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Ablative photodecomposition of organic polymer films by far-UV excimer laser irradiation

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Abstract

Radiation of wavelengths shorter than 200 nm is intensely absorbed by nearly all organic polymers. More than 95% of the photons are absorbed in a depth of ~3000 Å. Far-UV radiation has an efficiency of >50% at breaking bonds in organic material. As a result when a laser pulse of 193-nm wavelength impinges on an organic film, numerous small fragments are created in a small volume. When the intensity of the pulse exceeds a threshold value (~10 mJ/cm2), the small fragments ablate—they explosively burst out of the irradiated volume.

© 1983 Optical Society of America

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