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  • Conference on Lasers and Electro-Optics/International Quantum Electronics Conference
  • OSA Technical Digest (CD) (Optica Publishing Group, 2009),
  • paper IPDB9
  • https://doi.org/10.1364/IQEC.2009.IPDB9

Direct Observation of the Conical Intersection in cis-trans Photoisomerization of Rhodopsin

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Abstract

High-time-resolution broadband pump-probe spectroscopy of rhodopsin reveals the loss of reactant and appearance of photoproduct features within ≈100fs, which are signatures of a wavepacket moving through a conical intersection. Experiments are supported by molecular dynamics simulations.

© 2009 Optical Society of America

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