Simple Model of a Line Selected, Long Chain, Pulsed DF-CO<sub>2</sub> Chemical Transfer Laser

R. L. Kerber

doi:10.1364/AO.12.001157

Applied Optics
Vol. 12,
Issue 6,
pp. 1157-1164
(1973)
•https://doi.org/10.1364/AO.12.001157

Simple Model of a Line Selected, Long Chain, Pulsed DF-CO₂ Chemical Transfer Laser

R. L. Kerber

Not Accessible

Your library or personal account may give you access

Get PDF
Email
Share
Get Citation
Copy Citation Text
R. L. Kerber, "Simple Model of a Line Selected, Long Chain, Pulsed DF-CO₂ Chemical Transfer Laser," Appl. Opt. 12, 1157-1164 (1973)

Export Citation
- BibTex
- Endnote (RIS)
- HTML
- Plain Text
Citation alert
Save article

Abstract

A rate equation model of a pulsed DF-CO₂ chemical transfer laser is Simplified by investigating the relationship of kinetic mechanisms. The model reduces to one equation which when Solved permits calculation of all pulse characteristics as a function of time. At low levels of initiation, predictions of this laser simulation model are in excellent agreement with those of a more comprehensive model presented in an earlier paper. Model predictions are also found to be consistent with experiment. The simplicity of the present model lends itself to easy physical interpretation and permits efficient and accurate prediction of transfer laser performance characteristics in regimes of practical interest.

Full Article | PDF Article

More Like This

Chain reaction pulsed HF laser: a simple model

R. L. Kerber and J. S. Whittier
Appl. Opt. 15(10) 2358-2366 (1976)

Transfer chemical laser: modeling of a cw DF–CO₂ laser

S. W. Zelazny, J. A. Blauer, L. Wood, L. H. Sentman, and W. C. Solomon
Appl. Opt. 15(5) 1164-1171 (1976)

Kinetic Model and Computer Simulation of Continuous Wave DF-CO₂ Chemical Transfer Lasers

W. Baumann, J. A. Blauer, S. W. Zelazny, and W. C. Solomon
Appl. Opt. 13(12) 2823-2834 (1974)

Previous Article Next Article

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Figures (3)

You do not have subscription access to this journal. Figure files are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Tables (2)

You do not have subscription access to this journal. Article tables are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Equations (53)

You do not have subscription access to this journal. Equations are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

React.	Reaction^a	Rate coefficient^b
1^c	F₂ + M₁ ⇌ F + F + M₁	k₁ = 5.0 × 10¹³e^35.3^θ
2	D₂(0) + M₂ ⇌ D + D + M₂	k₋₂ = 10¹⁸T^−1.0
3_v	DF(v) + M₁ ⇌ D + F + M₁	k₃_v = 1.2 × 10¹⁸T^−1.0e^{(137.13 −E_v)θ}	v = 0, …, 9
4a	F + D₂(0) ⇌ DF(1) + D	k₄_a = 6.54 × 10¹²e^1.46^θ
4b	F + D₂(0) ⇌ DF(2) + D	k₄_b = 1.52 × 10¹³e^1.46^θ
4c	F + D₂(0) ⇌ DF(3) + D	k₄_c = 2.34 × 10¹³e^1.46^θ
4d	F + D₂(0) ⇌ DF(4) + D	k₄_d = 1.66 × 10¹³e^1.46^θ
4e	F + D₂(0) ⇌ DF(5) + D	k₋₄_e = 4.0 × 10¹²T^0.15e³^θ
4f_v	F + D₂(0) ⇌ DF(v) + D	k₋₄_fv = 1.2 × 10¹³T^0.15	v = 6, …, 9
5a	D + F₂ ⇌ DF(1) + F	k₅_a = 2.61 × 10¹²e^2.4^θ
5b	D + F₂ ⇌ DF(2) + F	k₅_b = 3.26 × 10¹²e^2.4^θ
5c	D + F₂ ⇌ DF(3) + F	k₅_c = 3.82 × 10¹²e^2.4^θ
5d	D + F₂ ⇌ DF(4) + F	k₅_d = 4.0 × 10¹²e^2.4^θ
5e	D + F₂ ⇌ DF(5) + F	k₅_e = 1.04 × 10¹³e^2.4^θ
5f	D + F₂ ⇌ DF(6) + F	k₅_f = 2.48 × 10¹³e^2.4^θ
5g	D + F₂ ⇌ DF(7) + F	k₅_g = 3.98 × 10¹³e^2.4^θ
5h	D + F₂ ⇌ DF(8) + F	k₅_h = 5.02 × 10¹³e^2.4^θ
5i	D + F₂ ⇌ DF(9) + F	k₅_i = 3.52 × 10¹³e^2.4^θ
6a_v	DF(v) + M₃ ⇌ DF(v − 1) + M₃	k_{6a_v} = 4.0 × 10³vT^2.2	v = 1, …, 9
6b_v	DF(v) + M₄ ⇌ DF(v − 1) + M₄	k_{6b_v} = 3.7 × 10⁻⁶vT^4.66	v = 1, …, 9
6c_v	DF(v) + M₅ ⇌ DF(v − 1) + M₅	k_{6c_v} = 2.44 × 10⁻¹¹vT^6.71e^−8.884^θ	v = 1, …, 9
6d_v	DF(v) + M₆ ⇌ DF(v − 1) + M₆	k_{6d_v} = 0.14vT^3.66	v = 1, …, 9
6e₁	DF(1) + M₇ ⇌ DF(0) + M₇	k₆_e_₁ = 5.0 × 10¹²e^1.25^θ
6e₂	DF(2) + M₇ ⇌ DF(1) + M₇	k₆_e_₂ = 5.0 × 10¹²e^0.55^θ
6e_v	DF(v) + M₇ ⇌ DF(v − 1) + M₇	k_{6e_v} = 5.0 × 10¹²	v = 3, …, 9
7a_v	DF(v) + DF(v) ⇌ DF(v − 1) + DF(v + 1)	k_{7a_v} = 1.25 × 10¹²T^0.5	v = 1, …, 8
7b_v	DF(v) + DF(v + 1) ⇌ DF(v − 1) + DF(v + 2)	k_{7b_v} = 6.12 × 10¹¹T^0.5	v = 1, …, 7
7c_v	DF(v) + DF(v + 2) ⇌ DF(v − 1) + DF(v + 3)	k_{7c_v} = 3.06 × 10¹¹T^0.5	v = 1, …, 6
8a	DF(1) + D₂(0) ⇌ DF(0) + D₂(1)	k₋₈_a = 6.3 × 10¹¹
8b	DF(2) + D₂(0) ⇌ DF(1) + D₂(1)	k₋₈_b = 6.3 × 10¹¹
8c	DF(3) + D₂(0) ⇌ DF(2) + D₂(1)	k₋₈_c = 6.3 × 10¹¹
8d	DF(1) + D₂(0) ⇌ DF(0) + D₂(2)	k₋₈_d = 6.3 × 10¹¹
8e	DF(2) + D₂(1) ⇌ DF(1) + D₂(2)	k₋₈_e = 6.3 × 10¹¹
9_v	D₂(v) + M₈ ⇌ D₂(v − 1) + M₈	k₉_v = 1.51 × 10⁻⁵vT^4.6
10_v^d	DF(v) + CO₂(00⁰0) ⇌ DF(v − 1) + CO₂(00⁰1)	k₁₀_v = 9.2 × 10¹⁴vT^−1.0	v = 1, …, 9
11	CO₂(00⁰1) + CO₂(00⁰0) ⇌ CO₂(10⁰0) + CO₂(01¹0)	k₁₁ = 3.4 × 10¹T^2.5e^0.39^θ
12⁰	CO₂(00⁰1) + CO₂(00⁰0) ⇌ CO₂(02⁰0) + CO₂(01¹0)	k₁₂⁰ = 1.2 × 10¹T^2.5e^θ
13	CO₂(11¹0) + CO₂(00⁰0) ⇌ CO₂(10⁰0) + CO₂(01¹0)	k₁₃ = 7.5 × 10¹⁰T^0.5
14	CO₂(030) + CO₂(00⁰0) ⇌ CO₂(10¹0) + CO₂(01¹0)	k₁₄ = 1.1 × 10⁹T^0.5
15⁰	CO₂(030) + CO₂(00⁰0) ⇌ CO₂(02⁰0) + CO₂(01¹0)	k₁₅⁰ = 1.1 × 10¹¹T^0.5
15²	CO₂(030) + CO₂(00⁰0) ⇌ CO₂(02²0) + CO₂(01¹0)	k₁₅² = 2.25 × 10¹¹T^0.5
16	CO₂(10⁰0) + CO₂(00⁰0) ⇌ CO₂(01¹0) + CO₂(01¹0)	k₁₆ = 1.5 × 10¹¹T^0.5
17⁰	CO₂(02⁰0) + CO₂(00⁰0) ⇌ CO₂(01¹0) + CO₂(01¹0)	k₁₇⁰ = 1.5 × 10¹¹T^0.5
17²	CO₂(02²0) + CO₂(00⁰0) ⇌ CO₂(01¹0) + CO₂(01¹0)	k₁₇² = 1.2 × 10¹²T^0.5
18a	CO₂(00⁰1) + M₃ ⇌ CO₂(11¹0) + M₃	k₁₈_a = 8.85 × 10⁻⁴T^4.75e^−1.484^θ
18b	CO₂(00⁰1) + M₉ ⇌ CO₂(11¹0) + M₉	k₁₈_b = 1.13 × 10⁻⁷T^5.8e^−2.436^θ
18c	CO₂(00⁰1) + M₁₀ ⇌ CO₂(11¹0) + M₁₀	k₁₈_c = 6.4 × 10⁷T^1.5
18d	CO₂(00⁰1) + M₅ ⇌ CO₂(11¹0) + M₅	k₁₈_d = 1.45 × 10¹⁴T^−1.0
19a	CO₂(00⁰1) + M₃ ⇌ CO₂(030) + M₃	k₁₉_a = 6.8 × 10⁻⁷T^5.55e^−1.484^θ
19b	CO₂(00⁰1) + M₉ ⇌ CO₂(030) + M₉	k₁₉_b = 8.7 × 10⁻¹¹T^6.6e^−2.436^θ
19c	CO₂(00⁰1) + M₁₀ ⇌ CO₂(030) + M₁₀	k₁₉_c = 4.9 × 10⁴T^2.3
19d	CO₂(00⁰1) + M₅ ⇌ CO₂(030) + M₅	k₁₉_d = 1.1 × 10¹¹T^−0.2
20	CO₂(11¹0) + M₁₁ ⇌ CO₂(030) + M₁₁	k₂₀ = 2.6 × 10⁷T^1.5
21⁰	CO₂(11¹0) + M₁₁ ⇌ CO₂(02⁰0) + M₁₁	k₂₁⁰ = 8.6 × 10⁻³T^4.19e^0.903^θ
21²	CO₂(11¹0) + M₁₁ ⇌ CO₂(02²0) + M₁₁	k₂₁² = 7.9 × 10⁴T^2.5e^4.41^θ
22	CO₂(11¹0) + M₁₁ ⇌ CO₂(10⁰0) + M₁₁	k₂₂ = 5.9T^3.78e^0.549^θ
23⁰	CO₂(030) + M₁₁ ⇌ CO₂(02⁰0) + M₁₁	k₂₃⁰ = 3.87 × 10²T^3.3e^1.24^θ
23²	CO₂(030) + M₁₁ ⇌ CO₂(02²0) + M₁₁	k₂₃² = 5.7 × 10²T^3.32e^1.22^θ
24	CO₂(030) + M₁₁ ⇌ CO₂(10⁰0) + M₁₁	k₂₄ = 4.9 × 10²T^3.04e^1.06^θ
25⁰	CO₂(10⁰0) + M₁₁ ⇌ CO₂(02⁰0) + M₁₁	k₂₅⁰ = 2.6 × 10⁸T^1.5
25²	CO₂(10⁰0) + M₁₁ ⇌ CO₂(02²0) + M₁₁	k₂₅² = 5.8 × 10⁸T^1.5
26a	CO₂(10⁰0) + M₁₂ ⇌ CO₂(01¹0) + M₁₂	k₂₆_a = 4.4 × 10²T^3.26e^1.48^θ
26b	CO₂(10⁰0) + M₁₃ ⇌ CO₂(01¹0) + M₁₃	k₂₆_b = 1.5 × 10³T^2.95e^−0.8433^θ
26c	CO₂(10⁰0) + M₁₄ ⇌ CO₂(01¹0) + M₁₄	k₂₆_c = 1.65 × 10¹⁴T^−1.0
27	CO₂(02²0) + M₁₁ ⇌ CO₂(02⁰0) + M₁₁	k₋₂₇ = 5.9 × 10⁸T^1.5
28a⁰	CO₂(02⁰0) + M₁₂ ⇌ CO₂(01¹0) + M₁₂	k₂₈_a⁰ = 2.4 × 10³T^3.1e^1.4^θ
28b⁰	CO₂(02⁰0) + M₁₃ ⇌ CO₂(01¹0) + M₁₃	k₂₈_b⁰ = 2.8 × 10¹³T^2.95e^−0.8433^θ
28c⁰	CO₂(02⁰0) + M₁₄ ⇌ CO₂(01¹0) + M₁₄	k₂₈_c⁰ = 3.13 × 10¹⁴T^−1.0
28_a²	CO₂(02²0) + M₁₂ ⇌ CO₂(01¹0) + M₁₂	k₂₈_a² = 6.0 × 10²T^3.31e^1.3^θ
28b²	CO₂(02²0) + M₁₃ ⇌ CO₂(01¹0) + M₁₃	k₂₈_b² = 3.3 × 10³T^2.95e^−0.8433^θ
28c²	CO₂(02²0) + M₁₄ ⇌ CO₂(01¹0) + M₁₄	k₂₈_c² = 3.68 × 10¹⁴T^−1.0
29a	CO₂(01¹0) + M₁₂ ⇌ CO₂(00⁰0) + M₁₂	k₂₉_a = 2.17 × 10⁻²T^4.19e^−1.132^θ
29b	CO₂(01¹0) + M₁₃ ⇌ CO₂(00⁰0) + M₁₃	k₂₉_b = 8.27 × 10²T^2.95e^−0.8433^θ
29c	CO₂(01¹0) + M₁₄ ⇌ CO₂(00⁰0) + M₁₄	k₂₉_c = 9.2 × 10¹³T^−1.0

	I_{0_max} (kW)	E (j/1-atm)	t_c (a sec)
Simple model	160	26.5	17.3
Experiment4	165	~34	~17.3

React.	Reaction^a	Rate coefficient^b
1^c	F₂ + M₁ ⇌ F + F + M₁	k₁ = 5.0 × 10¹³e^35.3^θ
2	D₂(0) + M₂ ⇌ D + D + M₂	k₋₂ = 10¹⁸T^−1.0
3_v	DF(v) + M₁ ⇌ D + F + M₁	k₃_v = 1.2 × 10¹⁸T^−1.0e^{(137.13 −E_v)θ}	v = 0, …, 9
4a	F + D₂(0) ⇌ DF(1) + D	k₄_a = 6.54 × 10¹²e^1.46^θ
4b	F + D₂(0) ⇌ DF(2) + D	k₄_b = 1.52 × 10¹³e^1.46^θ
4c	F + D₂(0) ⇌ DF(3) + D	k₄_c = 2.34 × 10¹³e^1.46^θ
4d	F + D₂(0) ⇌ DF(4) + D	k₄_d = 1.66 × 10¹³e^1.46^θ
4e	F + D₂(0) ⇌ DF(5) + D	k₋₄_e = 4.0 × 10¹²T^0.15e³^θ
4f_v	F + D₂(0) ⇌ DF(v) + D	k₋₄_fv = 1.2 × 10¹³T^0.15	v = 6, …, 9
5a	D + F₂ ⇌ DF(1) + F	k₅_a = 2.61 × 10¹²e^2.4^θ
5b	D + F₂ ⇌ DF(2) + F	k₅_b = 3.26 × 10¹²e^2.4^θ
5c	D + F₂ ⇌ DF(3) + F	k₅_c = 3.82 × 10¹²e^2.4^θ
5d	D + F₂ ⇌ DF(4) + F	k₅_d = 4.0 × 10¹²e^2.4^θ
5e	D + F₂ ⇌ DF(5) + F	k₅_e = 1.04 × 10¹³e^2.4^θ
5f	D + F₂ ⇌ DF(6) + F	k₅_f = 2.48 × 10¹³e^2.4^θ
5g	D + F₂ ⇌ DF(7) + F	k₅_g = 3.98 × 10¹³e^2.4^θ
5h	D + F₂ ⇌ DF(8) + F	k₅_h = 5.02 × 10¹³e^2.4^θ
5i	D + F₂ ⇌ DF(9) + F	k₅_i = 3.52 × 10¹³e^2.4^θ
6a_v	DF(v) + M₃ ⇌ DF(v − 1) + M₃	k_{6a_v} = 4.0 × 10³vT^2.2	v = 1, …, 9
6b_v	DF(v) + M₄ ⇌ DF(v − 1) + M₄	k_{6b_v} = 3.7 × 10⁻⁶vT^4.66	v = 1, …, 9
6c_v	DF(v) + M₅ ⇌ DF(v − 1) + M₅	k_{6c_v} = 2.44 × 10⁻¹¹vT^6.71e^−8.884^θ	v = 1, …, 9
6d_v	DF(v) + M₆ ⇌ DF(v − 1) + M₆	k_{6d_v} = 0.14vT^3.66	v = 1, …, 9
6e₁	DF(1) + M₇ ⇌ DF(0) + M₇	k₆_e_₁ = 5.0 × 10¹²e^1.25^θ
6e₂	DF(2) + M₇ ⇌ DF(1) + M₇	k₆_e_₂ = 5.0 × 10¹²e^0.55^θ
6e_v	DF(v) + M₇ ⇌ DF(v − 1) + M₇	k_{6e_v} = 5.0 × 10¹²	v = 3, …, 9
7a_v	DF(v) + DF(v) ⇌ DF(v − 1) + DF(v + 1)	k_{7a_v} = 1.25 × 10¹²T^0.5	v = 1, …, 8
7b_v	DF(v) + DF(v + 1) ⇌ DF(v − 1) + DF(v + 2)	k_{7b_v} = 6.12 × 10¹¹T^0.5	v = 1, …, 7
7c_v	DF(v) + DF(v + 2) ⇌ DF(v − 1) + DF(v + 3)	k_{7c_v} = 3.06 × 10¹¹T^0.5	v = 1, …, 6
8a	DF(1) + D₂(0) ⇌ DF(0) + D₂(1)	k₋₈_a = 6.3 × 10¹¹
8b	DF(2) + D₂(0) ⇌ DF(1) + D₂(1)	k₋₈_b = 6.3 × 10¹¹
8c	DF(3) + D₂(0) ⇌ DF(2) + D₂(1)	k₋₈_c = 6.3 × 10¹¹
8d	DF(1) + D₂(0) ⇌ DF(0) + D₂(2)	k₋₈_d = 6.3 × 10¹¹
8e	DF(2) + D₂(1) ⇌ DF(1) + D₂(2)	k₋₈_e = 6.3 × 10¹¹
9_v	D₂(v) + M₈ ⇌ D₂(v − 1) + M₈	k₉_v = 1.51 × 10⁻⁵vT^4.6
10_v^d	DF(v) + CO₂(00⁰0) ⇌ DF(v − 1) + CO₂(00⁰1)	k₁₀_v = 9.2 × 10¹⁴vT^−1.0	v = 1, …, 9
11	CO₂(00⁰1) + CO₂(00⁰0) ⇌ CO₂(10⁰0) + CO₂(01¹0)	k₁₁ = 3.4 × 10¹T^2.5e^0.39^θ
12⁰	CO₂(00⁰1) + CO₂(00⁰0) ⇌ CO₂(02⁰0) + CO₂(01¹0)	k₁₂⁰ = 1.2 × 10¹T^2.5e^θ
13	CO₂(11¹0) + CO₂(00⁰0) ⇌ CO₂(10⁰0) + CO₂(01¹0)	k₁₃ = 7.5 × 10¹⁰T^0.5
14	CO₂(030) + CO₂(00⁰0) ⇌ CO₂(10¹0) + CO₂(01¹0)	k₁₄ = 1.1 × 10⁹T^0.5
15⁰	CO₂(030) + CO₂(00⁰0) ⇌ CO₂(02⁰0) + CO₂(01¹0)	k₁₅⁰ = 1.1 × 10¹¹T^0.5
15²	CO₂(030) + CO₂(00⁰0) ⇌ CO₂(02²0) + CO₂(01¹0)	k₁₅² = 2.25 × 10¹¹T^0.5
16	CO₂(10⁰0) + CO₂(00⁰0) ⇌ CO₂(01¹0) + CO₂(01¹0)	k₁₆ = 1.5 × 10¹¹T^0.5
17⁰	CO₂(02⁰0) + CO₂(00⁰0) ⇌ CO₂(01¹0) + CO₂(01¹0)	k₁₇⁰ = 1.5 × 10¹¹T^0.5
17²	CO₂(02²0) + CO₂(00⁰0) ⇌ CO₂(01¹0) + CO₂(01¹0)	k₁₇² = 1.2 × 10¹²T^0.5
18a	CO₂(00⁰1) + M₃ ⇌ CO₂(11¹0) + M₃	k₁₈_a = 8.85 × 10⁻⁴T^4.75e^−1.484^θ
18b	CO₂(00⁰1) + M₉ ⇌ CO₂(11¹0) + M₉	k₁₈_b = 1.13 × 10⁻⁷T^5.8e^−2.436^θ
18c	CO₂(00⁰1) + M₁₀ ⇌ CO₂(11¹0) + M₁₀	k₁₈_c = 6.4 × 10⁷T^1.5
18d	CO₂(00⁰1) + M₅ ⇌ CO₂(11¹0) + M₅	k₁₈_d = 1.45 × 10¹⁴T^−1.0
19a	CO₂(00⁰1) + M₃ ⇌ CO₂(030) + M₃	k₁₉_a = 6.8 × 10⁻⁷T^5.55e^−1.484^θ
19b	CO₂(00⁰1) + M₉ ⇌ CO₂(030) + M₉	k₁₉_b = 8.7 × 10⁻¹¹T^6.6e^−2.436^θ
19c	CO₂(00⁰1) + M₁₀ ⇌ CO₂(030) + M₁₀	k₁₉_c = 4.9 × 10⁴T^2.3
19d	CO₂(00⁰1) + M₅ ⇌ CO₂(030) + M₅	k₁₉_d = 1.1 × 10¹¹T^−0.2
20	CO₂(11¹0) + M₁₁ ⇌ CO₂(030) + M₁₁	k₂₀ = 2.6 × 10⁷T^1.5
21⁰	CO₂(11¹0) + M₁₁ ⇌ CO₂(02⁰0) + M₁₁	k₂₁⁰ = 8.6 × 10⁻³T^4.19e^0.903^θ
21²	CO₂(11¹0) + M₁₁ ⇌ CO₂(02²0) + M₁₁	k₂₁² = 7.9 × 10⁴T^2.5e^4.41^θ
22	CO₂(11¹0) + M₁₁ ⇌ CO₂(10⁰0) + M₁₁	k₂₂ = 5.9T^3.78e^0.549^θ
23⁰	CO₂(030) + M₁₁ ⇌ CO₂(02⁰0) + M₁₁	k₂₃⁰ = 3.87 × 10²T^3.3e^1.24^θ
23²	CO₂(030) + M₁₁ ⇌ CO₂(02²0) + M₁₁	k₂₃² = 5.7 × 10²T^3.32e^1.22^θ
24	CO₂(030) + M₁₁ ⇌ CO₂(10⁰0) + M₁₁	k₂₄ = 4.9 × 10²T^3.04e^1.06^θ
25⁰	CO₂(10⁰0) + M₁₁ ⇌ CO₂(02⁰0) + M₁₁	k₂₅⁰ = 2.6 × 10⁸T^1.5
25²	CO₂(10⁰0) + M₁₁ ⇌ CO₂(02²0) + M₁₁	k₂₅² = 5.8 × 10⁸T^1.5
26a	CO₂(10⁰0) + M₁₂ ⇌ CO₂(01¹0) + M₁₂	k₂₆_a = 4.4 × 10²T^3.26e^1.48^θ
26b	CO₂(10⁰0) + M₁₃ ⇌ CO₂(01¹0) + M₁₃	k₂₆_b = 1.5 × 10³T^2.95e^−0.8433^θ
26c	CO₂(10⁰0) + M₁₄ ⇌ CO₂(01¹0) + M₁₄	k₂₆_c = 1.65 × 10¹⁴T^−1.0
27	CO₂(02²0) + M₁₁ ⇌ CO₂(02⁰0) + M₁₁	k₋₂₇ = 5.9 × 10⁸T^1.5
28a⁰	CO₂(02⁰0) + M₁₂ ⇌ CO₂(01¹0) + M₁₂	k₂₈_a⁰ = 2.4 × 10³T^3.1e^1.4^θ
28b⁰	CO₂(02⁰0) + M₁₃ ⇌ CO₂(01¹0) + M₁₃	k₂₈_b⁰ = 2.8 × 10¹³T^2.95e^−0.8433^θ
28c⁰	CO₂(02⁰0) + M₁₄ ⇌ CO₂(01¹0) + M₁₄	k₂₈_c⁰ = 3.13 × 10¹⁴T^−1.0
28_a²	CO₂(02²0) + M₁₂ ⇌ CO₂(01¹0) + M₁₂	k₂₈_a² = 6.0 × 10²T^3.31e^1.3^θ
28b²	CO₂(02²0) + M₁₃ ⇌ CO₂(01¹0) + M₁₃	k₂₈_b² = 3.3 × 10³T^2.95e^−0.8433^θ
28c²	CO₂(02²0) + M₁₄ ⇌ CO₂(01¹0) + M₁₄	k₂₈_c² = 3.68 × 10¹⁴T^−1.0
29a	CO₂(01¹0) + M₁₂ ⇌ CO₂(00⁰0) + M₁₂	k₂₉_a = 2.17 × 10⁻²T^4.19e^−1.132^θ
29b	CO₂(01¹0) + M₁₃ ⇌ CO₂(00⁰0) + M₁₃	k₂₉_b = 8.27 × 10²T^2.95e^−0.8433^θ
29c	CO₂(01¹0) + M₁₄ ⇌ CO₂(00⁰0) + M₁₄	k₂₉_c = 9.2 × 10¹³T^−1.0

	I_{0_max} (kW)	E (j/1-atm)	t_c (a sec)
Simple model	160	26.5	17.3
Experiment4	165	~34	~17.3

Abstract

Cited By

Figures (3)

Tables (2)

Equations (53)

Applied Optics