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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 25,
  • Issue 2,
  • pp. 187-191
  • (1971)

Vibrational Spectra of Tetrahedral Cyclopentadienyl Halogeno Complexes of Ti(iv) and Zr(iv)

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Abstract

The ir and Raman spectra of CpTiCl<sub>3</sub> and Cp<sub>2</sub>MX<sub>2</sub> (Cp = C<sub>5</sub>H<sub>5</sub>, <i>M</i> = Ti, Zr and Hf, and <i>X</i> = a halogen) type compounds have been measured. Approximate normal coordinate analyses have been carried out to assign the skeletal modes in the low frequency region.

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