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Optica Publishing Group
  • Frontiers in Optics 2007/Laser Science XXIII/Organic Materials and Devices for Displays and Energy Conversion
  • OSA Technical Digest (CD) (Optica Publishing Group, 2007),
  • paper JWC21
  • https://doi.org/10.1364/FIO.2007.JWC21

Influence of the Pi-Electrons Distribution on the Magnetooptical Activity Stimulation in Some Aromatic Liquids

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Abstract

Experimental results of Faraday rotation spectra in a range between 1.8 – 3.65 eV were obtained for H2O, CCl4, dimethilaniline, benzene, nitrobenzene, o-toluidine, o-anisidine, m-chloraniline and o-chloraniline. Self-consistent field (SCF) semi-empirical quantum mechanics calculations using MNDO/D method for organic molecules was chosen to evaluate electron spectra in visible and UV range to interpret experimental results It is shown that magneto-optical response of samples changes significantly with the geometry of pi-electrons distribution in aromatic liquids.

© 2007 APS DLS

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