Abstract

Air-broadened halfwidths of eighteen transitions in the ν6 band of H2O2 have been determined at room temperature from high resolution laboratory spectra recorded with a tunable diode laser system. The measured transitions occur in the 1252–1291-cm−1 region. For these eighteen transitions, the measured halfwidths range from 0.0923 to 0.1155 cm−1 atm−1.

© 1986 Optical Society of America

Full Article  |  PDF Article

References

  • View by:
  • |
  • |
  • |

  1. C. Miller, D. L. Filkin, A. J. Owens, J. M. Steed, J. P. Jesson, “A Two-Dimensional Model of Stratospheric Chemistry and Transport,” J. Geophys. Res. 86, 12 (1981).
    [Crossref]
  2. J. A. Logan, M. J. Prather, S. C. Wofsy, M. B. McElroy, “Tropospheric Chemistry: A Global Perspective,” J. Geophys. Res. 86, 7210 (1981).
    [Crossref]
  3. D. G. Murcray, W. J. Williams, D. B. Barker, A. Goldman, C. Bradford, G. Cooke, “Measurements of Constituents of Interest in the Chemistry of the Ozone Layer Using IR Techniques,” in Proceedings, WMO Symposium on the Geophysical Aspects and Consequences of Change in the Composition of the Stratosphere, WMO No. 511, 61, Toronto (June1978).
  4. J. C. Larsen, C. P. Rinsland, A. Goldman, D. G. Murcray, F. J. Murcray, “Upper Limits for Stratospheric H2O2 and HOCl from High Resolution Balloon-Borne Infrared Solar Absorption Spectra,” Geophys. Res. Lett. 12, 663 (1985).
    [Crossref]
  5. F. P. J. Valero, D. Goorvitch, F. S. Bonomo, R. W. Boese, “Intensity of the Hydrogen Peroxide ν6(b) Band Around 1266 cm−1,” Appl. Opt. 20, 4097 (1981).
    [Crossref] [PubMed]
  6. D. Goorvitch, F. P. J. Valero, F. S. Bonomo, P. M. Silvaggio, “Band Model Analysis of the H2O2ν6(b) Band,” J. Quant. Spectrosc. Radiat. Transfer 27, 575 (1982).
    [Crossref]
  7. J. J. Hillman, W. B. Olson, A. Goldman, “High Resolution Infrared Spectrum of Hydrogen Peroxide: The ν6 Fundamental Band,” J. Mol. Spectros.117 (1986), in press.
    [Crossref]
  8. V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, D. C. Benner, “Measurements of 12CH4ν4 Band Halfwidths Using a Tunable Diode Laser System and a Fourier Transform Spectrometer,” Appl. Opt. 24, 2788 (1985).
    [Crossref] [PubMed]
  9. V. Malathy Devi, D. C. Benner, C. P. Rinsland, M. A. H. Smith, B. D. Sidney, “Tunable Diode Laser Measurements of N2-and Air-Broadened Halfwidths: Lines in the (ν4 + ν5)° Band of 12C2H2 Near 7.4 μm,” J. Mol. Spectrosc. 114, 49 (1985).
    [Crossref]
  10. J. J. Olivero, R. L. Longbothum, “Empirical Fits to the Voigt Profile,” J. Quant. Spectrosc. Radiat. Transfer 8, 1379 (1968).
  11. B. Fridovich, V. Malathy Devi, P. P. Das, “Convolution of a Doppler Line by a Gaussian Instrument Function,” J. Mol. Spectrosc. 81, 269 (1980).
    [Crossref]
  12. L. S. Rothman et al., “AFGL Atmospheric Absorption Line Parameters Compilation: 1982 Edition,” Appl. Opt. 22, 2247 (1983).
    [Crossref] [PubMed]

1985 (3)

J. C. Larsen, C. P. Rinsland, A. Goldman, D. G. Murcray, F. J. Murcray, “Upper Limits for Stratospheric H2O2 and HOCl from High Resolution Balloon-Borne Infrared Solar Absorption Spectra,” Geophys. Res. Lett. 12, 663 (1985).
[Crossref]

V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, D. C. Benner, “Measurements of 12CH4ν4 Band Halfwidths Using a Tunable Diode Laser System and a Fourier Transform Spectrometer,” Appl. Opt. 24, 2788 (1985).
[Crossref] [PubMed]

V. Malathy Devi, D. C. Benner, C. P. Rinsland, M. A. H. Smith, B. D. Sidney, “Tunable Diode Laser Measurements of N2-and Air-Broadened Halfwidths: Lines in the (ν4 + ν5)° Band of 12C2H2 Near 7.4 μm,” J. Mol. Spectrosc. 114, 49 (1985).
[Crossref]

1983 (1)

1982 (1)

D. Goorvitch, F. P. J. Valero, F. S. Bonomo, P. M. Silvaggio, “Band Model Analysis of the H2O2ν6(b) Band,” J. Quant. Spectrosc. Radiat. Transfer 27, 575 (1982).
[Crossref]

1981 (3)

F. P. J. Valero, D. Goorvitch, F. S. Bonomo, R. W. Boese, “Intensity of the Hydrogen Peroxide ν6(b) Band Around 1266 cm−1,” Appl. Opt. 20, 4097 (1981).
[Crossref] [PubMed]

C. Miller, D. L. Filkin, A. J. Owens, J. M. Steed, J. P. Jesson, “A Two-Dimensional Model of Stratospheric Chemistry and Transport,” J. Geophys. Res. 86, 12 (1981).
[Crossref]

J. A. Logan, M. J. Prather, S. C. Wofsy, M. B. McElroy, “Tropospheric Chemistry: A Global Perspective,” J. Geophys. Res. 86, 7210 (1981).
[Crossref]

1980 (1)

B. Fridovich, V. Malathy Devi, P. P. Das, “Convolution of a Doppler Line by a Gaussian Instrument Function,” J. Mol. Spectrosc. 81, 269 (1980).
[Crossref]

1968 (1)

J. J. Olivero, R. L. Longbothum, “Empirical Fits to the Voigt Profile,” J. Quant. Spectrosc. Radiat. Transfer 8, 1379 (1968).

Barker, D. B.

D. G. Murcray, W. J. Williams, D. B. Barker, A. Goldman, C. Bradford, G. Cooke, “Measurements of Constituents of Interest in the Chemistry of the Ozone Layer Using IR Techniques,” in Proceedings, WMO Symposium on the Geophysical Aspects and Consequences of Change in the Composition of the Stratosphere, WMO No. 511, 61, Toronto (June1978).

Benner, D. C.

V. Malathy Devi, D. C. Benner, C. P. Rinsland, M. A. H. Smith, B. D. Sidney, “Tunable Diode Laser Measurements of N2-and Air-Broadened Halfwidths: Lines in the (ν4 + ν5)° Band of 12C2H2 Near 7.4 μm,” J. Mol. Spectrosc. 114, 49 (1985).
[Crossref]

V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, D. C. Benner, “Measurements of 12CH4ν4 Band Halfwidths Using a Tunable Diode Laser System and a Fourier Transform Spectrometer,” Appl. Opt. 24, 2788 (1985).
[Crossref] [PubMed]

Boese, R. W.

Bonomo, F. S.

D. Goorvitch, F. P. J. Valero, F. S. Bonomo, P. M. Silvaggio, “Band Model Analysis of the H2O2ν6(b) Band,” J. Quant. Spectrosc. Radiat. Transfer 27, 575 (1982).
[Crossref]

F. P. J. Valero, D. Goorvitch, F. S. Bonomo, R. W. Boese, “Intensity of the Hydrogen Peroxide ν6(b) Band Around 1266 cm−1,” Appl. Opt. 20, 4097 (1981).
[Crossref] [PubMed]

Bradford, C.

D. G. Murcray, W. J. Williams, D. B. Barker, A. Goldman, C. Bradford, G. Cooke, “Measurements of Constituents of Interest in the Chemistry of the Ozone Layer Using IR Techniques,” in Proceedings, WMO Symposium on the Geophysical Aspects and Consequences of Change in the Composition of the Stratosphere, WMO No. 511, 61, Toronto (June1978).

Cooke, G.

D. G. Murcray, W. J. Williams, D. B. Barker, A. Goldman, C. Bradford, G. Cooke, “Measurements of Constituents of Interest in the Chemistry of the Ozone Layer Using IR Techniques,” in Proceedings, WMO Symposium on the Geophysical Aspects and Consequences of Change in the Composition of the Stratosphere, WMO No. 511, 61, Toronto (June1978).

Das, P. P.

B. Fridovich, V. Malathy Devi, P. P. Das, “Convolution of a Doppler Line by a Gaussian Instrument Function,” J. Mol. Spectrosc. 81, 269 (1980).
[Crossref]

Filkin, D. L.

C. Miller, D. L. Filkin, A. J. Owens, J. M. Steed, J. P. Jesson, “A Two-Dimensional Model of Stratospheric Chemistry and Transport,” J. Geophys. Res. 86, 12 (1981).
[Crossref]

Fridovich, B.

B. Fridovich, V. Malathy Devi, P. P. Das, “Convolution of a Doppler Line by a Gaussian Instrument Function,” J. Mol. Spectrosc. 81, 269 (1980).
[Crossref]

Goldman, A.

J. C. Larsen, C. P. Rinsland, A. Goldman, D. G. Murcray, F. J. Murcray, “Upper Limits for Stratospheric H2O2 and HOCl from High Resolution Balloon-Borne Infrared Solar Absorption Spectra,” Geophys. Res. Lett. 12, 663 (1985).
[Crossref]

D. G. Murcray, W. J. Williams, D. B. Barker, A. Goldman, C. Bradford, G. Cooke, “Measurements of Constituents of Interest in the Chemistry of the Ozone Layer Using IR Techniques,” in Proceedings, WMO Symposium on the Geophysical Aspects and Consequences of Change in the Composition of the Stratosphere, WMO No. 511, 61, Toronto (June1978).

J. J. Hillman, W. B. Olson, A. Goldman, “High Resolution Infrared Spectrum of Hydrogen Peroxide: The ν6 Fundamental Band,” J. Mol. Spectros.117 (1986), in press.
[Crossref]

Goorvitch, D.

D. Goorvitch, F. P. J. Valero, F. S. Bonomo, P. M. Silvaggio, “Band Model Analysis of the H2O2ν6(b) Band,” J. Quant. Spectrosc. Radiat. Transfer 27, 575 (1982).
[Crossref]

F. P. J. Valero, D. Goorvitch, F. S. Bonomo, R. W. Boese, “Intensity of the Hydrogen Peroxide ν6(b) Band Around 1266 cm−1,” Appl. Opt. 20, 4097 (1981).
[Crossref] [PubMed]

Hillman, J. J.

J. J. Hillman, W. B. Olson, A. Goldman, “High Resolution Infrared Spectrum of Hydrogen Peroxide: The ν6 Fundamental Band,” J. Mol. Spectros.117 (1986), in press.
[Crossref]

Jesson, J. P.

C. Miller, D. L. Filkin, A. J. Owens, J. M. Steed, J. P. Jesson, “A Two-Dimensional Model of Stratospheric Chemistry and Transport,” J. Geophys. Res. 86, 12 (1981).
[Crossref]

Larsen, J. C.

J. C. Larsen, C. P. Rinsland, A. Goldman, D. G. Murcray, F. J. Murcray, “Upper Limits for Stratospheric H2O2 and HOCl from High Resolution Balloon-Borne Infrared Solar Absorption Spectra,” Geophys. Res. Lett. 12, 663 (1985).
[Crossref]

Logan, J. A.

J. A. Logan, M. J. Prather, S. C. Wofsy, M. B. McElroy, “Tropospheric Chemistry: A Global Perspective,” J. Geophys. Res. 86, 7210 (1981).
[Crossref]

Longbothum, R. L.

J. J. Olivero, R. L. Longbothum, “Empirical Fits to the Voigt Profile,” J. Quant. Spectrosc. Radiat. Transfer 8, 1379 (1968).

Malathy Devi, V.

V. Malathy Devi, D. C. Benner, C. P. Rinsland, M. A. H. Smith, B. D. Sidney, “Tunable Diode Laser Measurements of N2-and Air-Broadened Halfwidths: Lines in the (ν4 + ν5)° Band of 12C2H2 Near 7.4 μm,” J. Mol. Spectrosc. 114, 49 (1985).
[Crossref]

V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, D. C. Benner, “Measurements of 12CH4ν4 Band Halfwidths Using a Tunable Diode Laser System and a Fourier Transform Spectrometer,” Appl. Opt. 24, 2788 (1985).
[Crossref] [PubMed]

B. Fridovich, V. Malathy Devi, P. P. Das, “Convolution of a Doppler Line by a Gaussian Instrument Function,” J. Mol. Spectrosc. 81, 269 (1980).
[Crossref]

McElroy, M. B.

J. A. Logan, M. J. Prather, S. C. Wofsy, M. B. McElroy, “Tropospheric Chemistry: A Global Perspective,” J. Geophys. Res. 86, 7210 (1981).
[Crossref]

Miller, C.

C. Miller, D. L. Filkin, A. J. Owens, J. M. Steed, J. P. Jesson, “A Two-Dimensional Model of Stratospheric Chemistry and Transport,” J. Geophys. Res. 86, 12 (1981).
[Crossref]

Murcray, D. G.

J. C. Larsen, C. P. Rinsland, A. Goldman, D. G. Murcray, F. J. Murcray, “Upper Limits for Stratospheric H2O2 and HOCl from High Resolution Balloon-Borne Infrared Solar Absorption Spectra,” Geophys. Res. Lett. 12, 663 (1985).
[Crossref]

D. G. Murcray, W. J. Williams, D. B. Barker, A. Goldman, C. Bradford, G. Cooke, “Measurements of Constituents of Interest in the Chemistry of the Ozone Layer Using IR Techniques,” in Proceedings, WMO Symposium on the Geophysical Aspects and Consequences of Change in the Composition of the Stratosphere, WMO No. 511, 61, Toronto (June1978).

Murcray, F. J.

J. C. Larsen, C. P. Rinsland, A. Goldman, D. G. Murcray, F. J. Murcray, “Upper Limits for Stratospheric H2O2 and HOCl from High Resolution Balloon-Borne Infrared Solar Absorption Spectra,” Geophys. Res. Lett. 12, 663 (1985).
[Crossref]

Olivero, J. J.

J. J. Olivero, R. L. Longbothum, “Empirical Fits to the Voigt Profile,” J. Quant. Spectrosc. Radiat. Transfer 8, 1379 (1968).

Olson, W. B.

J. J. Hillman, W. B. Olson, A. Goldman, “High Resolution Infrared Spectrum of Hydrogen Peroxide: The ν6 Fundamental Band,” J. Mol. Spectros.117 (1986), in press.
[Crossref]

Owens, A. J.

C. Miller, D. L. Filkin, A. J. Owens, J. M. Steed, J. P. Jesson, “A Two-Dimensional Model of Stratospheric Chemistry and Transport,” J. Geophys. Res. 86, 12 (1981).
[Crossref]

Prather, M. J.

J. A. Logan, M. J. Prather, S. C. Wofsy, M. B. McElroy, “Tropospheric Chemistry: A Global Perspective,” J. Geophys. Res. 86, 7210 (1981).
[Crossref]

Rinsland, C. P.

J. C. Larsen, C. P. Rinsland, A. Goldman, D. G. Murcray, F. J. Murcray, “Upper Limits for Stratospheric H2O2 and HOCl from High Resolution Balloon-Borne Infrared Solar Absorption Spectra,” Geophys. Res. Lett. 12, 663 (1985).
[Crossref]

V. Malathy Devi, D. C. Benner, C. P. Rinsland, M. A. H. Smith, B. D. Sidney, “Tunable Diode Laser Measurements of N2-and Air-Broadened Halfwidths: Lines in the (ν4 + ν5)° Band of 12C2H2 Near 7.4 μm,” J. Mol. Spectrosc. 114, 49 (1985).
[Crossref]

V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, D. C. Benner, “Measurements of 12CH4ν4 Band Halfwidths Using a Tunable Diode Laser System and a Fourier Transform Spectrometer,” Appl. Opt. 24, 2788 (1985).
[Crossref] [PubMed]

Rothman, L. S.

Sidney, B. D.

V. Malathy Devi, D. C. Benner, C. P. Rinsland, M. A. H. Smith, B. D. Sidney, “Tunable Diode Laser Measurements of N2-and Air-Broadened Halfwidths: Lines in the (ν4 + ν5)° Band of 12C2H2 Near 7.4 μm,” J. Mol. Spectrosc. 114, 49 (1985).
[Crossref]

Silvaggio, P. M.

D. Goorvitch, F. P. J. Valero, F. S. Bonomo, P. M. Silvaggio, “Band Model Analysis of the H2O2ν6(b) Band,” J. Quant. Spectrosc. Radiat. Transfer 27, 575 (1982).
[Crossref]

Smith, M. A. H.

V. Malathy Devi, D. C. Benner, C. P. Rinsland, M. A. H. Smith, B. D. Sidney, “Tunable Diode Laser Measurements of N2-and Air-Broadened Halfwidths: Lines in the (ν4 + ν5)° Band of 12C2H2 Near 7.4 μm,” J. Mol. Spectrosc. 114, 49 (1985).
[Crossref]

V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, D. C. Benner, “Measurements of 12CH4ν4 Band Halfwidths Using a Tunable Diode Laser System and a Fourier Transform Spectrometer,” Appl. Opt. 24, 2788 (1985).
[Crossref] [PubMed]

Steed, J. M.

C. Miller, D. L. Filkin, A. J. Owens, J. M. Steed, J. P. Jesson, “A Two-Dimensional Model of Stratospheric Chemistry and Transport,” J. Geophys. Res. 86, 12 (1981).
[Crossref]

Valero, F. P. J.

D. Goorvitch, F. P. J. Valero, F. S. Bonomo, P. M. Silvaggio, “Band Model Analysis of the H2O2ν6(b) Band,” J. Quant. Spectrosc. Radiat. Transfer 27, 575 (1982).
[Crossref]

F. P. J. Valero, D. Goorvitch, F. S. Bonomo, R. W. Boese, “Intensity of the Hydrogen Peroxide ν6(b) Band Around 1266 cm−1,” Appl. Opt. 20, 4097 (1981).
[Crossref] [PubMed]

Williams, W. J.

D. G. Murcray, W. J. Williams, D. B. Barker, A. Goldman, C. Bradford, G. Cooke, “Measurements of Constituents of Interest in the Chemistry of the Ozone Layer Using IR Techniques,” in Proceedings, WMO Symposium on the Geophysical Aspects and Consequences of Change in the Composition of the Stratosphere, WMO No. 511, 61, Toronto (June1978).

Wofsy, S. C.

J. A. Logan, M. J. Prather, S. C. Wofsy, M. B. McElroy, “Tropospheric Chemistry: A Global Perspective,” J. Geophys. Res. 86, 7210 (1981).
[Crossref]

Appl. Opt. (3)

Geophys. Res. Lett. (1)

J. C. Larsen, C. P. Rinsland, A. Goldman, D. G. Murcray, F. J. Murcray, “Upper Limits for Stratospheric H2O2 and HOCl from High Resolution Balloon-Borne Infrared Solar Absorption Spectra,” Geophys. Res. Lett. 12, 663 (1985).
[Crossref]

J. Geophys. Res. (2)

C. Miller, D. L. Filkin, A. J. Owens, J. M. Steed, J. P. Jesson, “A Two-Dimensional Model of Stratospheric Chemistry and Transport,” J. Geophys. Res. 86, 12 (1981).
[Crossref]

J. A. Logan, M. J. Prather, S. C. Wofsy, M. B. McElroy, “Tropospheric Chemistry: A Global Perspective,” J. Geophys. Res. 86, 7210 (1981).
[Crossref]

J. Mol. Spectrosc. (2)

B. Fridovich, V. Malathy Devi, P. P. Das, “Convolution of a Doppler Line by a Gaussian Instrument Function,” J. Mol. Spectrosc. 81, 269 (1980).
[Crossref]

V. Malathy Devi, D. C. Benner, C. P. Rinsland, M. A. H. Smith, B. D. Sidney, “Tunable Diode Laser Measurements of N2-and Air-Broadened Halfwidths: Lines in the (ν4 + ν5)° Band of 12C2H2 Near 7.4 μm,” J. Mol. Spectrosc. 114, 49 (1985).
[Crossref]

J. Quant. Spectrosc. Radiat. Transfer (2)

J. J. Olivero, R. L. Longbothum, “Empirical Fits to the Voigt Profile,” J. Quant. Spectrosc. Radiat. Transfer 8, 1379 (1968).

D. Goorvitch, F. P. J. Valero, F. S. Bonomo, P. M. Silvaggio, “Band Model Analysis of the H2O2ν6(b) Band,” J. Quant. Spectrosc. Radiat. Transfer 27, 575 (1982).
[Crossref]

Other (2)

J. J. Hillman, W. B. Olson, A. Goldman, “High Resolution Infrared Spectrum of Hydrogen Peroxide: The ν6 Fundamental Band,” J. Mol. Spectros.117 (1986), in press.
[Crossref]

D. G. Murcray, W. J. Williams, D. B. Barker, A. Goldman, C. Bradford, G. Cooke, “Measurements of Constituents of Interest in the Chemistry of the Ozone Layer Using IR Techniques,” in Proceedings, WMO Symposium on the Geophysical Aspects and Consequences of Change in the Composition of the Stratosphere, WMO No. 511, 61, Toronto (June1978).

Cited By

OSA participates in Crossref's Cited-By Linking service. Citing articles from OSA journals and other participating publishers are listed here.

Alert me when this article is cited.


Figures (2)

Fig. 1
Fig. 1

Tunable diode laser spectrum of H2O2 around 1289.8 cm−1. Ge etalon fringes (FSR = 0.0245 cm−1) recorded simultaneously are also shown. The zero intensity level as determined by blocking the beam is indicated at lower left. The pressure of the H2O2 sample - was 1.27 Torr.

Fig. 2
Fig. 2

Example of an air-broadened H2O2 line at 1286.9360 cm−1 recorded in this study. The upper spectrum was recorded with 0.5 Torr of H2O2 and the lower spectrum shows the same lines when broadened with 15.6 Torr of dry, zero air.

Tables (1)

Tables Icon

Table I Halfwidths (in cm−1 atm−1) for the ν6 Band Lines of H2O2 at 296 Ka

Equations (7)

Equations on this page are rendered with MathJax. Learn more.

b L = b L 0 ( H 2 O 2 H 2 O 2 ) p ( H 2 O 2 ) + b L 0 ( H 2 O 2 H 2 O ) p ( H 2 O ) + b L 0 ( H 2 O 2 air ) p ( air ) ,
2 b V = C 1 b L + ( C 2 b L 2 + 4 C 3 b D 2 ) 1 / 2 ,
b L 0 ( H 2 O 2 air )
K a
K c
K a
K c

Metrics