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  1. D.-S. Wang, H. Chew, M. Kerker, Appl. Opt. 19, 2256 (1980).
    [CrossRef] [PubMed]
  2. M. Kerker, D.-S. Wang, H. Chew, Appl. Opt. 19, 3373 (1980).
    [CrossRef] [PubMed]
  3. R. P. Van Duyne, in Chemical and Biological Applications of Lasers, C. B. Moore, Ed. (Academic, N.Y., 1979), Vol. 4, p. 174.
  4. J. A. Creighton, C. G. Blatchford, M. G. Albrecht, J. Chem. Soc., Faraday Trans. 75, 790 (1979).
    [CrossRef]
  5. M. Carey Lea, Am. J. Sci. 37, 476 (1889).
  6. M. Kerker, The Scattering of Light and other Electromagnetic Radiation, (Academic, N.Y., 1969).
  7. P. B. Johnson, R. W. Christy, Phys. Rev. B: 6, 4370 (1972).
    [CrossRef]
  8. G. Frens, J. T. G. Overbeek, Kolloid Z. Z. Polym. 233, 922 (1969).
    [CrossRef]
  9. J. T. Edsall, J. Chem. Phys. 5, 508 (1937).
    [CrossRef]
  10. F. R. Dollish, W. G. Fately, F. F. Bentley, Characteristic Raman Frequencies of Organic Compounds, (Wiley-Interscience, New York, 1974).
  11. U. Kreibig, Z. Phys. 234, 307 (1970).
    [CrossRef]
  12. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Wiley-Interscience, N.Y., 1978).
  13. C. B. Baddiel, C. D. Cavendish, W. O. George, J. Mol. Struct. 5, 263 (1970).
    [CrossRef]
  14. S. M. Tsimbler, L. L. Shevchenko, V. V. Grigoreva, Zh. Prikl. Spektrosk, 10, 522 (1969).

1980 (2)

1979 (1)

J. A. Creighton, C. G. Blatchford, M. G. Albrecht, J. Chem. Soc., Faraday Trans. 75, 790 (1979).
[CrossRef]

1972 (1)

P. B. Johnson, R. W. Christy, Phys. Rev. B: 6, 4370 (1972).
[CrossRef]

1970 (2)

U. Kreibig, Z. Phys. 234, 307 (1970).
[CrossRef]

C. B. Baddiel, C. D. Cavendish, W. O. George, J. Mol. Struct. 5, 263 (1970).
[CrossRef]

1969 (2)

S. M. Tsimbler, L. L. Shevchenko, V. V. Grigoreva, Zh. Prikl. Spektrosk, 10, 522 (1969).

G. Frens, J. T. G. Overbeek, Kolloid Z. Z. Polym. 233, 922 (1969).
[CrossRef]

1937 (1)

J. T. Edsall, J. Chem. Phys. 5, 508 (1937).
[CrossRef]

1889 (1)

M. Carey Lea, Am. J. Sci. 37, 476 (1889).

Albrecht, M. G.

J. A. Creighton, C. G. Blatchford, M. G. Albrecht, J. Chem. Soc., Faraday Trans. 75, 790 (1979).
[CrossRef]

Baddiel, C. B.

C. B. Baddiel, C. D. Cavendish, W. O. George, J. Mol. Struct. 5, 263 (1970).
[CrossRef]

Bentley, F. F.

F. R. Dollish, W. G. Fately, F. F. Bentley, Characteristic Raman Frequencies of Organic Compounds, (Wiley-Interscience, New York, 1974).

Blatchford, C. G.

J. A. Creighton, C. G. Blatchford, M. G. Albrecht, J. Chem. Soc., Faraday Trans. 75, 790 (1979).
[CrossRef]

Carey Lea, M.

M. Carey Lea, Am. J. Sci. 37, 476 (1889).

Cavendish, C. D.

C. B. Baddiel, C. D. Cavendish, W. O. George, J. Mol. Struct. 5, 263 (1970).
[CrossRef]

Chew, H.

Christy, R. W.

P. B. Johnson, R. W. Christy, Phys. Rev. B: 6, 4370 (1972).
[CrossRef]

Creighton, J. A.

J. A. Creighton, C. G. Blatchford, M. G. Albrecht, J. Chem. Soc., Faraday Trans. 75, 790 (1979).
[CrossRef]

Dollish, F. R.

F. R. Dollish, W. G. Fately, F. F. Bentley, Characteristic Raman Frequencies of Organic Compounds, (Wiley-Interscience, New York, 1974).

Edsall, J. T.

J. T. Edsall, J. Chem. Phys. 5, 508 (1937).
[CrossRef]

Fately, W. G.

F. R. Dollish, W. G. Fately, F. F. Bentley, Characteristic Raman Frequencies of Organic Compounds, (Wiley-Interscience, New York, 1974).

Frens, G.

G. Frens, J. T. G. Overbeek, Kolloid Z. Z. Polym. 233, 922 (1969).
[CrossRef]

George, W. O.

C. B. Baddiel, C. D. Cavendish, W. O. George, J. Mol. Struct. 5, 263 (1970).
[CrossRef]

Grigoreva, V. V.

S. M. Tsimbler, L. L. Shevchenko, V. V. Grigoreva, Zh. Prikl. Spektrosk, 10, 522 (1969).

Johnson, P. B.

P. B. Johnson, R. W. Christy, Phys. Rev. B: 6, 4370 (1972).
[CrossRef]

Kerker, M.

Kreibig, U.

U. Kreibig, Z. Phys. 234, 307 (1970).
[CrossRef]

Nakamoto, K.

K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Wiley-Interscience, N.Y., 1978).

Overbeek, J. T. G.

G. Frens, J. T. G. Overbeek, Kolloid Z. Z. Polym. 233, 922 (1969).
[CrossRef]

Shevchenko, L. L.

S. M. Tsimbler, L. L. Shevchenko, V. V. Grigoreva, Zh. Prikl. Spektrosk, 10, 522 (1969).

Tsimbler, S. M.

S. M. Tsimbler, L. L. Shevchenko, V. V. Grigoreva, Zh. Prikl. Spektrosk, 10, 522 (1969).

Van Duyne, R. P.

R. P. Van Duyne, in Chemical and Biological Applications of Lasers, C. B. Moore, Ed. (Academic, N.Y., 1979), Vol. 4, p. 174.

Wang, D.-S.

Am. J. Sci. (1)

M. Carey Lea, Am. J. Sci. 37, 476 (1889).

Appl. Opt. (2)

J. Chem. Phys. (1)

J. T. Edsall, J. Chem. Phys. 5, 508 (1937).
[CrossRef]

J. Chem. Soc., Faraday Trans. (1)

J. A. Creighton, C. G. Blatchford, M. G. Albrecht, J. Chem. Soc., Faraday Trans. 75, 790 (1979).
[CrossRef]

J. Mol. Struct. (1)

C. B. Baddiel, C. D. Cavendish, W. O. George, J. Mol. Struct. 5, 263 (1970).
[CrossRef]

Kolloid Z. Z. Polym. (1)

G. Frens, J. T. G. Overbeek, Kolloid Z. Z. Polym. 233, 922 (1969).
[CrossRef]

Phys. Rev. B (1)

P. B. Johnson, R. W. Christy, Phys. Rev. B: 6, 4370 (1972).
[CrossRef]

Z. Phys. (1)

U. Kreibig, Z. Phys. 234, 307 (1970).
[CrossRef]

Zh. Prikl. Spektrosk (1)

S. M. Tsimbler, L. L. Shevchenko, V. V. Grigoreva, Zh. Prikl. Spektrosk, 10, 522 (1969).

Other (4)

K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Wiley-Interscience, N.Y., 1978).

F. R. Dollish, W. G. Fately, F. F. Bentley, Characteristic Raman Frequencies of Organic Compounds, (Wiley-Interscience, New York, 1974).

R. P. Van Duyne, in Chemical and Biological Applications of Lasers, C. B. Moore, Ed. (Academic, N.Y., 1979), Vol. 4, p. 174.

M. Kerker, The Scattering of Light and other Electromagnetic Radiation, (Academic, N.Y., 1969).

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Figures (3)

Fig. 1
Fig. 1

Absorption spectrum of 500:1 diluted silver sol with adsorbed citrate —; theoretical extinction efficiency normalized at peak absorbance, λ = 400 nm, ---.

Fig. 2
Fig. 2

Raman spectra with 514.5-nm Ar+ excitation. A, 1.37 M sodium citrate; B, freshly diluted sol; C, one week old sol; D, two week old sol. Experimental conditions: laser power, 50 mw; sensitivity, 4000 cps; spectral slit width, 10 cm−1; time constant, 2 sec; scan speed, 1 cm−1/sec.

Fig. 3
Fig. 3

Raman spectra of 1.37 M sodium citrate, LHS, vs silver sol with adsorbed citrate, RHS, in 1400-cm−1 region. Experimental conditions: laser power, 50 mW; spectral slit width, 10 cm−1; scan speed, 1 cm−1/sec.

Excitation wavelength, nmSensitivityTime constant, sec
A647.1 Kr+4000 cps2
B514.5 Ar+4000 cps2
C457.9 Ar+4000 cps2
D406.7 Kr+LHS, 1 μA; RHS, 3 nA4.4
E351 Kr+LHS, 1 μA; RHS, 3 nA4.4

Tables (1)

Tables Icon

Table I Measured and Calculated Raman Enhancements

Metrics