Jack Sugar, Victor Kaufman, and William L. Rowan, "Spectra of the P i isoelectronic sequence from Co xiii to Mo xxviii," J. Opt. Soc. Am. B 8, 22-26 (1991)
Phosphoruslike spectra Cu xv to Mo xxviii have been identified in tokamak- and laser-produced plasmas in the wavelength range of 83 to 163 Å. These were obtained with the TEXT tokamak at the University of Texas and the 1-GW Nd:glass laser at the National Institute of Standards and Technology, using 2.2- and 10.7-m grazing-incidence spectrographs, respectively. Wavelength measurements were made with an uncertainty of ±0.005 Å. All the classified lines arise from the 3s23p3–3s23p23d array. They were identified through detailed comparisons with Hartree–Fock calculations of wavelengths and relative intensities along the isoelectronic sequence. All spectra from Cu to Mo were observed, except for Rb and Sr, whose wavelengths are predicted by interpolation with an uncertainty of ±0.02 Å. By means of previously observed magnetic-dipole (M1) lines within the 3s23p3 ground configuration and comparisons with published Dirac–Fock calculations, all the energy levels of this configuration were determined with an uncertainty of ±10 to 100 cm−1 for Co to Mo. These levels were used to predict all the M1 wavelengths. A correction to the Co xiv ground configuration is made by means of a previously published list of M1 lines.
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Wavelengths > 2000 Å are values in air. Newly predicted values are preceded by the symbol *. The rest are observed values from the compilation (Ref. 10).
Value in Ref. 10 of 944.6(2) is replaced by predicted wavelength.
Value in Ref. 10 of 1319.1(3) is replaced by predicted wavelength.
Value in Ref. 10 of 1660.4(2) is replaced by predicted wavelength.
Value in Ref. 10 of 1292.4(2) is replaced by predicted wavelength.
Value in Ref. 10 of 569.2(5) is replaced by predicted wavelength.
Value in Ref. 10 of 912.0(3) is replaced by predicted wavelength.
Value in Ref. 10 of 914.7(10) is replaced by predicted wavelength.
Value in Ref. 10 of 2717.8(3) is replaced by predicted wavelength.
Value in Ref. 10 of 812.1(2) is replaced by predicted wavelength.
Table 2
Percentage Composition of the Levels of the 3s23p3 Ground Configuration with J = 3/2
J = 3/2 Levels
Ni xiv Eigenstates
Zn xvi Eigenstates
Ge xviii Eigenstates
Se xx Eigenstates
Kr xxii Eigenstates
Sr xxiv Eigenstates
Zr xxvi Eigenstates
Mo xxviii Eigenstates
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
95
4
1
91
7
2
86
11
3
78
16
6
69
22
9
61
27
12
53
31
16
47
35
18
2P∘
3
81
16
4
77
19
5
73
22
6
69
24
8
66
26
9
64
27
10
62
28
11
61
28
2D∘
2
14
84
5
16
79
9
16
75
16
14
70
23
12
65
31
9
60
37
7
56
42
5
53
Table 3
Observed Spectraa of the P i Isoelectronic Sequence for Cu xv to As xix
Cu xv
Zn xvi
Ga xvii
Ge xviii
As xix
Transition
Wavelength
Intensity
Wavelength
Intensity
Wavelength
Intensity
Wavelength
Intensity
Wavelength
Intensity
3s23p3 − 3s2(3p2)3d
154.713
200
146.223
200
(138.491)
m
131.450
100
124.104
20
158.944
10
150.534
5
(142.973)
136.114
30
129.871
10
(159.308)
(149.767)
(141.163)
133.389
3
126.358
5
159.677
1
(150.694)
(142.526)
135.026
5
128.129
10
160.143
10
150.838
3
142.397
10
(134.720)
m
127.668
3
161.381
40
152.392
50
144.213
20
136.705
30
129.784
10
161.852
5
(152.562)
(144.178)
136.584
3
(129.714)
163.274
2
153.802
5
(145.222)
(137.369)
(130.145)
Wavelengths are in angstroms; those given in parentheses are calculated values corrected with the O—C curves. Intensities are visually estimated from the plate blackening. The symbol m means masked by an inpurity line.
Table 4
Observed Spectraa of the P i Isoelectronic Sequence for Se xx to Sr xxiv
Wavelengths are in angstroms; those given in parentheses are calculated values corrected with the O—C curves. Intensities are visually estimated from the plate blackening. The symbol m means masked by an inpurity line.
Blended with Br xx line.
Blended with Br xxii line.
Blended with Kr xxiii line.
Table 5
Observed Spectraa of the P i Isoelectronic Sequence for Y xxv to Mo xxviii
Wavelengths are in angstroms; those given in parentheses are calculated values corrected with the O—C curves. Intensities are visually estimated from the plate blackening. The symbol bl means blend; m means masked by an impurity line.
Blended with Mo xxx line.
Table 6
Energy Levelsa of Copper to Bromine Ions in the P i Isoelectronic Sequence (in units of cm−1)
J
Cu xv
Zn xvi
Ga xvii
Ge xviii
As xix
Se xx
Br xxi
3s23p3 4S∘
3/2
0
0
0
0
0
0
0
2D∘
3/2
47 940
50 266
52 916
56 117
59 938
64 687
70 601
5/2
57803
62 488
67 727
73 646
80 380
88 071
96 897
2P∘
1/2
91106
97579
104 622
112 334
120 916
130 426
141 103
3/2
105 962
116 594
128 577
142 132
157 462
174 780
194 400
3s2(3p2)3d (3P)4P
5/2
619 652
656 202
(693 419)
731 502
770 511
810 830
852 400
3/2
626 264
(663 600)
(701 630)
740 598
780 463
821 820
864 360
(1D)2D
3/2
672 380
713 229
755 178
(798 400)
843 220
889 690
938 330
5/2
675 651
(717 970)
(761 320)
805 800
851 340
897 910
945 510
(1D)2P
3/2
703 573
747 766
(793 220)
(840 300)
(889 290)
(3P)2F
7/2
704 207
746 375
(789 800)
834 392
886 155
928 220
977 870
(3P)2D
5/2
735 114
780 896
(828 010)
876 810
927 457
980 300
103 5580
Level values in parentheses are derived from interpolated or extrapolated O—C values.
Table 7
Energy Levelsa of Krypton to Molybdenum Ions in the P i Isoelectronic Sequence (in units of cm−1)
J
Kr xxii
Rb xxiii
Sr xxiv
Y xxv
Zr xxvi
Nb xxvii
Mo xxviii
3s23p3 4S∘
3/2
0
0
0
0
0
0
0
2D∘
3/2
77 801
(86 478)
(96 817)
108 950
122 960
138 940
156 960
5/2
106 960
(118 418)
(131 405)
146 014
162 350
180 560
200 710
2P∘
1/2
153 025
(166 341)
(181 025)
197 666
215 890
235 940
257 940
3/2
216 479
(241 259)
(268 821)
299 843
334 070
371 870
413 440
3s2(3p2)3d (3P)4P
5/2
895 500
(940 230)
(986 710)
1035 140
1085 730
1138 630
1193 940
3/2
908 570
(954 380)
(1002 160)
1052 130
1104 860
1160 860
(1220 300)
(1D)2D
3/2
989 810
(1043 700)
(1100 690)
1161 080
1224 500
1291 620
(1362 610)
5/2
995 430
(1048 200)
(1104 190)
1163 910
1226 860
1293 690
1364 420
(3P)2F
7/2
1029 790
(1084 080)
(1140 930)
1200 760
1263 890
1330 590
1401 070
(3P)2D
5/2
1093 630
(1154 420)
(1218 050)
(1285 360)
(1355 910)
1430 380
1508 720
Level values in parentheses are derived from interpolated or extrapolated O—C values.
Tables (7)
Table 1
Wavelengths (in Å)a for All M1 Transitions within the 3s23p3 Ground Configuration of P-like Fe through Mo
Wavelengths > 2000 Å are values in air. Newly predicted values are preceded by the symbol *. The rest are observed values from the compilation (Ref. 10).
Value in Ref. 10 of 944.6(2) is replaced by predicted wavelength.
Value in Ref. 10 of 1319.1(3) is replaced by predicted wavelength.
Value in Ref. 10 of 1660.4(2) is replaced by predicted wavelength.
Value in Ref. 10 of 1292.4(2) is replaced by predicted wavelength.
Value in Ref. 10 of 569.2(5) is replaced by predicted wavelength.
Value in Ref. 10 of 912.0(3) is replaced by predicted wavelength.
Value in Ref. 10 of 914.7(10) is replaced by predicted wavelength.
Value in Ref. 10 of 2717.8(3) is replaced by predicted wavelength.
Value in Ref. 10 of 812.1(2) is replaced by predicted wavelength.
Table 2
Percentage Composition of the Levels of the 3s23p3 Ground Configuration with J = 3/2
J = 3/2 Levels
Ni xiv Eigenstates
Zn xvi Eigenstates
Ge xviii Eigenstates
Se xx Eigenstates
Kr xxii Eigenstates
Sr xxiv Eigenstates
Zr xxvi Eigenstates
Mo xxviii Eigenstates
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
2P∘
2D∘
4S∘
95
4
1
91
7
2
86
11
3
78
16
6
69
22
9
61
27
12
53
31
16
47
35
18
2P∘
3
81
16
4
77
19
5
73
22
6
69
24
8
66
26
9
64
27
10
62
28
11
61
28
2D∘
2
14
84
5
16
79
9
16
75
16
14
70
23
12
65
31
9
60
37
7
56
42
5
53
Table 3
Observed Spectraa of the P i Isoelectronic Sequence for Cu xv to As xix
Cu xv
Zn xvi
Ga xvii
Ge xviii
As xix
Transition
Wavelength
Intensity
Wavelength
Intensity
Wavelength
Intensity
Wavelength
Intensity
Wavelength
Intensity
3s23p3 − 3s2(3p2)3d
154.713
200
146.223
200
(138.491)
m
131.450
100
124.104
20
158.944
10
150.534
5
(142.973)
136.114
30
129.871
10
(159.308)
(149.767)
(141.163)
133.389
3
126.358
5
159.677
1
(150.694)
(142.526)
135.026
5
128.129
10
160.143
10
150.838
3
142.397
10
(134.720)
m
127.668
3
161.381
40
152.392
50
144.213
20
136.705
30
129.784
10
161.852
5
(152.562)
(144.178)
136.584
3
(129.714)
163.274
2
153.802
5
(145.222)
(137.369)
(130.145)
Wavelengths are in angstroms; those given in parentheses are calculated values corrected with the O—C curves. Intensities are visually estimated from the plate blackening. The symbol m means masked by an inpurity line.
Table 4
Observed Spectraa of the P i Isoelectronic Sequence for Se xx to Sr xxiv
Wavelengths are in angstroms; those given in parentheses are calculated values corrected with the O—C curves. Intensities are visually estimated from the plate blackening. The symbol m means masked by an inpurity line.
Blended with Br xx line.
Blended with Br xxii line.
Blended with Kr xxiii line.
Table 5
Observed Spectraa of the P i Isoelectronic Sequence for Y xxv to Mo xxviii
Wavelengths are in angstroms; those given in parentheses are calculated values corrected with the O—C curves. Intensities are visually estimated from the plate blackening. The symbol bl means blend; m means masked by an impurity line.
Blended with Mo xxx line.
Table 6
Energy Levelsa of Copper to Bromine Ions in the P i Isoelectronic Sequence (in units of cm−1)
J
Cu xv
Zn xvi
Ga xvii
Ge xviii
As xix
Se xx
Br xxi
3s23p3 4S∘
3/2
0
0
0
0
0
0
0
2D∘
3/2
47 940
50 266
52 916
56 117
59 938
64 687
70 601
5/2
57803
62 488
67 727
73 646
80 380
88 071
96 897
2P∘
1/2
91106
97579
104 622
112 334
120 916
130 426
141 103
3/2
105 962
116 594
128 577
142 132
157 462
174 780
194 400
3s2(3p2)3d (3P)4P
5/2
619 652
656 202
(693 419)
731 502
770 511
810 830
852 400
3/2
626 264
(663 600)
(701 630)
740 598
780 463
821 820
864 360
(1D)2D
3/2
672 380
713 229
755 178
(798 400)
843 220
889 690
938 330
5/2
675 651
(717 970)
(761 320)
805 800
851 340
897 910
945 510
(1D)2P
3/2
703 573
747 766
(793 220)
(840 300)
(889 290)
(3P)2F
7/2
704 207
746 375
(789 800)
834 392
886 155
928 220
977 870
(3P)2D
5/2
735 114
780 896
(828 010)
876 810
927 457
980 300
103 5580
Level values in parentheses are derived from interpolated or extrapolated O—C values.
Table 7
Energy Levelsa of Krypton to Molybdenum Ions in the P i Isoelectronic Sequence (in units of cm−1)
J
Kr xxii
Rb xxiii
Sr xxiv
Y xxv
Zr xxvi
Nb xxvii
Mo xxviii
3s23p3 4S∘
3/2
0
0
0
0
0
0
0
2D∘
3/2
77 801
(86 478)
(96 817)
108 950
122 960
138 940
156 960
5/2
106 960
(118 418)
(131 405)
146 014
162 350
180 560
200 710
2P∘
1/2
153 025
(166 341)
(181 025)
197 666
215 890
235 940
257 940
3/2
216 479
(241 259)
(268 821)
299 843
334 070
371 870
413 440
3s2(3p2)3d (3P)4P
5/2
895 500
(940 230)
(986 710)
1035 140
1085 730
1138 630
1193 940
3/2
908 570
(954 380)
(1002 160)
1052 130
1104 860
1160 860
(1220 300)
(1D)2D
3/2
989 810
(1043 700)
(1100 690)
1161 080
1224 500
1291 620
(1362 610)
5/2
995 430
(1048 200)
(1104 190)
1163 910
1226 860
1293 690
1364 420
(3P)2F
7/2
1029 790
(1084 080)
(1140 930)
1200 760
1263 890
1330 590
1401 070
(3P)2D
5/2
1093 630
(1154 420)
(1218 050)
(1285 360)
(1355 910)
1430 380
1508 720
Level values in parentheses are derived from interpolated or extrapolated O—C values.