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Conferences > IQEC > 1986 > TUGG > TUGG3
  • International Quantum Electronics Conference
  • OSA Technical Digest (Optica Publishing Group, 1986),
  • paper TUGG3

Decomposition of methanol on Ru(001) studied using laser-induced thermal desorption

A. A. DECKERT, J. L. BRAND, C. H. MAK, and S. M. GEORGE

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Abstract

The decomposition of methanol on Ru(001) is studied as a model surface reaction system. Laser-induced thermal desorption (LITD) is used as a real-time probe of the surface reaction. The measurements yield a reaction activation barrier of 12 kcal/mole if a pre-exponential of 5 × 1011 s−1 is assumed, in the LITD experiment, the sample is prepared by saturating the Ru(001) surface at 100 K with methanol. The surface temperature is ramped linearly up to 400 K at 1.5 K/s.

© 1986 Optical Society of America

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