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Finding Intersections Between Electronic Excited States with Ultrafast X-ray Scattering and Spectroscopy

Kasper S. Kjær and Kelly J. Gaffney

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Abstract

We use ultrafast x-ray emission spectroscopy and x-ray scattering to study photo-induced spin crossover in [Fe(2,2’-bipyridine)3]2+. These measurements enable the projection of intersections between ligand field excited states onto the Fe-ligand bond length coordinate.

© 2017 Optical Society of America

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