2-Dimensional Measurement of the Solvent Intermolecular Response in Solvation

Sungnam Park; Jeongho Kim; Norbert F. Scherer

14th International Conference on Ultrafast Phenomena
Technical Digest (CD) (Optica Publishing Group, 2004),
paper TuB7

2-Dimensional Measurement of the Solvent Intermolecular Response in Solvation

Sungnam Park, Jeongho Kim, and Norbert F. Scherer

International Conference on Ultrafast Phenomena 2004

Niigata Japan
25–30 July 2004
ISBN: 3-54024-110-8

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Multidimensional Spectroscopy (TuB)

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S. Park, J. Kim, and N. F. Scherer, "2-Dimensional Measurement of the Solvent Intermolecular Response in Solvation," in 14th International Conference on Ultrafast Phenomena, Technical Digest (CD) (Optica Publishing Group, 2004), paper TuB7.

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Abstract

The solvent intermolecular response in solvation is studied by 2-D polarizability response spectroscopy. The isotropic and anisotropic solvent response spectra of Coumarin 153 in CH₃CN, measured during solvation, reveal enhanced translational vs. orientational dynamics.

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