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  • International Quantum Electronics Conference
  • OSA Technical Digest (Optica Publishing Group, 1987),
  • paper WBB3

Saturation of picosecond transient belaching in trans-polyacetylene

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Abstract

Su and Schneller1 predicted charged soliton pairs to be the primary photoexcitations of trans-polyacetylene, since they can be supported by its degenerate ground-state configurations. These solitons are mobile domain boundaries between different phases of bond alternation in this 1-D conjugated polymer. Recent picosecond time-resolved absorption experiments on the midgap photoinduced absorption of trans-polyacetylene have identified directly photogenerated charged solitons for the first time.2

© 1987 Optical Society of America

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