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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 67,
  • Issue 9,
  • pp. 1013-1018
  • (2013)

Photothermal Lens Spectrometry Measurements in Highly Turbid Media

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Abstract

We measured the photothermal lens signal in samples exhibiting high turbidity using a pump-probe scheme. We show that the photothermal lens signal properties remain nearly unchanged up to values of turbidity of 6 cm<sup>?1</sup> despite the signal reduction due to the decrease of excitation power associated to turbidity losses. The signal starts decreasing abruptly for values of turbidity larger than 6 cm<sup>?1</sup>. Multiple light scattering yields a reduction of the temperature gradients, which results in a decrease of the effective signal. However, the signal-to-noise ratio remains above 50 for turbidity values of 9 cm<sup>?1</sup>, which corresponds to a reduction of light transmission by more than four orders of magnitude. We report on the detection of the photothermal lens signal through a 2 mm layer of organic tissue with a signal-to-noise ratio of about 500. This technique appears promising for imaging applications in organic samples, which usually exhibit high turbidity for visible and near-infrared light.

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