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Femtosecond Vibrational Spectroscopic Study on Photoexcitation Dynamics of DNO-bound Myoglobin

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Abstract

Time-resolved vibrational spectra of DNO-bound myoglobin showed instantaneous bleach that decays on a picosecond time scale, suggesting that most of the photoexcited MbDNO undergoes picosecond geminate rebinding of DNO to Mb after its immediate deligation.

© 2014 Optical Society of America

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