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Pursuing Primary Processes of Diphenylcarbene in Binary Solvent Mixtures

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Abstract

An intermediate H-bonded complex formed in MeOH/MeCN solvent mixtures between photogenerated diphenylcarbene and a MeOH molecule is identified, both in theory and experiment. The complex is the ultrafast analog of findings at cryogenic temperatures.

© 2016 Optical Society of America

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