Three-photon infrared quantum cutting from single species of rare-earth Er3+ ions in Er0.3Gd0.7VO4 crystalline

Xiaobo Chen; Jinguang Wu; Xiaolin Xu; Yunzhi Zhang; Naruhito Sawanobori; Chunlin Zhang; Qinghua Pan; Gragory J. Salamo

doi:10.1364/OL.34.000887

Optics Letters
Vol. 34,
Issue 7,
pp. 887-889
(2009)
•https://doi.org/10.1364/OL.34.000887

Three-photon infrared quantum cutting from single species of rare-earth ${Er}^{3 +}$ ions in ${Er}_{0.3} {Gd}_{0.7} V O_{4}$ crystalline

Xiaobo Chen, Jinguang Wu, Xiaolin Xu, Yunzhi Zhang, Naruhito Sawanobori, Chunlin Zhang, Qinghua Pan, and Gragory J. Salamo

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Xiaobo Chen, Jinguang Wu, Xiaolin Xu, Yunzhi Zhang, Naruhito Sawanobori, Chunlin Zhang, Qinghua Pan, and Gragory J. Salamo, "Three-photon infrared quantum cutting from single species of rare-earth Er³⁺ ions in Er_0.3Gd_0.7VO₄ crystalline," Opt. Lett. 34, 887-889 (2009)

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Abstract

An effective three-photon IR quantum cutting excited by visible light used for solar cells, which has attracted broad attention of academia recently, is reported for the first time (to our knowledge). It is based on a single species of rare-earth ${Er}^{3 +}$ ion of ${Er}_{0.3} {Gd}_{0.7} V O_{4}$ crystalline. It was found that the approximate quantum cutting efficiency of the $1532.5 nm$ ${}^{4}I_{13 ∕ 2} \to {}^{4}I_{15 ∕ 2}$ fluorescence, when the ${}^{2}H_{11 ∕ 2}$ level was excited, is about 178.55%.

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	${}^{2}H_{11 ∕ 2}$	${}^{4}I_{9 ∕ 2}$	${}^{4}S_{3 ∕ 2}$	${}^{4}F_{9 ∕ 2}$
$557.0 nm$	$4.515 \times 10^{2}$
$667.5 nm$	$1.422 \times 10^{1}$		$2.178 \times 10^{1}$
$810.5 nm$	$4.741 \times 10^{1}$		$7.312 \times 10^{1}$	$2.281 \times 10^{1}$
$850.0 nm$	$2.695 \times 10^{2}$
$999.5 nm$	$3.083 \times 10^{4}$	$8.478 \times 10^{4}$	$4.067 \times 10^{4}$	$2.436 \times 10^{4}$
$1532.5 nm$	$7.737 \times 10^{5}$	$3.778 \times 10^{5}$	$3.804 \times 10^{5}$	$1.545 \times 10^{5}$
$η^{'}$	178.55%		147.09%	132.26%

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