Relative Transition Probabilities for Krypton

Myron H. Miller; Randy A. RoiG; Roger D. Bengtson

doi:10.1364/JOSA.62.001027

Journal of the Optical Society of America
Vol. 62,
Issue 9,
pp. 1027-1029
(1972)
•https://doi.org/10.1364/JOSA.62.001027

Relative Transition Probabilities for Krypton

Myron H. Miller, Randy A. RoiG, and Roger D. Bengtson

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Myron H. Miller, Randy A. RoiG, and Roger D. Bengtson, "Relative Transition Probabilities for Krypton," J. Opt. Soc. Am. 62, 1027-1029 (1972)

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Abstract

Relative transition probabilities of the more prominent Kr i and Kr ii lines have been measured using a gas-driven shock tube as a spectroscopic source. Results for 22 Kr i lines (4200 < λ < 8500 Å) and 33 Kr ii lines (4000< λ <5300 Å) have estimated reliabilities of 8–50%. The data are compared with other measurements and with theoretical calculations.

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Equations (57)

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Gases added to neon carrier	Temperatures [10³ K]	Plasma pressures (10⁶ dyn/cm²)	Number of experiments
0.2% SiH₄	10.8–12.9	6.1–25.2	9
+0.57% Kr	10.8–12.9	6.1–25.2	9
0.68% B₂H₆	10.7–12.2	5.7–19.0	7
+7.95% Kr	10.7–12.2	5.7–19.0	7
0.66% B₂H₆	10.1–11.4	8.0–22.0	6
+ 12.42% Kr²	10.1–11.4	8.0–22.0	6
1.92% Ar	10.2–12.4	6.3–22.0	4
+ 1.05% Kr
+0.63% Xe

λ_air (Å)	Classification	J_i–J_k	This work^a	Murphy
λ_air (Å)	Classification	J_i–J_k	This work^a	Experiment	Calculation	Fried-ricks
4273.97	$5 s [1 \frac{1}{2}] ° 6 p [1 \frac{1}{2}]$	2–2		2.0 A	3.30	1.19
4282.97	$5 s [1 \frac{1}{2}] ° - 6 p [1 \frac{1}{2}]$	2–1		0.54B	0.31	0.17
4318.55	$5 s [1 \frac{1}{2}] ° - 6 p [2 \frac{1}{2}]$	2–2		1.37A	0.79	0.42
4319.58	$5 s [1 \frac{1}{2}] ° - 6 p [2 \frac{1}{2}]$	2–3			2.34	2.44
4362.64	$5 s [1 \frac{1}{2}] ° - 6 p [\frac{1}{2}]$	2–1		0.90A	1.03	1.53
4376.12	$5 s [1 \frac{1}{2}] ° - 6 p [\frac{1}{2}]$	1–0		4.70A	7.00	1.65
4399.97	$5 s^{'} [1 \frac{1}{2}] ° - 6 p^{'} [1 \frac{1}{2}]$	1–2		1.93A	2.25	1.61	1.05
4410.37	$5 s [1 \frac{1}{2}] ° - 6 p {[2 \frac{1}{2}]}^{'}$	1–1		0.48C
4425.19	$5 s^{'} [\frac{1}{2}] ° - 6 p^{'} [1 \frac{1}{2}]$	1–1		0.95A	1.21	0.99
4453.92	$5 s [1 \frac{1}{2}] ° - 6 p [1 \frac{1}{2}]$	1–2		0.72A	0.89	0.51	0.73
4463.69	$5 s [1 \frac{1}{2}] ° - 6 p [1 \frac{1}{2}]$	1–1		2.14A	2.48	1.36	1.46
4502.35	$5 s [1 \frac{1}{2}] ° - 6 p [2 \frac{1}{2}]$	1–2		1.0	1.0	1.0	1.0
5562.23	$5 s [1 \frac{1}{2}] ° - 5 p^{'} [1 \frac{1}{2}]$	2–2		1.90C
5570.29	$5 s [1 \frac{1}{2}] ° - 5 p^{'} [\frac{1}{2}]$	2–1		11.3 D
5870.91	$5 s [1 \frac{1}{2}] ° - 5 p^{'} [1 \frac{1}{2}]$	1–2		9.40A
7587.41	$5 s [1 \frac{1}{2}] ° - 5 p [\frac{1}{2}]$	1–0		12.8 C
7601.54	$5 s [1 \frac{1}{2}] ° - 5 p [1 \frac{1}{2}]$	2–2		4.6 B	26.2	14.4
7685.25	$5 s^{'} [\frac{1}{2}] ° - 5 p^{'} [\frac{1}{2}]$	1–0		13.1 D		2.5
7694.54	$5 s [1 \frac{1}{2}] ° - 5 p [1 \frac{1}{2}]$	2–1		0.56D
7854.82	$5 s^{'} [\frac{1}{2}] ° - 5 p^{'} [\frac{1}{2}]$	0–1		6.29C	15.4	9.2
7928.60	$5 p [2 \frac{1}{2}] - 5 d [3 \frac{1}{2}] °$	2–3		1.71C
8059.50	$5 s^{'} [\frac{1}{2}] ° - 5 p^{'} [1 \frac{1}{2}]$	0–1		4.9 D	20.6	8.6
8508.87	$5 s^{'} [\frac{1}{2}] ° - 5 p^{'} [1 \frac{1}{2}]$	1–1		12.2 C	34.0	7.4

λ_air (Å)	Classification	J_i–J_k	This worka	Kooze-kanani et al. (Ref. 15)
4057.01	5s′ ²D–5p′ ²P°	$\frac{3}{2} - \frac{1}{2}$	0.78E
4065.11	5s′ ²D–5p′ ²D°	$\frac{3}{2} - \frac{3}{2}$	0.63D
4088.33	5s′ ²D–5p′ ²D°	$\frac{5}{2} - \frac{5}{2}$	0.84C
4098.72	5s⁴P–5p ²D°	$\frac{1}{2} - \frac{3}{2}$	1.83C	0.11
4145.12	5s⁴P–5p ⁴S°	$\frac{1}{2} - \frac{3}{2}$	0.38C	0.42
4236.64	5p ⁴P°–6s⁴P	$\frac{3}{2} - \frac{1}{2}$	1.58D
4250.58	5s²P–5p ²D°	$\frac{3}{2} - \frac{3}{2}$	0.51E
4268.81	5p ⁴S°–5d²P	$\frac{3}{2} - \frac{3}{2}$	2.7^bE
4292.92	5s⁴P–5p D°	$\frac{3}{2} - \frac{3}{2}$	0.67A	0.29
4300.49	5s²P–5p ⁴S°	$\frac{3}{2} - \frac{3}{2}$	0.35B	0.02
4322.98	5s″²D–5p″²P°	$\frac{1}{2} - \frac{3}{2}$	9.5 E
4355.47	5s⁴P–5p ⁴D°	$\frac{5}{2} - \frac{7}{2}$	1.0	1.0
4369.69	5p′ ²F°–4d″²D	$\frac{5}{2} - \frac{3}{2}$	18.4 D
4381.52	5s″²S–5f²D°	$\frac{1}{2} - \frac{3}{2}$	24.4 E
4386.54	5p ⁴P°–6s⁴P	$\frac{3}{2} - \frac{5}{2}$	1.83E
4422.70	5s′ ²D–5p′ ²P°	$\frac{3}{2} - \frac{3}{2}$	1.17C
4431.67	5s⁴P–5p ⁴D°	$\frac{1}{2} - \frac{1}{2}$	1.14B	0.59
4475.00	6s′ ²D–5p′ 2P°	$\frac{5}{2} - \frac{3}{2}$	1.12C
4523.14	5p ⁴P°–6s⁴P	$\frac{1}{2} - \frac{3}{2}$	5.8E
4577.20	5s′ ⁴D–5p′ ²F°	$\frac{5}{2} - \frac{7}{2}$	1.54A
4615.28	5s²P–5p ²P°	$\frac{3}{2} - \frac{3}{2}$	0.87C	0.48
4619.15	5s²P–5p ²D°	$\frac{3}{2} - \frac{5}{2}$	1.47 A	0.56
4633.88	5s′ ²D–5p′ ²F°	$\frac{3}{2} - \frac{5}{2}$	1.24C
4658.87	5s⁴P–5p ⁴P°	$\frac{5}{2} - \frac{3}{2}$	1.12A
4680.41	5s²P–5p ²S°	$\frac{1}{2} - \frac{1}{2}$	1.66D	0.70
4739.00	5s⁴P–5p ⁴D°	$\frac{5}{2} - \frac{5}{2}$	1.50B	0.03
4762.43	5s²P–5p ²D°	$\frac{1}{2} - \frac{3}{2}$	0.78B	0.64
4765.74	5s⁴P–5p ⁴D°	$\frac{3}{2} - \frac{5}{2}$	1.21B	0.42
4811.76	5s⁴P–5p ⁴D°	$\frac{1}{2} - \frac{3}{2}$	0.46D	0.25
4825.18	5s²P–5p ⁴S°	$\frac{1}{2} - \frac{3}{2}$	0.50E	0.05
4832.00	5s⁴P–5p ⁴P°	$\frac{3}{2} - \frac{1}{2}$	1.46B	0.65
4846.60	5s ²P–5p ²P°	$\frac{3}{2} - \frac{1}{2}$	1.75C
5208.32	5s⁴P–5p ⁴P°	$\frac{3}{2} - \frac{3}{2}$	3.21C	0.09

Level	Energy	Lifetime (ns) Fink et al. (Ref. 16)	Lifetime (ns)^a Present results
5p ⁴P_5/2°	16.60	8.5	5.2
5p ⁴P_3/2°	16.65	10.6	7.8
5p ⁴D_7/2°	16.83	8.7	8.7
5p ⁴D_5/2°	16.87	7.6	7.2
5p ⁴D_5/2°	17.16	7.7	7.7
5p ²D_5/2°	17.37	8.9	5.9
5p ⁴S_3/2°	17.57	8.3	7.1
5p ²D_3/2°	17.60	7.8	4.8
5p′ ²F_5/2°	18.49	11.3	7.0
5p′ ²F₇_/₂°	18.56	8.5	6.5
5p′ ²P_3/2°	18.62	7.6	7.7
5p′ ²P_1//2°	18.87	5.2	11.0
5p′ ²D_5/2°	18.88	7.5	10.0
5p″²P_3/2°	20.94	6.2	0.9

Gases added to neon carrier	Temperatures [10³ K]	Plasma pressures (10⁶ dyn/cm²)	Number of experiments
0.2% SiH₄	10.8–12.9	6.1–25.2	9
+0.57% Kr	10.8–12.9	6.1–25.2	9
0.68% B₂H₆	10.7–12.2	5.7–19.0	7
+7.95% Kr	10.7–12.2	5.7–19.0	7
0.66% B₂H₆	10.1–11.4	8.0–22.0	6
+ 12.42% Kr²	10.1–11.4	8.0–22.0	6
1.92% Ar	10.2–12.4	6.3–22.0	4
+ 1.05% Kr
+0.63% Xe

Abstract

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Tables (4)

Equations (57)

Journal of the Optical Society of America