Abstract

Absolute intensities for over 300 lines of eleven relatively weak bands of 12C16O2, 13C16O2, 16O12C18O, and 16O12C17O near 2050 cm−1 have been measured from 0.01-cm−1 resolution laboratory spectra recorded with the Fourier transform spectrometer in the McMath solar telescope complex at the National Solar Observatory on Kitt Peak. The spectral data were obtained with a natural sample of carbon dioxide at room temperature and low pressure (<10 Torr) and have a signal-to-rms noise of ≈4000. The intensities were determined using the technique of nonlinear least-squares spectral curve fitting. The measured line intensities obtained for each band have been analyzed to derive the vibrational band intensity and F-factor coefficients. The results are compared to values from the 1982 Air Force Geophysics Laboratory line parameters compilation.

© 1984 Optical Society of America

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  1. C. P. Rinsland, D. C. Benner, D. J. Richardson, R. A. Toth, “Absolute Intensity Measurements of the (1110)II ← 0000 band of 12C16O2 at 5.2 μm,” Appl. Opt. 22, 3805 (1983).
    [CrossRef] [PubMed]
  2. D. C. Benner, C. P. Rinsland, “Identification and Intensities of the ‘Forbidden’ 3ν23 band of 12C16O2,” J. Mol. Spectrosc. submitted.
  3. V. Malathy Devi, C. P. Rinsland, D. C. Benner, “Absolute Intensity Measurements of CO2 bands in the 2395–2680-cm−1 Region,” Appl. Opt. 23, 4067 (1984).
    [CrossRef]
  4. L. S. Rothman, L. D. G. Young, “Infrared Energy Levels and Intensities of Carbon Dixoide—II,” J. Quant. Spectrosc. Radiat. Transfer 25, 505 (1981).
    [CrossRef]
  5. C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution IR Spectra of Carbon Dioxide,” Appl. Opt. 23, 2051 (1984).
    [CrossRef] [PubMed]
  6. C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution Infrared Spectra of Carbon Dioxide: February 1984 Edition,” NASA Tech. Memo. 85764, (NASA Langley Research Center, Hampton, Va., 1984), 468 pp.
  7. G. Yamamoto, M. Tanaka, T. Aoki, “Estimation of Rotational Line Widths of Carbon Dioxide Bands,” J. Quant. Spectrosc. Radiat. Transfer 9, 371 (1969).
    [CrossRef]
  8. R. A. Toth, “Wavenumbers, Strengths, and Self-Broadened Widths of CO2 at 3 μm,” J. Mol. Spectrosc. 53, 1 (1974).
    [CrossRef]
  9. W. B. Olson, A. G. Maki, W. J. Lafferty, “Tables of N2O Absorption Lines for the Calibration of Tunable Infrared Lasers from 522 cm−1 to 657 cm−1 and from 1115 cm−1 to 1340 cm−1,” J. Phys. Chem. Ref. Data 10, 1065 (1981).
    [CrossRef]
  10. R. A. Toth, V. D. Gupta, J. W. Brault, “Line Positions and Strengths of HDO in the 2400–3300-cm−1 Region,” Appl. Opt. 21, 3337 (1982).
    [CrossRef] [PubMed]
  11. R. A. Toth, J. W. Brault, “Line Positions and Strengths in the (001), (110), and (030) Bands of HDO,” Appl. Opt. 22, 908 (1983).
    [CrossRef] [PubMed]
  12. R. A. Toth, “Line Strengths of N2O in the 1120–1440-cm−1 Region,” Appl. Opt. 23, 1825 (1984).
    [CrossRef] [PubMed]
  13. C. P. Rinsland, A. Baldacci, K. Narahari Rao, “Strengths of 13C16O2 Lines at 4.3 μm,” J. Mol. Spectrosc. 81, 256 (1980).
    [CrossRef]
  14. E. T. Whittaker, G. Robinson, The Calculus of Observations (Blackie, Glasgow, 1926), Chap. 9.
  15. R. A. McClatchey, W. S. Benedict, S. A. Clough, D. E. Burch, R. F. Calfee, K. Fox, L. S. Rothman, J. S. Garing, “AFCRL Atmospheric Absorption Line Parameters Compilation,” Report AFCRL-TR-73-0096, Environmental Research Paper No. 434 (Air Force Cambridge Research Laboratories, Bedford, Mass., 1973).
  16. L. S. Rothman, R. R. Gamache, A. Barbe, A. Goldman, J. R. Gillis, L. R. Brown, R. A. Toth, J.-M. Flaud, C. Camy-Peyret, “AFGL Atmospheric Absorption Line Parameters Compilation: 1982 Edition,” Appl. Opt. 22, 2247 (1983).
    [CrossRef] [PubMed]
  17. W. G. Mankin, M. T. Coffey, S. R. Drayson, D. W. T. Griffith, “Spectroscopic Measurement of Carbonyl Sulfide (OCS) in the Stratosphere,” Geophys. Res. Lett. 6, 853 (1979).
    [CrossRef]
  18. A. Girard, G. Fergant, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, N. Louisnard, “Latitudinal Distribution of Ten Stratospheric Species Deduced from Simultaneous Spectroscopic Measurements,” J. Geophys. Res. 88, 5377 (1983).
    [CrossRef]
  19. N. Louisnard, G. Fergant, A. Girard, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, “Infrared Absorption Spectroscopy Applied to Stratospheric Profiles of Minor Constituents,” J. Geophys. Res. 88, 5365 (1983).
    [CrossRef]

1984 (3)

1983 (5)

C. P. Rinsland, D. C. Benner, D. J. Richardson, R. A. Toth, “Absolute Intensity Measurements of the (1110)II ← 0000 band of 12C16O2 at 5.2 μm,” Appl. Opt. 22, 3805 (1983).
[CrossRef] [PubMed]

A. Girard, G. Fergant, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, N. Louisnard, “Latitudinal Distribution of Ten Stratospheric Species Deduced from Simultaneous Spectroscopic Measurements,” J. Geophys. Res. 88, 5377 (1983).
[CrossRef]

N. Louisnard, G. Fergant, A. Girard, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, “Infrared Absorption Spectroscopy Applied to Stratospheric Profiles of Minor Constituents,” J. Geophys. Res. 88, 5365 (1983).
[CrossRef]

R. A. Toth, J. W. Brault, “Line Positions and Strengths in the (001), (110), and (030) Bands of HDO,” Appl. Opt. 22, 908 (1983).
[CrossRef] [PubMed]

L. S. Rothman, R. R. Gamache, A. Barbe, A. Goldman, J. R. Gillis, L. R. Brown, R. A. Toth, J.-M. Flaud, C. Camy-Peyret, “AFGL Atmospheric Absorption Line Parameters Compilation: 1982 Edition,” Appl. Opt. 22, 2247 (1983).
[CrossRef] [PubMed]

1982 (1)

1981 (2)

L. S. Rothman, L. D. G. Young, “Infrared Energy Levels and Intensities of Carbon Dixoide—II,” J. Quant. Spectrosc. Radiat. Transfer 25, 505 (1981).
[CrossRef]

W. B. Olson, A. G. Maki, W. J. Lafferty, “Tables of N2O Absorption Lines for the Calibration of Tunable Infrared Lasers from 522 cm−1 to 657 cm−1 and from 1115 cm−1 to 1340 cm−1,” J. Phys. Chem. Ref. Data 10, 1065 (1981).
[CrossRef]

1980 (1)

C. P. Rinsland, A. Baldacci, K. Narahari Rao, “Strengths of 13C16O2 Lines at 4.3 μm,” J. Mol. Spectrosc. 81, 256 (1980).
[CrossRef]

1979 (1)

W. G. Mankin, M. T. Coffey, S. R. Drayson, D. W. T. Griffith, “Spectroscopic Measurement of Carbonyl Sulfide (OCS) in the Stratosphere,” Geophys. Res. Lett. 6, 853 (1979).
[CrossRef]

1974 (1)

R. A. Toth, “Wavenumbers, Strengths, and Self-Broadened Widths of CO2 at 3 μm,” J. Mol. Spectrosc. 53, 1 (1974).
[CrossRef]

1969 (1)

G. Yamamoto, M. Tanaka, T. Aoki, “Estimation of Rotational Line Widths of Carbon Dioxide Bands,” J. Quant. Spectrosc. Radiat. Transfer 9, 371 (1969).
[CrossRef]

Aoki, T.

G. Yamamoto, M. Tanaka, T. Aoki, “Estimation of Rotational Line Widths of Carbon Dioxide Bands,” J. Quant. Spectrosc. Radiat. Transfer 9, 371 (1969).
[CrossRef]

Baldacci, A.

C. P. Rinsland, A. Baldacci, K. Narahari Rao, “Strengths of 13C16O2 Lines at 4.3 μm,” J. Mol. Spectrosc. 81, 256 (1980).
[CrossRef]

Barbe, A.

Benedict, W. S.

R. A. McClatchey, W. S. Benedict, S. A. Clough, D. E. Burch, R. F. Calfee, K. Fox, L. S. Rothman, J. S. Garing, “AFCRL Atmospheric Absorption Line Parameters Compilation,” Report AFCRL-TR-73-0096, Environmental Research Paper No. 434 (Air Force Cambridge Research Laboratories, Bedford, Mass., 1973).

Benner, D. C.

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution IR Spectra of Carbon Dioxide,” Appl. Opt. 23, 2051 (1984).
[CrossRef] [PubMed]

V. Malathy Devi, C. P. Rinsland, D. C. Benner, “Absolute Intensity Measurements of CO2 bands in the 2395–2680-cm−1 Region,” Appl. Opt. 23, 4067 (1984).
[CrossRef]

C. P. Rinsland, D. C. Benner, D. J. Richardson, R. A. Toth, “Absolute Intensity Measurements of the (1110)II ← 0000 band of 12C16O2 at 5.2 μm,” Appl. Opt. 22, 3805 (1983).
[CrossRef] [PubMed]

D. C. Benner, C. P. Rinsland, “Identification and Intensities of the ‘Forbidden’ 3ν23 band of 12C16O2,” J. Mol. Spectrosc. submitted.

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution Infrared Spectra of Carbon Dioxide: February 1984 Edition,” NASA Tech. Memo. 85764, (NASA Langley Research Center, Hampton, Va., 1984), 468 pp.

Brault, J. W.

Brown, L. R.

Burch, D. E.

R. A. McClatchey, W. S. Benedict, S. A. Clough, D. E. Burch, R. F. Calfee, K. Fox, L. S. Rothman, J. S. Garing, “AFCRL Atmospheric Absorption Line Parameters Compilation,” Report AFCRL-TR-73-0096, Environmental Research Paper No. 434 (Air Force Cambridge Research Laboratories, Bedford, Mass., 1973).

Calfee, R. F.

R. A. McClatchey, W. S. Benedict, S. A. Clough, D. E. Burch, R. F. Calfee, K. Fox, L. S. Rothman, J. S. Garing, “AFCRL Atmospheric Absorption Line Parameters Compilation,” Report AFCRL-TR-73-0096, Environmental Research Paper No. 434 (Air Force Cambridge Research Laboratories, Bedford, Mass., 1973).

Camy-Peyret, C.

Clough, S. A.

R. A. McClatchey, W. S. Benedict, S. A. Clough, D. E. Burch, R. F. Calfee, K. Fox, L. S. Rothman, J. S. Garing, “AFCRL Atmospheric Absorption Line Parameters Compilation,” Report AFCRL-TR-73-0096, Environmental Research Paper No. 434 (Air Force Cambridge Research Laboratories, Bedford, Mass., 1973).

Coffey, M. T.

W. G. Mankin, M. T. Coffey, S. R. Drayson, D. W. T. Griffith, “Spectroscopic Measurement of Carbonyl Sulfide (OCS) in the Stratosphere,” Geophys. Res. Lett. 6, 853 (1979).
[CrossRef]

Drayson, S. R.

W. G. Mankin, M. T. Coffey, S. R. Drayson, D. W. T. Griffith, “Spectroscopic Measurement of Carbonyl Sulfide (OCS) in the Stratosphere,” Geophys. Res. Lett. 6, 853 (1979).
[CrossRef]

Fergant, G.

A. Girard, G. Fergant, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, N. Louisnard, “Latitudinal Distribution of Ten Stratospheric Species Deduced from Simultaneous Spectroscopic Measurements,” J. Geophys. Res. 88, 5377 (1983).
[CrossRef]

N. Louisnard, G. Fergant, A. Girard, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, “Infrared Absorption Spectroscopy Applied to Stratospheric Profiles of Minor Constituents,” J. Geophys. Res. 88, 5365 (1983).
[CrossRef]

Ferry, P. S.

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution IR Spectra of Carbon Dioxide,” Appl. Opt. 23, 2051 (1984).
[CrossRef] [PubMed]

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution Infrared Spectra of Carbon Dioxide: February 1984 Edition,” NASA Tech. Memo. 85764, (NASA Langley Research Center, Hampton, Va., 1984), 468 pp.

Flaud, J.-M.

Fox, K.

R. A. McClatchey, W. S. Benedict, S. A. Clough, D. E. Burch, R. F. Calfee, K. Fox, L. S. Rothman, J. S. Garing, “AFCRL Atmospheric Absorption Line Parameters Compilation,” Report AFCRL-TR-73-0096, Environmental Research Paper No. 434 (Air Force Cambridge Research Laboratories, Bedford, Mass., 1973).

Gamache, R. R.

Garing, J. S.

R. A. McClatchey, W. S. Benedict, S. A. Clough, D. E. Burch, R. F. Calfee, K. Fox, L. S. Rothman, J. S. Garing, “AFCRL Atmospheric Absorption Line Parameters Compilation,” Report AFCRL-TR-73-0096, Environmental Research Paper No. 434 (Air Force Cambridge Research Laboratories, Bedford, Mass., 1973).

Gillis, J. R.

Girard, A.

A. Girard, G. Fergant, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, N. Louisnard, “Latitudinal Distribution of Ten Stratospheric Species Deduced from Simultaneous Spectroscopic Measurements,” J. Geophys. Res. 88, 5377 (1983).
[CrossRef]

N. Louisnard, G. Fergant, A. Girard, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, “Infrared Absorption Spectroscopy Applied to Stratospheric Profiles of Minor Constituents,” J. Geophys. Res. 88, 5365 (1983).
[CrossRef]

Goldman, A.

Gramont, L.

A. Girard, G. Fergant, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, N. Louisnard, “Latitudinal Distribution of Ten Stratospheric Species Deduced from Simultaneous Spectroscopic Measurements,” J. Geophys. Res. 88, 5377 (1983).
[CrossRef]

N. Louisnard, G. Fergant, A. Girard, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, “Infrared Absorption Spectroscopy Applied to Stratospheric Profiles of Minor Constituents,” J. Geophys. Res. 88, 5365 (1983).
[CrossRef]

Griffith, D. W. T.

W. G. Mankin, M. T. Coffey, S. R. Drayson, D. W. T. Griffith, “Spectroscopic Measurement of Carbonyl Sulfide (OCS) in the Stratosphere,” Geophys. Res. Lett. 6, 853 (1979).
[CrossRef]

Gupta, V. D.

Lado-Bordowsky, O.

A. Girard, G. Fergant, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, N. Louisnard, “Latitudinal Distribution of Ten Stratospheric Species Deduced from Simultaneous Spectroscopic Measurements,” J. Geophys. Res. 88, 5377 (1983).
[CrossRef]

N. Louisnard, G. Fergant, A. Girard, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, “Infrared Absorption Spectroscopy Applied to Stratospheric Profiles of Minor Constituents,” J. Geophys. Res. 88, 5365 (1983).
[CrossRef]

Lafferty, W. J.

W. B. Olson, A. G. Maki, W. J. Lafferty, “Tables of N2O Absorption Lines for the Calibration of Tunable Infrared Lasers from 522 cm−1 to 657 cm−1 and from 1115 cm−1 to 1340 cm−1,” J. Phys. Chem. Ref. Data 10, 1065 (1981).
[CrossRef]

Laurent, J.

N. Louisnard, G. Fergant, A. Girard, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, “Infrared Absorption Spectroscopy Applied to Stratospheric Profiles of Minor Constituents,” J. Geophys. Res. 88, 5365 (1983).
[CrossRef]

A. Girard, G. Fergant, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, N. Louisnard, “Latitudinal Distribution of Ten Stratospheric Species Deduced from Simultaneous Spectroscopic Measurements,” J. Geophys. Res. 88, 5377 (1983).
[CrossRef]

Le Boiteux, S.

A. Girard, G. Fergant, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, N. Louisnard, “Latitudinal Distribution of Ten Stratospheric Species Deduced from Simultaneous Spectroscopic Measurements,” J. Geophys. Res. 88, 5377 (1983).
[CrossRef]

N. Louisnard, G. Fergant, A. Girard, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, “Infrared Absorption Spectroscopy Applied to Stratospheric Profiles of Minor Constituents,” J. Geophys. Res. 88, 5365 (1983).
[CrossRef]

Lemaitre, M. P.

N. Louisnard, G. Fergant, A. Girard, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, “Infrared Absorption Spectroscopy Applied to Stratospheric Profiles of Minor Constituents,” J. Geophys. Res. 88, 5365 (1983).
[CrossRef]

A. Girard, G. Fergant, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, N. Louisnard, “Latitudinal Distribution of Ten Stratospheric Species Deduced from Simultaneous Spectroscopic Measurements,” J. Geophys. Res. 88, 5377 (1983).
[CrossRef]

Louisnard, N.

A. Girard, G. Fergant, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, N. Louisnard, “Latitudinal Distribution of Ten Stratospheric Species Deduced from Simultaneous Spectroscopic Measurements,” J. Geophys. Res. 88, 5377 (1983).
[CrossRef]

N. Louisnard, G. Fergant, A. Girard, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, “Infrared Absorption Spectroscopy Applied to Stratospheric Profiles of Minor Constituents,” J. Geophys. Res. 88, 5365 (1983).
[CrossRef]

Maki, A. G.

W. B. Olson, A. G. Maki, W. J. Lafferty, “Tables of N2O Absorption Lines for the Calibration of Tunable Infrared Lasers from 522 cm−1 to 657 cm−1 and from 1115 cm−1 to 1340 cm−1,” J. Phys. Chem. Ref. Data 10, 1065 (1981).
[CrossRef]

Malathy Devi, V.

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution IR Spectra of Carbon Dioxide,” Appl. Opt. 23, 2051 (1984).
[CrossRef] [PubMed]

V. Malathy Devi, C. P. Rinsland, D. C. Benner, “Absolute Intensity Measurements of CO2 bands in the 2395–2680-cm−1 Region,” Appl. Opt. 23, 4067 (1984).
[CrossRef]

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution Infrared Spectra of Carbon Dioxide: February 1984 Edition,” NASA Tech. Memo. 85764, (NASA Langley Research Center, Hampton, Va., 1984), 468 pp.

Mankin, W. G.

W. G. Mankin, M. T. Coffey, S. R. Drayson, D. W. T. Griffith, “Spectroscopic Measurement of Carbonyl Sulfide (OCS) in the Stratosphere,” Geophys. Res. Lett. 6, 853 (1979).
[CrossRef]

McClatchey, R. A.

R. A. McClatchey, W. S. Benedict, S. A. Clough, D. E. Burch, R. F. Calfee, K. Fox, L. S. Rothman, J. S. Garing, “AFCRL Atmospheric Absorption Line Parameters Compilation,” Report AFCRL-TR-73-0096, Environmental Research Paper No. 434 (Air Force Cambridge Research Laboratories, Bedford, Mass., 1973).

Narahari Rao, K.

C. P. Rinsland, A. Baldacci, K. Narahari Rao, “Strengths of 13C16O2 Lines at 4.3 μm,” J. Mol. Spectrosc. 81, 256 (1980).
[CrossRef]

Olson, W. B.

W. B. Olson, A. G. Maki, W. J. Lafferty, “Tables of N2O Absorption Lines for the Calibration of Tunable Infrared Lasers from 522 cm−1 to 657 cm−1 and from 1115 cm−1 to 1340 cm−1,” J. Phys. Chem. Ref. Data 10, 1065 (1981).
[CrossRef]

Richardson, D. J.

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution IR Spectra of Carbon Dioxide,” Appl. Opt. 23, 2051 (1984).
[CrossRef] [PubMed]

C. P. Rinsland, D. C. Benner, D. J. Richardson, R. A. Toth, “Absolute Intensity Measurements of the (1110)II ← 0000 band of 12C16O2 at 5.2 μm,” Appl. Opt. 22, 3805 (1983).
[CrossRef] [PubMed]

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution Infrared Spectra of Carbon Dioxide: February 1984 Edition,” NASA Tech. Memo. 85764, (NASA Langley Research Center, Hampton, Va., 1984), 468 pp.

Rinsland, C. P.

V. Malathy Devi, C. P. Rinsland, D. C. Benner, “Absolute Intensity Measurements of CO2 bands in the 2395–2680-cm−1 Region,” Appl. Opt. 23, 4067 (1984).
[CrossRef]

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution IR Spectra of Carbon Dioxide,” Appl. Opt. 23, 2051 (1984).
[CrossRef] [PubMed]

C. P. Rinsland, D. C. Benner, D. J. Richardson, R. A. Toth, “Absolute Intensity Measurements of the (1110)II ← 0000 band of 12C16O2 at 5.2 μm,” Appl. Opt. 22, 3805 (1983).
[CrossRef] [PubMed]

C. P. Rinsland, A. Baldacci, K. Narahari Rao, “Strengths of 13C16O2 Lines at 4.3 μm,” J. Mol. Spectrosc. 81, 256 (1980).
[CrossRef]

D. C. Benner, C. P. Rinsland, “Identification and Intensities of the ‘Forbidden’ 3ν23 band of 12C16O2,” J. Mol. Spectrosc. submitted.

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution Infrared Spectra of Carbon Dioxide: February 1984 Edition,” NASA Tech. Memo. 85764, (NASA Langley Research Center, Hampton, Va., 1984), 468 pp.

Robinson, G.

E. T. Whittaker, G. Robinson, The Calculus of Observations (Blackie, Glasgow, 1926), Chap. 9.

Rothman, L. S.

L. S. Rothman, R. R. Gamache, A. Barbe, A. Goldman, J. R. Gillis, L. R. Brown, R. A. Toth, J.-M. Flaud, C. Camy-Peyret, “AFGL Atmospheric Absorption Line Parameters Compilation: 1982 Edition,” Appl. Opt. 22, 2247 (1983).
[CrossRef] [PubMed]

L. S. Rothman, L. D. G. Young, “Infrared Energy Levels and Intensities of Carbon Dixoide—II,” J. Quant. Spectrosc. Radiat. Transfer 25, 505 (1981).
[CrossRef]

R. A. McClatchey, W. S. Benedict, S. A. Clough, D. E. Burch, R. F. Calfee, K. Fox, L. S. Rothman, J. S. Garing, “AFCRL Atmospheric Absorption Line Parameters Compilation,” Report AFCRL-TR-73-0096, Environmental Research Paper No. 434 (Air Force Cambridge Research Laboratories, Bedford, Mass., 1973).

Sutton, C. H.

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution IR Spectra of Carbon Dioxide,” Appl. Opt. 23, 2051 (1984).
[CrossRef] [PubMed]

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution Infrared Spectra of Carbon Dioxide: February 1984 Edition,” NASA Tech. Memo. 85764, (NASA Langley Research Center, Hampton, Va., 1984), 468 pp.

Tanaka, M.

G. Yamamoto, M. Tanaka, T. Aoki, “Estimation of Rotational Line Widths of Carbon Dioxide Bands,” J. Quant. Spectrosc. Radiat. Transfer 9, 371 (1969).
[CrossRef]

Toth, R. A.

Whittaker, E. T.

E. T. Whittaker, G. Robinson, The Calculus of Observations (Blackie, Glasgow, 1926), Chap. 9.

Yamamoto, G.

G. Yamamoto, M. Tanaka, T. Aoki, “Estimation of Rotational Line Widths of Carbon Dioxide Bands,” J. Quant. Spectrosc. Radiat. Transfer 9, 371 (1969).
[CrossRef]

Young, L. D. G.

L. S. Rothman, L. D. G. Young, “Infrared Energy Levels and Intensities of Carbon Dixoide—II,” J. Quant. Spectrosc. Radiat. Transfer 25, 505 (1981).
[CrossRef]

Appl. Opt. (7)

Geophys. Res. Lett. (1)

W. G. Mankin, M. T. Coffey, S. R. Drayson, D. W. T. Griffith, “Spectroscopic Measurement of Carbonyl Sulfide (OCS) in the Stratosphere,” Geophys. Res. Lett. 6, 853 (1979).
[CrossRef]

J. Geophys. Res. (2)

A. Girard, G. Fergant, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, N. Louisnard, “Latitudinal Distribution of Ten Stratospheric Species Deduced from Simultaneous Spectroscopic Measurements,” J. Geophys. Res. 88, 5377 (1983).
[CrossRef]

N. Louisnard, G. Fergant, A. Girard, L. Gramont, O. Lado-Bordowsky, J. Laurent, S. Le Boiteux, M. P. Lemaitre, “Infrared Absorption Spectroscopy Applied to Stratospheric Profiles of Minor Constituents,” J. Geophys. Res. 88, 5365 (1983).
[CrossRef]

J. Mol. Spectrosc. (2)

R. A. Toth, “Wavenumbers, Strengths, and Self-Broadened Widths of CO2 at 3 μm,” J. Mol. Spectrosc. 53, 1 (1974).
[CrossRef]

C. P. Rinsland, A. Baldacci, K. Narahari Rao, “Strengths of 13C16O2 Lines at 4.3 μm,” J. Mol. Spectrosc. 81, 256 (1980).
[CrossRef]

J. Phys. Chem. Ref. Data (1)

W. B. Olson, A. G. Maki, W. J. Lafferty, “Tables of N2O Absorption Lines for the Calibration of Tunable Infrared Lasers from 522 cm−1 to 657 cm−1 and from 1115 cm−1 to 1340 cm−1,” J. Phys. Chem. Ref. Data 10, 1065 (1981).
[CrossRef]

J. Quant. Spectrosc. Radiat. Transfer (2)

L. S. Rothman, L. D. G. Young, “Infrared Energy Levels and Intensities of Carbon Dixoide—II,” J. Quant. Spectrosc. Radiat. Transfer 25, 505 (1981).
[CrossRef]

G. Yamamoto, M. Tanaka, T. Aoki, “Estimation of Rotational Line Widths of Carbon Dioxide Bands,” J. Quant. Spectrosc. Radiat. Transfer 9, 371 (1969).
[CrossRef]

Other (4)

D. C. Benner, C. P. Rinsland, “Identification and Intensities of the ‘Forbidden’ 3ν23 band of 12C16O2,” J. Mol. Spectrosc. submitted.

C. P. Rinsland, D. C. Benner, V. Malathy Devi, P. S. Ferry, C. H. Sutton, D. J. Richardson, “Atlas of High Resolution Infrared Spectra of Carbon Dioxide: February 1984 Edition,” NASA Tech. Memo. 85764, (NASA Langley Research Center, Hampton, Va., 1984), 468 pp.

E. T. Whittaker, G. Robinson, The Calculus of Observations (Blackie, Glasgow, 1926), Chap. 9.

R. A. McClatchey, W. S. Benedict, S. A. Clough, D. E. Burch, R. F. Calfee, K. Fox, L. S. Rothman, J. S. Garing, “AFCRL Atmospheric Absorption Line Parameters Compilation,” Report AFCRL-TR-73-0096, Environmental Research Paper No. 434 (Air Force Cambridge Research Laboratories, Bedford, Mass., 1973).

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Figures (1)

Fig. 1
Fig. 1

Laboratory spectrum (lower panel) recorded with 3.000 Torr of natural CO2 in a 385.76-m absorption path at 25.2°C and residuals in percent (observed–calculated) from a least-squares fit to the data (upper panel). The observed spectrum and the residuals have been normalized to the highest intensity measured in the fitted region. Tick marks above the observed spectrum indicate the positions of the nineteen lines included in the analysis. This spectral region contains the low J lines of the Q branch of the 11101 ← 00001 band of 13C16O2.

Tables (5)

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Table I Experimental Conditions

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Table II Range in J and Number of Lines Measured in Each Band

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Table III Observed Line Positions (cm−1) and Observed and Calculated Line Intensities(cm−1/molecule cm−2 at 296 K) for Some CO2 Bands near 2050 cm−1

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Table IV Vibrational Band Intensity Sv, F-factor Coefficients, and Integrated Band Intensity Sband Determined from the Analysisa

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Table V Comparison of Vlbrational Band Intensities Sv (in 10−24 cm−1/moleculec m−2 at 296 K) and A1 Coefficients of the F factor Determined in this Study and Values from the 1982 Air Force Geophysics Laboratory (AFGL) Line Parameters Compilation

Equations (5)

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S i = ν i ν 0 S v L i Q r exp ( - C 2 E i / T 0 ) [ 1 - exp ( - C 2 ν i / T 0 ) ] F ,
L i = ( J ± l + 1 ) ( J ± l + 2 ) / ( J + 1 ) R branch , L i = ( J l ) ( J l - 1 ) / J P branch , L i = ( 2 J + 1 ) ( J l ) ( J ± l + 1 ) / [ J ( J + 1 ) ] Q branch ,
F = [ 1 + A 1 m + A 2 m 2 + A 3 m 3 + A 4 J ( J + 1 ) ] 2             P and R branches , F = [ 1 + A 4 J ( J + 1 ) ] 2             Q branch ,
S band = J S ( J ) + m S ( m ) ,
β = ( S obs - S calc ) / S calc ,

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