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Long-lived Excited States in 7- and 9-Methylpurine Probed by fs Time-Resolved Vibrational Absorption Spectroscopy

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Abstract

Transient vibrational absorption spectroscopy elucidates common deactivation pathways after UV photoexcitation for 7- and 9-methylpurine. However, 9-methylpurine exhibits an additional relaxation channel revealed by indirect observation of the excited 1ππ* state

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