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Fast Recombination after Electron Photo-Detachment of Hydroxide in H-bonded Liquids

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Abstract

Femtosecond pump-repump-probe spectroscopy on OH in H-bonded liquids reveals an ultrafast (0.7–1 ps) geminate recombination channel. The process is assigned to formation of short-lieved OH:e pairs facilitated by the inhomogeneity local H-bonding environment of OH.

© 2012 Optical Society of America

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