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Femtosecond UV Studies of Relaxation Processes in Cytochrome C

A. Cannizzo, O. Bräm, C. Consani, F. van Mourik, and M. Chergui

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Abstract

UV femtosecond fluorescence and transient-absorption studies of ferric and ferrous cytochrome C are presented. We characterize their photocycles, which are described in terms of a model based on electron metal-to-heme back-donation from occupied metal d orbitals.

© 2010 Optical Society of America

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