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fs-Fluorescence Measurements of the Adenine Dinucleotide: Direct Observation of the Excimer State

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Abstract

Femtosecond time-resolved fluorescence measurements on the adenine dinucleotide d(pApA) revealed wavelength-dependent, complex excited-state relaxation dynamics via monomer-like and via excimer states, depending on the degree of base stacking.

© 2010 Optical Society of America

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