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Remarks on the Infrared Spectra of Metallic Salts Containing Groups of the XO2-Type Ion

Clément Duval and Jean LeComte

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Abstract

A study has been made of infrared spectra of metallic salts containing groups of the XO2-type ion. It has been shown that metaborate (and orthoborate) polymerize. Vibration spectra of the metallic metaborates indicate that the BO2− does not exist in the free state but under the polymerized form (BO2)n. Postulations are made concerning this structure.

© 1954 Optical Society of America

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