The absorption spectrum of fluorine F i observed with the helium continuum

H. P. Palenius; R. E. Huffman; J. C. Larrabee; Y. Tanaka

doi:10.1364/JOSA.68.001564

Journal of the Optical Society of America
Vol. 68,
Issue 11,
pp. 1564-1574
(1978)
•https://doi.org/10.1364/JOSA.68.001564

The absorption spectrum of fluorine F i observed with the helium continuum

H. P. Palenius, R. E. Huffman, J. C. Larrabee, and Y. Tanaka

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H. P. Palenius, R. E. Huffman, J. C. Larrabee, and Y. Tanaka, "The absorption spectrum of fluorine F i observed with the helium continuum," J. Opt. Soc. Am. 68, 1564-1574 (1978)

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Abstract

Absorption series of ground-state atomic fluorine, 2p^{5 2}P_3/2,1/2, have been observed in the 730–620 Å wavelength region with the helium continuum. These series have been identified with n s and n d Rydberg series converging to the four lowest states of F ii, 2p^{4 3}P_2,1,0 and 2p^{4 1}D₂. Fourteen new F i lines observed in emission in the wavelength region 9519–5166 Å are also reported. As a result of these observations, more than a hundred new F i energy levels have been established. In addition, six new O i absorption lines are given.

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I (Intensity)	λ_obs, Å	σ, cm⁻¹	n	n*
^a	728.74	137 223	7	5.765 4
4	723.957	138 129.8	8	6.769 3
4	720.943	138 707.2	9	7.770 8
5	718.907	139 100.1	10	8.777 1
2	717.493	139 374.2	11	9.767 1
3^b	716.442	139 578.6	12	10.77 1
1	715.652	139 732.7	13	11.77 3
3^c	715.042	139 851.9	14	12.77 3
3	714.555	139 947.2	15	13.78 8
1	714.166	140 023.5	16	14.80
0	713.850	140 085.5	17	15.81
1	713.590	140 136.5	18	16.82

I	λ_obs, Å	σ, cm⁻¹	upper level	n*
0	727.125	137 527.9	7s[1]_3/2	5.734 0
0	727.027	137 546.5	7s[1]_1/2	5.750 0
2	722.303	138 446.1	8s[1]_3/2	6.734 7
2	722.215	138 463.0	8s[1]_1/2	6.758 4
1	719.265	139 030.8	9s[1]_3/2	7.733 8

I	λ_obs, Å	σ, cm⁻¹	n	n*
0	726.265	137 690.8	7	5.746 1
1	721.492	138 601.7	8	6.744 1
1	718.473	139 184.1	9	7.743 0
3^a	716.442	139 578.6	10	8.742
3^b	715.042	139 851.9	11	9.734
3	713.968	140 062.3	12	10.735 8
5^c	713.164	140 220.2	13	11.755
2	712.574	140 336.3	14	12.721
1	712.083	140 433.1	15	13.739

I	λ_obs, Å	σ, cm⁻¹	J^a	n	E_av, cm⁻¹	n*
58	681.831	146 663.9	3/2	4	146 663.7	2.729 05
36	683.717	146 259.3	1/2	4	146 663.7	2.729 05
32	651.344	153 528.7	3/2	5	153 528.6	3.734 28
15	633.065	153 124.1	1/2	5	153 528.6	3.734 28
13	638.951	156 506.5	3/2	6	156 506.5	4.736 51
7	640.605	156 102.4	1/2	6	156 506.5	4.736 51
6	632.650	158 065.3	3/2	7	158 064.9	5.737 96
3	634.275	157 660.3	1/2	7	158 064.9	5.737 96
3	629.005	158 981.2	3/2	8	158 981.7	6.739 20
1	630.604	158 578.1	1/2	8	158 981.7	6.739 20
2	626.707	159 564.2	3/2	9	159 564.5	7.736 5
1	628.295	159 160.8	1/2	9	159 564.5	7.736 5
2	625.156	159 960.1	3/2	10	159 960.1	8.736 2
2	624.056	160 242.0	3/2	11	160 242.0	9.743 5
2	623.256	160 447.7	3/2	12	160 447.7	10.746 6
1	622.655	160 602.7	3/2	13	160 602.7	11.747 3
0	622.191	160 722.4	3/2	14	160 722.4	12.745

I	λ_obs, Å	σ, cm⁻¹	n	n*
2^a	727.54	137 449	6	5.973 8
4	723.212	138 272.0	7	6.979 8
9	720.447	138 802.7	8	7.983 4
4^a	718.57	139 165	9	8.985 3
13	717.236	139 424.1	10	9.986 3
11	716.251	139 615.9	11	10.989 5
14^b	715.503	139 761.8	12	11.995
7	714.928	139 874.2	13	12.991
2	714.474	139 963.1	14	13.981
7	714.104	140 035.6	15	14.982
5	713.803	140 094.7	16	15.978
2	713.548	140 144.7	17	16.999
4	713.341	140 185.4	18	17.989
5^c	713.164	140 220.2	19	18.99
3^d	713.007	140 251.1	20	20.03
2	712.877	140 276.7	21	21.04
1	712.768	140 298.1	22	22.02

I	λ_obs, Å	σ, cm⁻¹	J^a	n	E, cm⁻¹	n*
1	723.171	138 279.9	3/2	7	138 279.9	6.992 06
0	725.290	137 875.8	1/2	7	138 279.9	6.992 06
2	722.506	138 407.2	1/2	8	138 811.3	8.003 3
3	720.621	138 769.1	1/2	9	139 173.2	9.011 5
1	719.315	139 021.2	1/2	10	139 425.3	9.991 4

I	λ_obs, Å	σ, cm⁻¹	J^a	n	E_av, cm⁻¹	n*
8	721.435	138 612.6	3/2	7	138 612.4	6.978 86
1	723.547	138 208.0	1/2	7	138 612.4	6.978 86
6	718.686	139 142.8	3/2	8	139 142.3	7.980 08
2	720.785	138 737.7	1/2	8	139 142.3	7.980 08
5	716.818	139 505.4	3/2	9	139 505.4	8.982 4
m	718.907		1/2	9	139 505.4	8.982 4
14^b	715.503	139 761.8	3/2	10	139 762.6	9.974 9
2	717.574	139 368.5	1/2	10	139 762.6	9.974 9
8	714.519	139 954.3	3/2	11	139 954.5	10.975 3
2	716.586	139 550.7	1/2	11	139 954.5	10.975 3
5	713.771	140 101.0	3/2	12	140 101.0	11.980 5
2^c	715.827	139 698.6	1/2	12	140 101.0	11.980 5
3	713.191	140 215.0	3/2	13	140 215.2	12.990 3
1	715.250	139 811.3	1/2	13	140 215.2	12.990 3
2	712.740	140 303.6	3/2	14	140 303.8	13.977
1	714.797	139 899.9	1/2	14	140 303.8	13.977
1	712.362	140 378.1	3/2	15	140 377.4	14.994
0	714.426	139 972.5	1/2	15	140 377.4	14.994
1	712.078	140 434.0	3/2	16	140 433.8	15.944
1	714.136	140 029.4	1/2	16	140 433.8	15.944
1	711.816	140 485.7	3/2	17	140 485.7	16.999

I	λ_obs, Å	σ, cm⁻¹	J^a	n	E, cm⁻¹	n*
2	720.668	138 760.1	3/2	7	138 761.6	6.979 33
2	722.758	138 359.0	1/2	7	138 761.6	6.979 33
2	717.920	139 291.3	3/2	8	139 290.8	7.979 15
2	720.015	138 886.1	1/2	8	139 290.8	7.979 15
3	716.064	139 652.3	3/2	9	139 652.8	8.977 4
2	718.137	139 249.3	1/2	9	139 652.8	8.977 4
3	714.735	139 912.0	3/2	10	139 911.6	9.975 3
2	716.809	139 507.1	1/2	10	139 911.6	9.975 3
2	713.756	140 103.9	3/2	11	140 103.9	10.978 3
2^b	715.827	139 698.6	1/2	11	140 103.9	10.978 3
3^c	713.007	140 251.1	3/2	12	140 251.1	11.990
2	715.067	139 847.0	1/2	12	140 251.1	11.990
1	712.432	140 364.3	3/2	13	140 364.5	12.994
2	714.487	139 960.6	1/2	13	140 364.5	12.994
1	711.956	149 458.1	3/2	14	140 458.0	14.04
2	714.012	140 053.7	1/2	14	140 458.0	14.04
1	711.599	140 528.6	3/2	15	140 529.2	15.04
1	713.645	140 125.6	1/2	15	140 529.2	15.04
0	711.302	140 587.2	3/2	16	140 587.2	16.03

I	λ_obs, Å	σ, cm⁻¹	J^a	n	E_av, cm⁻¹	n*
36	670.571	149 126.6	3/2	3	149 126.7	2.990 41
15	672.392	148 722.8	1/2	3	149 126.7	2.990 41
20	647.264	154 496.5	3/2	4	154 496.6	3.987 58
8	648.960	154 092.7	1/2	4	154 496.6	3.987 58
8	637.008	156 983.9	3/2	5	156 985.3	4.986 86
3	638.640	156 582.7	1/2	5	156 985.3	4.986 86
3	631.572	158 335.5	3/2	6	158 335.2	5.985 81
2	633.189	157 930.7	1/2	6	158 335.2	5.985 81
2	628.338	159 150.0	3/2	7	159 150.0	6.986 9
0	629.938	158 745.9	1/2	7	159 150.0	6.986 9
1	626.257	159 678.9	3/2	8	159 678.9	7.989 8

I	λ_obs, Å	σ, cm⁻¹	J^a	n	E_av, cm⁻¹	n*
50	671.413	148 939.6	3/2	3	148 939.7	2.967 89
24	673.239	148 535.7	1/2	3	148 939.7	2.967 89
22	647.592	154 418.2	3/2	4	154 419.0	3.965 35
10	649.284	154 015.8	1/2	4	154 419.0	3.965 35
12	637.160	156 946.4	3/2	5	156 946.2.	4.964 92
4	638.807	156 541.8	1/2	5	156 946.2.	4.964 92
5	631.660	158 313.4	3/2	6	158 313.6	5.964 81
3	633.273	157 909.8	1/2	6	158 313.6	5.964 81
3	628.393	159 136.1	3/2	7	159 136.1	6.965 40
2	629.993	158 731.9	1/2	7	159 136.1	6.965 40
2	626.286	159 671.5	3/2	8	159 671.4	7.972 45
1	627.876	159 267.1	1/2	8	159 671.4	7.972 45
2^b	624.853	160 037.6	3/2	9	160 036.8	8.979 0
1	626.445	159 630.9	1/2	9	160 036.8	8.979 0
2	623.852	160 294.4	3/2	10	160 294.5	9.972 6
0	625.428	159 890.6	1/2	10	160 294.5	9.972 6
1	623.102	160 487.4	3/2	11	160 487.4	10.978 3
1	622.536	160 633.3	3/2	12	160 633.3	11.979 9
0	622.107	160 744.1	3/2	13	160 744.1	12.955

I	λ_obs, Å	σ, cm⁻¹	J^a	n	E_av, cm⁻¹	n*
4	670.315	149 183.6	3/2	3	149 183.6	2.997 34
3^b	672.132	148 780.3	1/2	3	149 183.6	2.997 34
3	648.212	154 270.5	3/2	4	154 270.5	3.923 79
1	649.914	153 866.5	1/2	4	154 270.5	3.923 79
1	637.555	156 849.2	3/2	5	156 849.2	4.911 7
0	639.202	156 445.1	1/2	5	156 849.2	4.911 7
1	632.062	158 212.3	3/2	6?	158 212.3	5.869 2

I	λ_obs, Å	λ_Lidén	σ, cm⁻¹	Identification
2	9518.11		10 503.41	2p⁴(¹D)3p [2]_5/2 –	2p(¹D)3d [3]_1/2
1	9511.15		10 511.09	[2]_3/2 –	[3]_5/2
2	8820.39		11 334.26	[1]_3/2 –	[1]_3/2
1	8806.69		11 351.89	[1]_1/2 –	[1]_1/2
0	8664.05		11 538.78	[1]_1/2 –	[2]_3/2
1	8634.60		11 518.13	[1]_1/2 –	[0]_1/2
1	8621.38		11 595.89	[1]_1/2 –	[0]_1/2
4	8612.64	0.58	11 607.65	[3]_7/2 –	[3]_7/2
3	8606.03	0.06	11 616.57	[3]_5/2 –	[3]_5/2
1^a	7315.07		13 666.64	3s [2]_3/2 –	3p [1]_1/2
1	7305.15		13 685.20	[2]_5/2 –	[1]_3/2
1	5903.50		16 934.41	3p [3]_7/2 –	4d [3]_7/2
0	5900.46		16 943.14	[3]_5/2 –	[3]_5/2
0	5166.42		19 350.37	3p [3]_7/2 –	5d [4]_9/2

Level	Energy, cm⁻¹	ΔE	n*
3s[2]_5/2	123 920.07	−0.96	1.711 13
[2]_3/2	123 921.03		1.711 16
3p[3]_7/2	137 598.01	8.90	2.147 25
[3]_5/2	137 589.11		2.146 85
[2]_5/2	138 702.54	7.96	2.198 88
[2]_3/2	138 694.58		2.198 50
[1]_3/2	137 605.27^a	17.70	2.147 58
[1]_1/2	137 587.57^a		2.146 78
3d[4]_9/2	148 968.22	0.01	2.971 26
[4]_7/2	148 968.21		2.971 26
[3]_7/2	149 206.78	0.13	3.000 19
[3]_5/2	149 206.65		3.000 18
[2]_5/2,3/2	149 126.7		2.990 41
[1]_3/2,1/2	148 939.7		2.967 89
[0]_1/2	149 183.6		2.997 34
4d[4]_9/2	154 426.40	0.01	3.967 42
[4]_7/2	154 426.39		3.967 41
[3]_7/2	154 532.42	0.17	3.997 93
[3]_5/2	154 532.25		3.997 88
5d [4]_9/2	156 948.38		4.966 09

Energy level	Observed, cm⁻¹	Calculated^a	Δ	Calculated^b	Δ
2p⁴(¹D)3d[4]	148 969.20	148 968 (962)	1 (7)	149 197	−228
[3]	149 206.71	149 229 (212)	−22 (−5)	149 438	−231
[2]	149 126.7	149 132 (118)	−5 (9)	149 347	−220
[1]	148 939.7	148 932 (925)	8 (15)	149 160	−220
[0]	149 185.4			149 027	158
4d[4]	154 427.38	154 426	1	154 654	−227
[3]	154 532.36	154 536	−4	154 756	−224
[2]	154 496.6	154 497	0	154 720	−223
[1]	154 419.0	154 414	5	154 642	−223
[0]	154 270.5			154 587	−316
4s[2]	146 664.7	146 655	9

I	λ_obs, Å	σ, cm⁻¹	Identification^a
2	673.754	148 422.0	2p^{4 3}P₁ – 2p³(²P)8d ³DP
0	671.257	148 974.1	³P₀ – 10d ³DP
1	667.865	149 730.9	³P₂ – 15s ³P
1	667.804	149 744.5	³P₂ – 14d ³DP
1	667.545	149 802.6	³P₂ – 16s ³P
1	667.265	149 865.4	³P₂ – 17s ³P

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