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  1. D. R. Crosley, Opt. Eng. 20, 511 (1981).
    [CrossRef]
  2. D. R. Crosley, R. K. Lengel, J. Quant. Spectrosc. Radiat. Transfer 17, 59 (1977); I. L. Chidsey, D. R. Crosley, J. Quant. Spectrosc. Radiat. Transfer 23, 187 (1980).
    [CrossRef]
  3. K. R. German, J. Chem. Phys. 64, 4065 (1976).
    [CrossRef]
  4. R. K. Lengel, D. R. Crosley, Chem. Phys. Lett. 32, 261 (1975); J. Chem. Phys. 68, 5309 (1978).
    [CrossRef]
  5. P. W. Fairchild, G. P. Smith, D. R. Crosley, at Western States Meeting of the Combustion Institute, Livermore, Calif., Oct. 1982;J. Chem. Phys. to be published.
  6. D. R. Crosley, G. P. Smith, Appl. Opt. 19, 517 (1980).
    [CrossRef] [PubMed]
  7. G. P. Smith, D. R. Crosley, in Eighteenth Symposium (International) on Combustion (Combustion Institute, Pittsburgh, 1981), p. 1511.
    [CrossRef]
  8. D. R. Crosley, G. P. Smith, Combust. Flame 44, 27 (1982).
    [CrossRef]
  9. A. G. Gaydon, The Spectroscopy of Flames (Chapman & Hall, London, 1974).
    [CrossRef]

1982 (1)

D. R. Crosley, G. P. Smith, Combust. Flame 44, 27 (1982).
[CrossRef]

1981 (1)

D. R. Crosley, Opt. Eng. 20, 511 (1981).
[CrossRef]

1980 (1)

1977 (1)

D. R. Crosley, R. K. Lengel, J. Quant. Spectrosc. Radiat. Transfer 17, 59 (1977); I. L. Chidsey, D. R. Crosley, J. Quant. Spectrosc. Radiat. Transfer 23, 187 (1980).
[CrossRef]

1976 (1)

K. R. German, J. Chem. Phys. 64, 4065 (1976).
[CrossRef]

1975 (1)

R. K. Lengel, D. R. Crosley, Chem. Phys. Lett. 32, 261 (1975); J. Chem. Phys. 68, 5309 (1978).
[CrossRef]

Crosley, D. R.

D. R. Crosley, G. P. Smith, Combust. Flame 44, 27 (1982).
[CrossRef]

D. R. Crosley, Opt. Eng. 20, 511 (1981).
[CrossRef]

D. R. Crosley, G. P. Smith, Appl. Opt. 19, 517 (1980).
[CrossRef] [PubMed]

D. R. Crosley, R. K. Lengel, J. Quant. Spectrosc. Radiat. Transfer 17, 59 (1977); I. L. Chidsey, D. R. Crosley, J. Quant. Spectrosc. Radiat. Transfer 23, 187 (1980).
[CrossRef]

R. K. Lengel, D. R. Crosley, Chem. Phys. Lett. 32, 261 (1975); J. Chem. Phys. 68, 5309 (1978).
[CrossRef]

G. P. Smith, D. R. Crosley, in Eighteenth Symposium (International) on Combustion (Combustion Institute, Pittsburgh, 1981), p. 1511.
[CrossRef]

P. W. Fairchild, G. P. Smith, D. R. Crosley, at Western States Meeting of the Combustion Institute, Livermore, Calif., Oct. 1982;J. Chem. Phys. to be published.

Fairchild, P. W.

P. W. Fairchild, G. P. Smith, D. R. Crosley, at Western States Meeting of the Combustion Institute, Livermore, Calif., Oct. 1982;J. Chem. Phys. to be published.

Gaydon, A. G.

A. G. Gaydon, The Spectroscopy of Flames (Chapman & Hall, London, 1974).
[CrossRef]

German, K. R.

K. R. German, J. Chem. Phys. 64, 4065 (1976).
[CrossRef]

Lengel, R. K.

D. R. Crosley, R. K. Lengel, J. Quant. Spectrosc. Radiat. Transfer 17, 59 (1977); I. L. Chidsey, D. R. Crosley, J. Quant. Spectrosc. Radiat. Transfer 23, 187 (1980).
[CrossRef]

R. K. Lengel, D. R. Crosley, Chem. Phys. Lett. 32, 261 (1975); J. Chem. Phys. 68, 5309 (1978).
[CrossRef]

Smith, G. P.

D. R. Crosley, G. P. Smith, Combust. Flame 44, 27 (1982).
[CrossRef]

D. R. Crosley, G. P. Smith, Appl. Opt. 19, 517 (1980).
[CrossRef] [PubMed]

G. P. Smith, D. R. Crosley, in Eighteenth Symposium (International) on Combustion (Combustion Institute, Pittsburgh, 1981), p. 1511.
[CrossRef]

P. W. Fairchild, G. P. Smith, D. R. Crosley, at Western States Meeting of the Combustion Institute, Livermore, Calif., Oct. 1982;J. Chem. Phys. to be published.

Appl. Opt. (1)

Chem. Phys. Lett. (1)

R. K. Lengel, D. R. Crosley, Chem. Phys. Lett. 32, 261 (1975); J. Chem. Phys. 68, 5309 (1978).
[CrossRef]

Combust. Flame (1)

D. R. Crosley, G. P. Smith, Combust. Flame 44, 27 (1982).
[CrossRef]

J. Chem. Phys. (1)

K. R. German, J. Chem. Phys. 64, 4065 (1976).
[CrossRef]

J. Quant. Spectrosc. Radiat. Transfer (1)

D. R. Crosley, R. K. Lengel, J. Quant. Spectrosc. Radiat. Transfer 17, 59 (1977); I. L. Chidsey, D. R. Crosley, J. Quant. Spectrosc. Radiat. Transfer 23, 187 (1980).
[CrossRef]

Opt. Eng. (1)

D. R. Crosley, Opt. Eng. 20, 511 (1981).
[CrossRef]

Other (3)

P. W. Fairchild, G. P. Smith, D. R. Crosley, at Western States Meeting of the Combustion Institute, Livermore, Calif., Oct. 1982;J. Chem. Phys. to be published.

G. P. Smith, D. R. Crosley, in Eighteenth Symposium (International) on Combustion (Combustion Institute, Pittsburgh, 1981), p. 1511.
[CrossRef]

A. G. Gaydon, The Spectroscopy of Flames (Chapman & Hall, London, 1974).
[CrossRef]

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Figures (4)

Fig. 1
Fig. 1

Low-resolution (2.5-Å) scan of the OH fluorescence produced upon exciting the N′ = 1 (top) and N′ = 10 (bottom) rotational levels of v′ = 1. Emission in the (1,1) band at λ > 3122 Å is from the level pumped by the laser, while that in (0,0) is due to molecules which have undergone collisional transfer to v′ = 0. The largest peaks in the (1,1) band are the branches emitted by the pumped level.

Fig. 2
Fig. 2

High-resolution scan of the OH fluorescence spectra obtained upon excitation of N′ = 1 and 5 in v′ = 1. Note the markedly different rotational distributions in v′ = 1 emission (λ > 3122 Å) in contrast to the similarities in the v′ = 0 fluorescence (λ < 3122 Å). As in Fig. 1, the largest (1,1) peaks belong to the pumped level.

Fig. 3
Fig. 3

Ratio of OH populations in v′ = 0 and v′ = 1 plotted vs the quantum number of the rotational level initially excited in v′ = 1. The straight line merely demonstrates the smoothness of the variation.

Fig. 4
Fig. 4

Boltzmann plots of the distribution over rotational levels in v′ = 0 of the vibrationally transferred molecules in excited OH. The vertical tic marks are separated by one natural logarithm unit; each plot is separated for clarity. The numbers denote the initially pumped rotational level in v′ = 1 and the temperature which best describes the corresponding distribution.

Equations (1)

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I ( 1 , 1 ) / I ( 0 , 0 ) 0 n 0 d t / 0 n 1 d t = V / Q .

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