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High-quality factor mid-infrared absorber based on all-dielectric metasurfaces

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Abstract

The absorption spectrum of metasurface absorbers can be manipulated by changing structures. However, narrowband performance absorbers with high quality factors (Q-factor) are hard to achieve, mainly for the ohmic loss of metal resonators. Here, we propose an all-dielectric metasurface absorber with narrow absorption linewidth in the mid-infrared range. Magnetic quadrupole resonance is excited in the stacked Ge-Si3N4 nanoarrays with an absorption of 89.6% and a Q-factor of 6120 at 6.612 µm. The separate lossless Ge resonator and lossy Si3N4 layer realize high electromagnetic field gain and absorption, respectively. And the proposed method successfully reduced the intrinsic loss of the absorber, which reduced the absorption beyond the resonant wavelength and improved the absorption efficiency of Si3N4 in the low loss range. Furthermore, the absorption intensity and wavelength can be modulated by adjusting the geometric parameters of the structure. We believe this research has good application prospects in mid-infrared lasers, thermal emitters, gas feature sensing, and spectral detection.

© 2023 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement

1. Introduction

Metasurfaces or metamaterials absorbers (MAs) with high performance and specific functions can construct nearly perfect absorption in subwavelength thickness [13]. The MAs based on the classic Metal-Dielectric-Metal (MDM) sandwich structure have been widely studied from visible light to microwave ranges [47]. These studies have promising applications in solar energy capture [8,9], radiative cooling [10,11], detection [1214], camouflage [15,16], etc. High spectral selectivity and resolution have a strong demand for narrowband response. The narrowband MAs can absorb specific wavelengths of radiation with solid spectral selectivity in the fields of spectral sensing [17,18] and thermal emitters [1921]. However, the absorption bandwidth of metallic MAs is limited due to the apparent intrinsic loss caused by ohmic damping [22]. Some resonance modes with low dissipation rates can suppress the intrinsic loss to improve the absorption quality factor (Q-factor) of metallic MAs, such as guided-mode resonance [23], lattice resonance [24,25], and high-order mode gain medium [26]. However, the absorption caused by ohmic loss is accompanied by a thermal effect instead of photogenerated carriers, which limits their application in optoelectronic devices.

In recent years, all-dielectric metasurfaces based on Mie resonances have attracted much attention due to their low-loss characteristic and provide rich optical resonance properties [2730], which have critical applications in wavefront control such as metalens [31,32] and holography [33,34]. Lossless dielectric resonators in the metasurface could exhibit magnetic and electric dipoles and higher-order resonances, which is an effective method for narrowband response [35]. As for a lossy system, lossy materials need to be introduced into dielectric resonators to achieve absorption. But there is a 50% absorption limit in a single resonance mode for dielectric films with subwavelength thicknesses, and the same goes for MAs [36,37]. The coupling effect of antisymmetric electromagnetic modes can break the limitation and 100% absorption achieved by introducing appropriate intrinsic losses to match the radiation losses [3841]. All-dielectric MAs based on Si and Ge resonators have been realized in the near-infrared and visible light bands [42,43]. The absorption originates from the resonance response provided by the high refractive index lossy dielectric unit. However, achieving narrowband and high absorption in all-dielectric MAs simultaneously in the mid-infrared range (3-14 µm) is still challenging. Some reports of mid-infrared high-Q absorbers based on metallic metasurface [44]. For example, the Q-factor of the absorbers based on cross or ring gold resonators reaches 30 and 118, respectively [22,45]. And a method of constructing high-Q dielectric resonators using a high-reflectivity metal layer could increase the Q-factor to more than 1000 by increasing the absorption of metal [46,47]. For all-dielectric MAs, the index of the commonly used infrared lossy materials such as Si3N4 and SiO2 are too low to realize the corresponding resonant mode response requires a larger size/wavelength ratio, which means an increase in intrinsic absorption effect, which would cause the expansion of absorption bandwidth.

In this study, we proposed a high-Q absorber based on an all-dielectric metasurface in the mid-infrared range. The narrowband absorption is based on the separation of resonance and lossy area. First, a lossless Ge-CaF2 resonator was designed to generate high-Q resonance. The magnetic quadrupole mode and magnetic dipole mode with ultra-narrow linewidth are generated at P1 (6.612 µm) and P2 (8.236 µm), respectively. Then, a selective narrowband absorber is achieved by applying the high-Q resonance to the lossy Si3N4 layer. The separate lossless Ge resonator and lossy layer realize high electromagnetic field gain and high absorption, respectively, while reducing the intrinsic loss of the material. Furthermore, due to the size sensitivity of resonances, the absorption intensity and wavelength can be modulated by adjusting the geometric parameters of the structure. Therefore, the high-Q wavelength-tunable absorption capability makes this research promising for applications in miniature infrared spectrometers, mid-infrared lasers, infrared detection and sensing.

2. Structure and design

The schematic diagram of the all-dielectric high-Q absorber proposed in this paper is shown in Fig. 1, where Si3N4 nanoarray and Ge nanoarray on a CaF2 substrate in sequence, with a unit period P of 3.38 µm. The thicknesses of the Si3N4 and Ge nanopillars are H0 = 100 nm and H1 = 4.38 µm, respectively, and their common diameter D is 2 µm. The loss of CaF2 and Ge can be ignored in the research wavelength range, and the refractive index of the two materials are fixed at 1.4 and 4 in the simulation. We simulated the performance of the structure by using the finite-difference time-domain (FDTD) method. The boundary conditions in the X and Y directions are periodic, and the normal incident infrared light reaches the structure along the Z-axis. The structure is polarization-independent, so we use linearly polarized light with the electric field direction along the X-direction for simulations, whose wave vectors and field directions are shown in Fig. 1.

 figure: Fig. 1.

Fig. 1. Schematic diagram of the all-dielectric narrowband absorber. P represents the period of the unit cell, and H0 and H1 represent the heights of the Si3N4 and Ge layers, respectively. The common diameter of the nanopillars is D.

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3. Result and discussion

Figure 2 shows the reflection (R), transmission (T), and absorption (A) spectrums of the Ge-Si3N4-CaF2 lossy absorber and the Ge-CaF2 lossless resonator, respectively. The absorption can be expressed as A = 1 - R - T. Under the excitation of normal incident electromagnetic waves, the subwavelength nanoarrays based on high-refractive-index dielectric material can excite different orders of electrical and magnetic resonances due to the Mie resonance effect, which shows abnormal reflection or transmission spectrum. Based on this, we constructed a lossless resonator structure using Ge-CaF2 units, in which the substrate is CaF2, and the Ge nanoarrays are the resonators. The scattering properties are shown in Fig. 2(c). Two ultra-narrow resonance peaks are generated at P1 (6.612 µm) and P2 (8.236 µm). Compared with the adjacent wavelength, the reflectivity of P1 decreased while P2 increased significantly. Before introducing lossy materials, the structure had no absorption in the entire spectral band, and the absorptivity was zero, as shown in Fig. 2(d). Then, we inserted a 100 nm-thick Si3N4 thin disk with the same diameter under the Ge resonator, as shown in Fig. 2(a). The Si3N4 disk will not excite new resonant modes to affect the Ge resonator for the mismatch between size and wavelength. Only Transmission and reflection at P1 and P2 are suppressed significantly, and the overall scattering curves are consistent with the case without lossy material. Indeed, we obtained two absorption peaks with high Q-factor, P1 and P2, corresponding to the original resonance peak, as shown in Fig. 2(b). Among the Ge-Si3N4-CaF2 absorber, the absorptivity of P1 is 89.6%, the FWHM of the absorption peak is 1.08 nm, and the Q-factor is 6120. The absorptivity of P2 is 38.9%, the FWHM is 22.2 nm, and the Q factor is 371. The Q-factor is given by Q = λ ⁄ FWHM, where λ is the absorption peak wavelength, and FWHM is the absorption peak full width at half maximum.

 figure: Fig. 2.

Fig. 2. (a) and (c) are the mid-infrared scattering curves of the Ge-Si3N4-CaF2 lossy absorber and the Ge-CaF2 low-loss resonator, respectively, where the transmittance is T, and the reflectance is R. (b) and (d) are the mid-infrared absorption curves of the absorber and resonator, respectively. The insert Fig. in (b) is a partial amplification of P1. The FWHM of the absorption peaks P1 and P2 are 1.08 nm and 22.2 nm, respectively.

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The intense resonance modes at the high-Q resonance peaks P1 and P2 enhance the absorption effect of the lossy material Si3N4, thus achieving high-Q absorption. Figure 3(a) lists the refractive index dispersion curves of Si3N4 at wavelengths from 2 to 14 µm [48]. The imaginary part of the refractive index k means extinction coefficient. The region with a large extinction coefficient is concentrated in the band of 10-14 µm, while the region with a shorter wavelength is smaller, which means weaker absorbing ability. We compared the absorption property of insert Si3N4 in different situations, as shown in Fig. 3(b). All films were placed on a CaF2 substrate. The yellow dotted curve in Fig. 3(b) shows the absorption of the 100 nm thick Si3N4 film in the wavelength range of 6-14 µm, which is consistent with the distribution of the extinction coefficient. At P3 (λ = 12 µm), the maximum absorptivity reaches 24.6%, which is only 2.6% at 6 µm. As shown by the green curve in Fig. 3(b), we reduced the filling ratio of lossy material by patterning the Si3N4 layer, which leads to a decrease in the equivalent extinction coefficient. For the convenience of nanofabrication, the radius of the Si3N4 disk is kept the same as that of the Ge nanopillar. Patterned Si3N4 restrained the intrinsic absorption of the structure, which leads the absorption at P3 from 24.6% to 6.9%. In this process, the filling ratio of Si3N4 is 27.5%, and the absorptivity is 28.0% of the previous situation, which shows that the absorptivity depends on the intrinsic absorption efficiency of the material without resonance interference. At this time, due to the mismatch between the Si3N4 layer size and the resonant wavelength, it is difficult to excite the resonant absorption mode with high quality factor, and the thickness of the structure needs to be increased to allow more resonant modes to exist. But the consequence is that the overall loss of the structure will rise. Therefore, we designed a low-loss Ge resonator structure to enhance the absorption of Si3N4 at a specific wavelength. By inserting the Si3N4 layer into the Ge-CaF2 resonator, shown by the blue curve in Fig. 3(b), sharp absorption peaks P1 and P2 are generated at the two strong resonances. And the absorption of other regions is close to those without the Ge resonator. The absorption spectrum obtained by the finally adopted Ge-Si3N4 nanopillar array structure is shown in the red curve in Fig. 3(b), the same as in Fig. 2(b). Compared with the case of Ge-Si3N4 film, the absorption of P1 and P2 is slightly increased. In order to maintain the unity of the variables in the comparison, we maintained the parameter consistency of the Ge resonator in the Ge-Si3N4 nanodisk structure and the Ge-Si3N4 film structure. Since the final Si3N4 nanodisk structure is used, the parameter selection of the Ge resonator is based on the nanodisk and adapted to obtain the best absorption effect and reduce the intrinsic absorption of P3, which improves the absorptivity contrast at the resonance absorption peak. The absorptivity of peaks P1 and P2 are not particularly dependent on the extinction coefficient of the material. Compared with the 100 nm Si3N4 film on the CaF2 substrate, the absorption at P1 and P2 increased by 30 times and 8 times, respectively, while the extinction coefficient of Si3N4 is 0.09. This method effectively improves the absorption of Si3N4 in the low-loss range, which can be generalized to other low-loss materials to improve their absorptivity.

 figure: Fig. 3.

Fig. 3. (a) Refractive index actual part n, imaginary part k of Si3N4. (b) The absorption curves of Si3N4 film, Si3N4 nanodisk array, and the absorption after adding Ge resonator. The Si3N4 thickness H0 is kept at 100 nm.

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In order to explain the absorption mechanism of the design structure, electromagnetic field distribution at P1 and P2 were extracted, as shown in Fig. 4. The direction of the arrow represents the direction of the electric/magnetic vector field. On the whole, the intensity of the electromagnetic field in the absorber has different degrees of multiplication at the two absorption peaks, which is a significant electromagnetic field enhancement effect brought by the high-Q resonance. For the P1 peak shown in Fig. 4(a), the electric field is concentrated in the center of the Ge column. The electric vector direction is perpendicular to the wave vector direction in the Z direction. As shown in Fig. 4(c), two opposite annular electric vectors are distributed on the XY plane. The magnetic dipole moments cancel each other and excite a magnetic quadrupole moment in Fig. 4(b). Therefore, this indicates that P1 is dominated by magnetic quadrupole (MQ) mode. For the P2 peak, as shown in Fig. 4(d)-(f), the electric field forms two circular vectors with the same rotation direction in the XZ plane, which excites two co-directional magnetic vectors in the YZ plane, indicating that the dominant mode is the second-order magnetic dipole (MD) mode. According to ${P_{abs}} = 0.5\omega \kappa {|E |^2}$, where ω is the angular frequency, κ is the extinction coefficient of the material, E is the electric field intensity [49], the absorptivity of the material is proportional to its extinction coefficient, and the square of the modulus of the electric field intensity in the material. The electric field at the center of the Ge resonator at P1 has a 50-fold gain compared to the incident light, which enhances the absorption of the Si3N4 layer.

 figure: Fig. 4.

Fig. 4. The local electromagnetic field distribution of absorption peaks P1 and P2. (a) and (d) are the electric field distributions on the XZ plane (Y = 0) of P1 and P2. (b) and (e) are the magnetic field distributions on the YZ plane (X = 0) of P1 and P2. (c)(g) are electric field distribution on the XY plane of P1 (Z = 2.19 µm) and P2 (Z = 3.4 µm). The position of the XY plane depends on the center position of the P1 and P2 fields.

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The response of the absorber depends mainly on the height of the Ge resonator. Each mode's resonant intensity and wavelength change accordingly when the height changes. Figure 5 shows the corresponding relationship between the changing trend of the reflection and absorption curves of the absorber wavelength and the resonator height H. The three white dotted lines in the reflection spectrum shown in Fig. 5(a) represent the electric dipole mode (ED), MQ, and MD2 modes, respectively, where P1 corresponds to the MQ mode. The final result of the influence of different resonance modes is the change of radiation states. In Fig. 5(a), the ED and MD2 modes correspond to the radiation states of high reflectivity, while the MQ mode is the radiation state of low reflectivity. Corresponding to the absorption peak P1, it can maintain the high-Q characteristics as a higher-order mode. According to the coupled-mode theory, the absorptivity A under the action of two coupled modes can be expressed as Eq. (1) [38]:

$${A = \frac{{2{\gamma _1}{\delta _1}}}{{{{({\omega - {\omega_1}} )}^2} + {{({{\gamma_1} + {\delta_1}} )}^2}}} + \frac{{2{\gamma _2}{\delta _2}}}{{{{({\omega - {\omega_2}} )}^2} + {{({{\gamma_2} + {\delta_2}} )}^2}}}}$$
where $\mathrm{\omega}$, ${\mathrm{\omega}_1}$, and ${\mathrm{\omega}_2}$ are the angular frequency of the electromagnetic wave and the resonance angular frequency of two modes, and γ and δ are the mode’s radiation loss and intrinsic loss. When only one mode is active, at the resonance frequency $\omega = {\omega _1}$, there is ${A_{max}} = 0.5$ only if ${\gamma _1} = {\delta _1}$. Therefore, the absorption rate of the peak P2 has an upper limit of 50%, which is only affected by a single magnetic dipole mode MD1. For P1, it is coupled with multiple modes, such as ED, MD2, and MQ so that Amax can reach 100%. As shown in Fig. 5(b), there is an apparent light-dark change process in its absorptivity. According to different characteristics, we divide the curve of P1 with H into four regions. In region 1, the resonance coupling intensity is weak, which limits the absorption improvement. Under the multi-mode coupling in the encircled region, where in region 2, it has the characteristics of a narrow spectrum and high absorption, and the absorption rate can reach 90%. In region 3, with the increase of H, the MQ mode is suppressed by ED mode, which characteristics are entirely obscured by the ED mode, showing high reflection and low absorption. Features, in region 4, where the MQ mode that actives alone realize high-Q absorption while the maximum absorption rate is less than 50%. The absorptivity can be modulated by controlling the height or aspect ratio of the resonator.

 figure: Fig. 5.

Fig. 5. Reflection (a) and absorption (b) curves of absorber at different Ge resonator heights. According to different characteristics, the curve of P1 with H was divided into four regions, which are represented in orange dashed ellipses.

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To realize the control of absorption wavelength and intensity, we simulated the situations of different periods and Si3N4 thicknesses. The obtained absorption curves are shown in Fig. 6. It can be seen from Fig. 6(a) that when the period changes, both P1 and P2 have a slight red-shift with the increase of the period, accompanied by the change of absorption intensity. The Q-factor of P2 shows a process of decreasing first and then increasing. The absorption is not the highest when the Q-factor is the largest, which indicates that a high Q-factor and high absorption are not completely equivalent. When the thickness of the loss material Si3N4 increases, as shown in Fig. 6(b), the absorption is enhanced except for the two resonance absorption peaks. The absorption wavelengths at P1 and P2 are almost unchanged because the absorption wavelength is determined by the relevant parameters of the upper Ge resonator. The absorption intensity of P1 decreases with the increase of Si3N4 thickness because the change of loss material thickness destroys the matching condition of resonance.

 figure: Fig. 6.

Fig. 6. The absorption curves of the absorber for the different (a) period (fill factor) P; (b) Si3N4 thickness H0.

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The absorption wavelength is positively related to the size of the Ge resonator. The absorption wavelength can be adjusted by proportional scaling to maintain the corresponding resonance intensity. β is defined as a scaling factor to describe scaling size. Taking the 1 µm-radius Ge column as the benchmark and maintaining the aspect ratio of the resonator, we show six absorption lines separated by a 2.5% difference of β, as shown in Fig. 7. The resonance wavelength red-shifts with the increase of the resonator size. In the 6.4-7.3 µm covered by the absorption line in Fig. 6, the absorber maintains a high absorptivity of more than 80%. And the FWHM of the absorption peak is maintained between 1-2 nm. The Q factor is maintained above 4000, where the absorption at other wavelengths in the observation range remains low, showing good contrast differences. The wavelength-modulated narrow-spectrum absorption characteristics of nm-scale linewidth and the high absorptivity contrast inside and outside the absorption peak endow the designed metasurface structure with good potential for spectral detection.

 figure: Fig. 7.

Fig. 7. Absorption curves and Q-factors corresponding to different resonator sizes. β is defined as a scaling factor to describe scaling size.

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4. Conclusion

In conclusion, we propose a high-Q absorber based on an all-dielectric metasurface in mid-infrared. Unlike other all-dielectric absorbers, Resonator and absorption layer is separated in the Ge-Si3N4-CaF2 absorber. The high-Q magnetic quadrupole resonance mode excited by the lossless Ge resonator enhances the absorption of the lossy Si3N4 thin layer so that the high absorption region occurs in a very narrow spectral width. The intrinsic loss of the absorber can be controlled by patterning Si3N4 to improve the wavelength contrast of absorption, which is crucial for spectral detection. The proposed absorber achieved a narrow absorption linewidth, and the obtained absorption peak P1 has an FWHM of 1.08 nm with a Q-factor of 6120. By discussing the local electromagnetic field distribution and the Cartesian multilevel decomposition of the absorber, it is clear that the main resonant modes of absorption peaks P1 and P2 in the structure are magnetic quadrupole resonance and magnetic dipole resonance, respectively. The enhancement effect of the electromagnetic field accompanied by the high-Q resonance is the reason for the absorption enhancement. The absorptivity at P1 is increased from 2.6% to 89.6%, while the extinction coefficient of Si3N4 is 0.09. This method effectively improves the absorption of Si3N4 in the low-loss range. In this way, the absorption area and wavelength are strictly limited, which can effectively improve the absorption intensity of specified electromagnetic waves in the specified material and the energy density inside the material after exposure to light. This research can also be extended to other infrared loss materials to enhance the light-matter interaction and absorption capabilities at specific needs and to improve detection sensitivity and response. Therefore, this research has good application prospects in mid-infrared laser, sensing, and photoelectric detection.

Funding

National Natural Science Foundation of China (61735018, 61805242); Scientific and Technological Development Project of Jilin Province (20220201080GX); Excellent Member of Youth Innovation Promotion Association of the Chinese Academy of Sciences (2014193, Y201836); Leading Talents and Team Project of Scientific and Technological Innovation for Young and Middle-aged Groups in Jilin Province (20190101012JH).

Disclosures

The authors declare no conflicts of interest.

Data availability

Data underlying the results presented in this paper are not publicly available at this time but may be obtained from the authors upon reasonable request.

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Data availability

Data underlying the results presented in this paper are not publicly available at this time but may be obtained from the authors upon reasonable request.

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Figures (7)

Fig. 1.
Fig. 1. Schematic diagram of the all-dielectric narrowband absorber. P represents the period of the unit cell, and H0 and H1 represent the heights of the Si3N4 and Ge layers, respectively. The common diameter of the nanopillars is D.
Fig. 2.
Fig. 2. (a) and (c) are the mid-infrared scattering curves of the Ge-Si3N4-CaF2 lossy absorber and the Ge-CaF2 low-loss resonator, respectively, where the transmittance is T, and the reflectance is R. (b) and (d) are the mid-infrared absorption curves of the absorber and resonator, respectively. The insert Fig. in (b) is a partial amplification of P1. The FWHM of the absorption peaks P1 and P2 are 1.08 nm and 22.2 nm, respectively.
Fig. 3.
Fig. 3. (a) Refractive index actual part n, imaginary part k of Si3N4. (b) The absorption curves of Si3N4 film, Si3N4 nanodisk array, and the absorption after adding Ge resonator. The Si3N4 thickness H0 is kept at 100 nm.
Fig. 4.
Fig. 4. The local electromagnetic field distribution of absorption peaks P1 and P2. (a) and (d) are the electric field distributions on the XZ plane (Y = 0) of P1 and P2. (b) and (e) are the magnetic field distributions on the YZ plane (X = 0) of P1 and P2. (c)(g) are electric field distribution on the XY plane of P1 (Z = 2.19 µm) and P2 (Z = 3.4 µm). The position of the XY plane depends on the center position of the P1 and P2 fields.
Fig. 5.
Fig. 5. Reflection (a) and absorption (b) curves of absorber at different Ge resonator heights. According to different characteristics, the curve of P1 with H was divided into four regions, which are represented in orange dashed ellipses.
Fig. 6.
Fig. 6. The absorption curves of the absorber for the different (a) period (fill factor) P; (b) Si3N4 thickness H0.
Fig. 7.
Fig. 7. Absorption curves and Q-factors corresponding to different resonator sizes. β is defined as a scaling factor to describe scaling size.

Equations (1)

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A = 2 γ 1 δ 1 ( ω ω 1 ) 2 + ( γ 1 + δ 1 ) 2 + 2 γ 2 δ 2 ( ω ω 2 ) 2 + ( γ 2 + δ 2 ) 2
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