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Understanding Photorefractivity in High-Performance Polymer Composites

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Abstract

Recently-developed photorefractive polymer composites now show sufficiently high performance to allow effects such as self-pumped phase conjugation and speeds approaching video frame rates. To understand the mechanisms leading to this new level of performance, a simple spectroscopic method for the determination of the trap density in fullerene-sensitized photorefractive (PR) polymers is presented. This method is compared with results obtained from traditional trap density measurements which involve two-wave mixing, and good correlation is observed. This technique is used to identify the inactive (compensating) trap as the nonlinear optical chromophore (NLO).

© 1999 Optical Society of America

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