef]

Dickinson, R. E.

R. E. Dickinson, R. J. Cicerone, “Future Global Warming from Atmospheric Trace Gases,” Nature London 319, 109–115 (1986).
[CrossRef]

Drayson, S. R.

S. R. Drayson et al., “Spectroscopy and Transmittances for the LIMS Experiment,” J. Geophys. Res. 89, 5141–5146 (1984).
[CrossRef]

Farmer, C. B.

C. B. Farmer, G. C. Toon, P. W. Schaper, J.-F. Blavier, L. L. Lowes, “Stratospheric Trace Gases in the Spring 1986 Antarctic Atmosphere,” Nature London 329, 126–130 (1987).
[CrossRef]

Flaud, J.-M.

C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 2ν2 + ν3 and 2ν2 + ν1 Bands of 16O3 at 4.1 μm: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 343–352 (1990).
[CrossRef]

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 3.6 μm Region of Ozone: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 171–181 (1989).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, “Line Parameters for 16O3 Bands in the 7-μm Region,” J. Mol. Spectrosc. 134, 106–112 (1989).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, A. Barbe, C. Secroun, P. Jouve, “Line Positions and Intensities for the 2ν3, ν1 + ν3, and 2ν1 Bands of Ozone,” J. Mol. Spectrosc. 80, 185–199 (1988).
[CrossRef]

C. P. Rinsland, M. A. H. Smith, J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, “Line Positions and Intensities of the 2ν3, ν1 + ν3, and 2ν1 Bands of 16O3,” J. Mol. Spectrosc. 130, 204–212 (1988).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O3: Line Positions and Intensities,” J. Mol. Spectrosc. 124, 209–217 (1987).
[CrossRef]

V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, “Line Positions and Intensities for the ν1 + ν2 and ν2 + ν3 Bands of 16O3,” J. Mol. Spectrosc. 125, 174–183 (1987).
[CrossRef]

C. Camy-Peyret, J.-M. Flaud, A. Perrin, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The Hybrid-Type Bands ν1 and ν3 of 16O16O18O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 345–354 (1986).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O18O16O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 334–344 (1986).
[CrossRef]

C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, M. A. H. Smith, G. M. Stokes, “Identification of 18O-Isotopic Lines of Ozone in Infrared Ground-Based Solar Absorption Spectra,” J. Geophys. Res. 90, 10,719–10,725 (1985).

J.-M. Flaud, C. Camy-Peyret, L. S. Rothman, “Improved Ozone Line Parameters in the 10- and 4.8-μm Regions,” Appl. Opt. 19, 655 (1980).
[CrossRef] [PubMed]

A. Barbe, C. Secroun, P. Jouve, C. Camy-Peyret, J.-M. Flaud, “High Resolution Infrared Spectrum of the ν2 + ν3 and ν1 + ν2 Bands of Ozone,” J. Mol. Spectrosc. 75, 103–110 (1979).
[CrossRef]

Gamache, R. R.

Goldman, A.

A. Goldman et al., “New Spectral Features of Stratospheric Trace Gases Identified from High-Resolution Infrared Balloon-Borne and Laboratory Spectra,” J. Geophys. Res. 94, 14,945–14,955 (1989).
[CrossRef]

A. Goldman et al., “Isotopic Abundances of Stratospheric Ozone from Balloon-Borne High Resolution Infrared Solar Spectra,” J. Geophys. Res. 94, 8467–8473 (1989).
[CrossRef]

C. P. Rinsland, A. Goldman, F. J. Murcray, F. H. Murcray, D. G. Murcray, “Infrared Measurements of Atmospheric Gases Above Mauna Loa, Hawaii, in February 1987,” J. Geophys. Res. 93, 12,607–12,626 (1988).
[CrossRef]

A. Goldman, T. G. Kyle, D. G. Murcray, F. H. Murcray, W. J. Williams, “Long Path Atmospheric Ozone Absorption in the 9–10-μm Region Observed from a Balloon-Borne Spectrometer,” Appl. Opt. 9, 565–580 (1970).
[CrossRef] [PubMed]

Gunson, M. R.

M. R. Gunson et al., “Measurements of CH4, N2O, CO, H2O and O3 in the Middle Atmosphere by the ATMOS Experiment on Spacelab 3,” J. Geophys. Res., in press.

Husson, N.

N. Husson et al., “The GEISA Spectroscopic Line Parameters Data Bank in 1984,” Ann. Geophys. 4, 185–190 (1986).

Jouve, P.

J.-M. Flaud, C. Camy-Peyret, A. Barbe, C. Secroun, P. Jouve, “Line Positions and Intensities for the 2ν3, ν1 + ν3, and 2ν1 Bands of Ozone,” J. Mol. Spectrosc. 80, 185–199 (1988).
[CrossRef]

A. Barbe, C. Secroun, P. Jouve, C. Camy-Peyret, J.-M. Flaud, “High Resolution Infrared Spectrum of the ν2 + ν3 and ν1 + ν2 Bands of Ozone,” J. Mol. Spectrosc. 75, 103–110 (1979).
[CrossRef]

Kiehl, J. T.

V. Ramanathan, R. J. Cicerone, H. B. Singh, J. T. Kiehl, “Trace Gas Trends and Their Potential Role in Climate Change,” J. Geophys. Res. 90, 5547–5566 (1985).
[CrossRef]

Kosters, J. J.

Kratz, D. P.

D. P. Kratz, R. D. Cess, “Infrared Radiation Models for Atmospheric Ozone,” J. Geophys. Res. 93, 7047–7054 (1988).
[CrossRef]

Kyle, T. G.

Lowes, L. L.

C. B. Farmer, G. C. Toon, P. W. Schaper, J.-F. Blavier, L. L. Lowes, “Stratospheric Trace Gases in the Spring 1986 Antarctic Atmosphere,” Nature London 329, 126–130 (1987).
[CrossRef]

Malathy Devi, V.

C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 2ν2 + ν3 and 2ν2 + ν1 Bands of 16O3 at 4.1 μm: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 343–352 (1990).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, “Line Parameters for 16O3 Bands in the 7-μm Region,” J. Mol. Spectrosc. 134, 106–112 (1989).
[CrossRef]

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 3.6 μm Region of Ozone: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 171–181 (1989).
[CrossRef]

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, D. C. Benner, K. B. Thakur, “Measurements of Air-Broadened and Nitrogen-Broadened Half-Widths and Shifts of Ozone Lines near 9 μm,” J. Opt. Soc. Am. B 5, 585–592 (1988).
[CrossRef]

C. P. Rinsland, M. A. H. Smith, J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, “Line Positions and Intensities of the 2ν3, ν1 + ν3, and 2ν1 Bands of 16O3,” J. Mol. Spectrosc. 130, 204–212 (1988).
[CrossRef]

V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, “Line Positions and Intensities for the ν1 + ν2 and ν2 + ν3 Bands of 16O3,” J. Mol. Spectrosc. 125, 174–183 (1987).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O3: Line Positions and Intensities,” J. Mol. Spectrosc. 124, 209–217 (1987).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O18O16O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 334–344 (1986).
[CrossRef]

C. Camy-Peyret, J.-M. Flaud, A. Perrin, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The Hybrid-Type Bands ν1 and ν3 of 16O16O18O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 345–354 (1986).
[CrossRef]

C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, M. A. H. Smith, G. M. Stokes, “Identification of 18O-Isotopic Lines of Ozone in Infrared Ground-Based Solar Absorption Spectra,” J. Geophys. Res. 90, 10,719–10,725 (1985).

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, “Measurements of Self-Broadening of Ozone,” in Technical Digest, Forty-Fourth Symposium on Molecular Spectroscopy, Ohio State U., Columbus (1989), paper TE11.

Murcray, D. G.

Murcray, F. H.

C. P. Rinsland, A. Goldman, F. J. Murcray, F. H. Murcray, D. G. Murcray, “Infrared Measurements of Atmospheric Gases Above Mauna Loa, Hawaii, in February 1987,” J. Geophys. Res. 93, 12,607–12,626 (1988).
[CrossRef]

A. Goldman, T. G. Kyle, D. G. Murcray, F. H. Murcray, W. J. Williams, “Long Path Atmospheric Ozone Absorption in the 9–10-μm Region Observed from a Balloon-Borne Spectrometer,” Appl. Opt. 9, 565–580 (1970).
[CrossRef] [PubMed]

Murcray, F. J.

F. J. Murcray, J. J. Kosters, R. D. Blatherwick, J. Olson, D. G. Murcray, “High Resolution Solar Spectrometer System for Measuring Atmospheric Constituents,” Appl. Opt. 29, 1520–1525 (1990).
[CrossRef] [PubMed]

C. P. Rinsland, A. Goldman, F. J. Murcray, F. H. Murcray, D. G. Murcray, “Infrared Measurements of Atmospheric Gases Above Mauna Loa, Hawaii, in February 1987,” J. Geophys. Res. 93, 12,607–12,626 (1988).
[CrossRef]

Olson, J.

Perrin, A.

C. Camy-Peyret, J.-M. Flaud, A. Perrin, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The Hybrid-Type Bands ν1 and ν3 of 16O16O18O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 345–354 (1986).
[CrossRef]

Pickett, H. M.

H. M. Pickett et al., “The Vibrational and Rotational Spectra of Ozone for the (0,1,0) and (0,2,0) States,” J. Mol. Spectrosc. 128, 151–171 (1988).
[CrossRef]

Ramanathan, V.

V. Ramanathan, R. J. Cicerone, H. B. Singh, J. T. Kiehl, “Trace Gas Trends and Their Potential Role in Climate Change,” J. Geophys. Res. 90, 5547–5566 (1985).
[CrossRef]

Remsberg, E. E.

E. E. Remsberg et al., “The Validation of NIMBUS 7 LIMS Measurements of Ozone,” J. Geophys. Res. 89, 5161–5178 (1984).
[CrossRef]

Rinsland, C. P.

C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 2ν2 + ν3 and 2ν2 + ν1 Bands of 16O3 at 4.1 μm: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 343–352 (1990).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, “Line Parameters for 16O3 Bands in the 7-μm Region,” J. Mol. Spectrosc. 134, 106–112 (1989).
[CrossRef]

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 3.6 μm Region of Ozone: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 171–181 (1989).
[CrossRef]

C. P. Rinsland, M. A. H. Smith, J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, “Line Positions and Intensities of the 2ν3, ν1 + ν3, and 2ν1 Bands of 16O3,” J. Mol. Spectrosc. 130, 204–212 (1988).
[CrossRef]

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, D. C. Benner, K. B. Thakur, “Measurements of Air-Broadened and Nitrogen-Broadened Half-Widths and Shifts of Ozone Lines near 9 μm,” J. Opt. Soc. Am. B 5, 585–592 (1988).
[CrossRef]

C. P. Rinsland, A. Goldman, F. J. Murcray, F. H. Murcray, D. G. Murcray, “Infrared Measurements of Atmospheric Gases Above Mauna Loa, Hawaii, in February 1987,” J. Geophys. Res. 93, 12,607–12,626 (1988).
[CrossRef]

V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, “Line Positions and Intensities for the ν1 + ν2 and ν2 + ν3 Bands of 16O3,” J. Mol. Spectrosc. 125, 174–183 (1987).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O3: Line Positions and Intensities,” J. Mol. Spectrosc. 124, 209–217 (1987).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O18O16O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 334–344 (1986).
[CrossRef]

C. Camy-Peyret, J.-M. Flaud, A. Perrin, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The Hybrid-Type Bands ν1 and ν3 of 16O16O18O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 345–354 (1986).
[CrossRef]

C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, M. A. H. Smith, G. M. Stokes, “Identification of 18O-Isotopic Lines of Ozone in Infrared Ground-Based Solar Absorption Spectra,” J. Geophys. Res. 90, 10,719–10,725 (1985).

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, “Measurements of Self-Broadening of Ozone,” in Technical Digest, Forty-Fourth Symposium on Molecular Spectroscopy, Ohio State U., Columbus (1989), paper TE11.

Rothman, L. S.

Schaper, P. W.

C. B. Farmer, G. C. Toon, P. W. Schaper, J.-F. Blavier, L. L. Lowes, “Stratospheric Trace Gases in the Spring 1986 Antarctic Atmosphere,” Nature London 329, 126–130 (1987).
[CrossRef]

Secroun, C.

J.-M. Flaud, C. Camy-Peyret, A. Barbe, C. Secroun, P. Jouve, “Line Positions and Intensities for the 2ν3, ν1 + ν3, and 2ν1 Bands of Ozone,” J. Mol. Spectrosc. 80, 185–199 (1988).
[CrossRef]

A. Barbe, C. Secroun, P. Jouve, C. Camy-Peyret, J.-M. Flaud, “High Resolution Infrared Spectrum of the ν2 + ν3 and ν1 + ν2 Bands of Ozone,” J. Mol. Spectrosc. 75, 103–110 (1979).
[CrossRef]

Singh, H. B.

V. Ramanathan, R. J. Cicerone, H. B. Singh, J. T. Kiehl, “Trace Gas Trends and Their Potential Role in Climate Change,” J. Geophys. Res. 90, 5547–5566 (1985).
[CrossRef]

Smith, M. A. H.

C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 2ν2 + ν3 and 2ν2 + ν1 Bands of 16O3 at 4.1 μm: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 343–352 (1990).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, “Line Parameters for 16O3 Bands in the 7-μm Region,” J. Mol. Spectrosc. 134, 106–112 (1989).
[CrossRef]

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 3.6 μm Region of Ozone: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 171–181 (1989).
[CrossRef]

C. P. Rinsland, M. A. H. Smith, J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, “Line Positions and Intensities of the 2ν3, ν1 + ν3, and 2ν1 Bands of 16O3,” J. Mol. Spectrosc. 130, 204–212 (1988).
[CrossRef]

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, D. C. Benner, K. B. Thakur, “Measurements of Air-Broadened and Nitrogen-Broadened Half-Widths and Shifts of Ozone Lines near 9 μm,” J. Opt. Soc. Am. B 5, 585–592 (1988).
[CrossRef]

V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, “Line Positions and Intensities for the ν1 + ν2 and ν2 + ν3 Bands of 16O3,” J. Mol. Spectrosc. 125, 174–183 (1987).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O3: Line Positions and Intensities,” J. Mol. Spectrosc. 124, 209–217 (1987).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O18O16O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 334–344 (1986).
[CrossRef]

C. Camy-Peyret, J.-M. Flaud, A. Perrin, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The Hybrid-Type Bands ν1 and ν3 of 16O16O18O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 345–354 (1986).
[CrossRef]

C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, M. A. H. Smith, G. M. Stokes, “Identification of 18O-Isotopic Lines of Ozone in Infrared Ground-Based Solar Absorption Spectra,” J. Geophys. Res. 90, 10,719–10,725 (1985).

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, “Measurements of Self-Broadening of Ozone,” in Technical Digest, Forty-Fourth Symposium on Molecular Spectroscopy, Ohio State U., Columbus (1989), paper TE11.

Stokes, G. M.

C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, M. A. H. Smith, G. M. Stokes, “Identification of 18O-Isotopic Lines of Ozone in Infrared Ground-Based Solar Absorption Spectra,” J. Geophys. Res. 90, 10,719–10,725 (1985).

Thakur, K. B.

Toon, G. C.

C. B. Farmer, G. C. Toon, P. W. Schaper, J.-F. Blavier, L. L. Lowes, “Stratospheric Trace Gases in the Spring 1986 Antarctic Atmosphere,” Nature London 329, 126–130 (1987).
[CrossRef]

Williams, W. J.

Ann. Geophys.

N. Husson et al., “The GEISA Spectroscopic Line Parameters Data Bank in 1984,” Ann. Geophys. 4, 185–190 (1986).

Appl. Opt.

J. Geophys. Res.

C. P. Rinsland, A. Goldman, F. J. Murcray, F. H. Murcray, D. G. Murcray, “Infrared Measurements of Atmospheric Gases Above Mauna Loa, Hawaii, in February 1987,” J. Geophys. Res. 93, 12,607–12,626 (1988).
[CrossRef]

A. Goldman et al., “New Spectral Features of Stratospheric Trace Gases Identified from High-Resolution Infrared Balloon-Borne and Laboratory Spectra,” J. Geophys. Res. 94, 14,945–14,955 (1989).
[CrossRef]

D. P. Kratz, R. D. Cess, “Infrared Radiation Models for Atmospheric Ozone,” J. Geophys. Res. 93, 7047–7054 (1988).
[CrossRef]

E. E. Remsberg et al., “The Validation of NIMBUS 7 LIMS Measurements of Ozone,” J. Geophys. Res. 89, 5161–5178 (1984).
[CrossRef]

S. R. Drayson et al., “Spectroscopy and Transmittances for the LIMS Experiment,” J. Geophys. Res. 89, 5141–5146 (1984).
[CrossRef]

C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, M. A. H. Smith, G. M. Stokes, “Identification of 18O-Isotopic Lines of Ozone in Infrared Ground-Based Solar Absorption Spectra,” J. Geophys. Res. 90, 10,719–10,725 (1985).

A. Goldman et al., “Isotopic Abundances of Stratospheric Ozone from Balloon-Borne High Resolution Infrared Solar Spectra,” J. Geophys. Res. 94, 8467–8473 (1989).
[CrossRef]

V. Ramanathan, R. J. Cicerone, H. B. Singh, J. T. Kiehl, “Trace Gas Trends and Their Potential Role in Climate Change,” J. Geophys. Res. 90, 5547–5566 (1985).
[CrossRef]

J. Mol. Spectrosc.

A. Barbe, C. Secroun, P. Jouve, C. Camy-Peyret, J.-M. Flaud, “High Resolution Infrared Spectrum of the ν2 + ν3 and ν1 + ν2 Bands of Ozone,” J. Mol. Spectrosc. 75, 103–110 (1979).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, A. Barbe, C. Secroun, P. Jouve, “Line Positions and Intensities for the 2ν3, ν1 + ν3, and 2ν1 Bands of Ozone,” J. Mol. Spectrosc. 80, 185–199 (1988).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O3: Line Positions and Intensities,” J. Mol. Spectrosc. 124, 209–217 (1987).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The ν1 and ν3 Bands of 16O18O16O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 334–344 (1986).
[CrossRef]

C. Camy-Peyret, J.-M. Flaud, A. Perrin, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The Hybrid-Type Bands ν1 and ν3 of 16O16O18O: Line Positions and Intensities,” J. Mol. Spectrosc. 118, 345–354 (1986).
[CrossRef]

V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, “Line Positions and Intensities for the ν1 + ν2 and ν2 + ν3 Bands of 16O3,” J. Mol. Spectrosc. 125, 174–183 (1987).
[CrossRef]

H. M. Pickett et al., “The Vibrational and Rotational Spectra of Ozone for the (0,1,0) and (0,2,0) States,” J. Mol. Spectrosc. 128, 151–171 (1988).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, “Line Parameters for 16O3 Bands in the 7-μm Region,” J. Mol. Spectrosc. 134, 106–112 (1989).
[CrossRef]

C. P. Rinsland, M. A. H. Smith, J.-M. Flaud, C. Camy-Peyret, V. Malathy Devi, “Line Positions and Intensities of the 2ν3, ν1 + ν3, and 2ν1 Bands of 16O3,” J. Mol. Spectrosc. 130, 204–212 (1988).
[CrossRef]

C. P. Rinsland, M. A. H. Smith, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 2ν2 + ν3 and 2ν2 + ν1 Bands of 16O3 at 4.1 μm: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 343–352 (1990).
[CrossRef]

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, J.-M. Flaud, C. Camy-Peyret, “The 3.6 μm Region of Ozone: Line Positions and Intensities,” J. Mol. Spectrosc. 139, 171–181 (1989).
[CrossRef]

J. Opt. Soc. Am. B

Nature London

R. E. Dickinson, R. J. Cicerone, “Future Global Warming from Atmospheric Trace Gases,” Nature London 319, 109–115 (1986).
[CrossRef]

C. B. Farmer, G. C. Toon, P. W. Schaper, J.-F. Blavier, L. L. Lowes, “Stratospheric Trace Gases in the Spring 1986 Antarctic Atmosphere,” Nature London 329, 126–130 (1987).
[CrossRef]

Other

M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, “Measurements of Self-Broadening of Ozone,” in Technical Digest, Forty-Fourth Symposium on Molecular Spectroscopy, Ohio State U., Columbus (1989), paper TE11.

M. R. Gunson et al., “Measurements of CH4, N2O, CO, H2O and O3 in the Middle Atmosphere by the ATMOS Experiment on Spacelab 3,” J. Geophys. Res., in press.

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Figures (4)

Fig. 1
Fig. 1

Comparison of a 0.003-cm−1 resolution solar occultation spectrum and a simulation of the data generated including the 1986 HITRAN ozone line parameters10 (upper panel) and a simulation of the data generated with new ozone line parameters (lower panel). In each panel, the upper curve is the line-by-line simulation which has been displaced vertically by 0.2 for clarity. The lower curve shows a solar spectrum obtained at sunset 6 June 1988 during a balloon flight from Palestine, TX conducted by the University of Denver atmospheric spectroscopy group. The spectrum (normalized to the highest intensity in the interval) was recorded with a Michelson interferometer from a float altitude of 36.85 km and at a solar astronomical zenith angle of 92.61°. The corresponding refracted tangent height is 30.27 km. Arrows and capital letters in the lower panel indicate examples of ozone spectral features produced by different vibration–rotation bands. The ozone isotopic species and vibrational bands corresponding to the marked features are A = 16O3 (002)–(100), B = 16O18AO16O (001)–(000), C = 16O3 (002)–(001), D = 16O16O18AO (001)–(000), E = 16O3 (011)–(010), F = 16O3 (101)–(100), G = 16O3 (100)–(000), H = 16O3 (001)–(000), and I = 16O3 (021)–(020). The R28 line of the 00011–10001 band of 12C16O2 at 980.9132 cm−1 (marked by a solid circle in both panels) is the only significant non-O3 absorption feature in this spectral interval.

Fig. 2
Fig. 2

Comparison of a 0.003-cm−1 resolution stratospheric solar occultation spectrum (same scan as shown in Fig. 1) and line-by-line simulations with the new ozone line parameters. The upper spectrum, which has been displaced vertically by 0.1 for clarity, shows the absorption computed for the 16O16O18AO isotopic species only. The feature near 1090.36 cm−1 is the Q-branch of the ν1 band. More than 300 lines are included in the calculations. The two lower spectra show a comparison of the measured solar spectrum (solid line) with a simulation of the absorption by all gases (open diamonds). The absorption in this region is due almost entirely to 16O3 lines and the lines of the 16O16O18AO ν1-band Q-branch.

Fig. 3
Fig. 3

Comparison of a 0.003-cm−1 resolution stratospheric solar occultation spectrum (same scan as shown in Figs. 1 and 2) and a line-by-line simulation including the new ozone line parameters. A number of features of the (200)–(001) band of 16O3 are identified.

Fig. 4
Fig. 4

Absorption line intensity (cm−1/molecule cm−2 at 296 K units) on a base 10 logarithm vs wavenumber scale for each ozone band. A plot with all the lines is presented in the same format at the bottom of the right column.

Tables (1)

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Table I Summary of O3 Bands Included in the Calculations

Equations (1)

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α L = a 0 + a 1 J + a 2 J 2 + a 3 J 3 ,

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