Table 1
Relative Terms in the Yi Spectrum
Term Symbol | Term Value | | Interval | Combinations |
---|
2D2 | 00.0 |
| | |
| | 530.4 | a2P, b2P, a2D′, b2D′, c2D′, a2F, b2F, c2F, 4D′, 4F, 4G′ |
2D3 | 530.4 | | |
4F2′ | 10937.3 |
| | |
| | 141.3 | 4D′, 4F, 4G′, c2D′, b2F, c2F |
4F3′ | 11078.6 | | |
| | 199.4 | |
4F4′ | 11278.0 | | |
| | 254.1 | |
4F5′ | 11532.1 | | |
a2D3′ | 16066.0 |
| | 2D |
| | − 80.1 | |
a2D2′ | 16146.1 | | |
a2F3 | 21528.5 |
| | 2D |
| | 387.1 | |
a2F4 | 21915.6 | | |
b2D2′ | 24131.1 |
| | 2D |
| | 615.3 | |
a2P2 | 24480.6 | | 2D |
| | −218.1 | |
b2F3 | 24518.5 | | 2D, 4F′ |
a2P1 | 24698.7 | | |
| | 381.0 | |
b2D3′ | 24746.4 | | |
b2F4 | 24899.5 | | |
b2P1 | 27824.8 |
| | 2D |
| | 314.8 | |
b2P2 | 28139.6 | | |
4G3′ | 28694.0 |
| | 2D, 4F′ |
| | 294.7 | |
4G4′ | 28988.7 | | |
| | 375.5 | |
4G5′ | 29364.2 | | |
| | 456.2 | |
4G6′ | 29820.4 | | |
4F2 | 31508.5 |
| | 2D, 4F′ |
| | 171.5 | |
4F3 | 31680.0 | | |
| | 229.1 | |
4F4 | 31909.1 | | |
| | 279.0 | |
4F5 | 32188.1 | | |
4D1′ | 33215.3 |
| | 2D, 4F′ |
| | 50.1 | |
4D2′ | 33265.4 | | |
| | 92.3 | |
4D3′ | 33357.7 | | |
| | 256.8 | |
c2F3 | 33608.4 | | 2D, 4F′ |
4D4′ | 33614.5 | | |
| | 421.3 | |
c2D2′ | 33906.9 | | 2D, 4F′ |
c2F4 | 34029.7 | 340.8 | |
c2D3′ | 34247.7 | | |
Table 2
Multiplets in the Yi Spectrum
| | 2D3 | | 530.4 | | 2D2 | |
---|
c2D3′ | | 2964.96 (30, ii) | | | | 2919.06 (20, ii) | |
| | 33717.49 | | | | 34247.63 | |
340.8 | | | | | | | |
c2D2′ | | 2995.25 (10, iii) | | | | 2948.39 (30, ii) | |
| | 33376.50 | | | | 33906.92 | |
|
c2F4 | | 2984.26 (50, ii) | | | | | |
| | 33499.38 | | | | | |
421.3 | | | | | | | |
c2F3 | | 3022.27 (12, ii) | | | | 2974.58 (35, ii) | |
| | 33078.09 | | | | 33608.37 | |
|
b2P2 | | 3620.95 (400, ii) | | | | 3552.70 (40, i) | |
| | 27609.21 | | | | 28139.61 | |
314.8 | | | | | | | |
b2P1 | | . | | | | 3592.90(200, ii) | |
| | | | | | 27824.78 | |
|
b2F4 | | * 4102.42 (350, ii) | | | | | |
| | 24369.03 | | | | | |
381.0 | | | | | | | |
b2F3 | | 4167.57 (100, ii) | | | | * 4077.39 (300, ii) | |
| | 23988.06 | | | | 24518.58 | |
|
b2D3′ | | 4128.35 (300, ii) | | | | 4039.84(60, ii) | |
| | 24215.95 | | | | 24746.47 | |
615.3 | | | | | | | |
b2D2′ | | 4235.94 (100, ii) | | | | 4142.88 (200, ii) | |
| | 23600.88 | | | | 24131.04 | |
|
a2P2 | | 4174.18 (100, ii) | | | | 4083.72 (100, ii) | |
| | 23950.08 | | | | 24480.58 | |
−218.1 | | | | | | | |
a2P1 | | | | | | 4047.66 (80, ii) | |
| | | | | | 24698.68 | |
|
a2F4 | | 4674.85 (125, i) | | | | | |
| | 21385.11 | | | | | |
387.1 | | | | | | | |
a2F3 | | 4761.02 (40, i) | | | | 4643.68 (150, i) | |
| | 20998.04 | | | | 21528.62 | |
|
a2D3′ | | 6435.030 (500, i) | | | | 6222.585 (250, ia) | |
| | 15535.66 | | | | 16066.05 | |
−80.1 | | | | | | | |
a2D2′ | | 6402.025 (200, ia) | | | | 6191.726 (500, ia) | |
| | 15615.75 | | | | 16146.13 | |
|
4D4′ | | 3021.70 (15, ii) | | | | | |
| | 33084.32 | | | | | |
256.8 | | | | | | | |
4D3′ | | 3045.36 (20, ii) | | | | 2996.93 (20, iii) | |
| | 32827.36 | | | | 33357.80 | |
92.3 | | | | | | | |
4D2′ | | ……. ? | | | | 3005.24 (12, iii) | |
| | 32735.1 | | | | 33265.58 | |
50.1 | | | | | | | |
4D1′ | | | | | | ……. ? | |
| | | | | | 33215.4 | |
|
4F5 | | | | | | | |
279.0 | | | | | | | |
4F4 | | 3185.93 (2, iiia) | | | | | |
| | 31378.95 | | | | | |
229.1 | | | | | | | |
4F3 | | 3209.38 (1) | | | | 3155.62 (3, iiia) | |
| | 31149.74 | | | | 31680.36 | |
171.6 | | | | | | | |
4F2 | | ……. ? | | | | 3172.85 (4, iiia) | |
| | 30978.1 | | | | 31508.37 | |
|
4G6′ | | | | | | | |
456.2 | | | | | | | |
4G5′ | | | | | | | |
375.5 | | | | | | | |
4G4′ | | 3512.88 (20, iii) | | | | | |
| | 28458.57 | | | | | |
294.7 | | | | | | | |
4G3′ | | ……. ? | | | | 3484.05 (10, iii) | |
| | 28163.9 | | | | 28694.07 | |
|
| 4F5′ | 254.1 | 4F4′ | 199.4 | 4F3′ | 141.3 | 4F2′ |
|
c2D3′ | | | 4352.34 (5, iii) | | 4314.92 (1) | | |
| | | 22969.71 | | 23168.90 | | |
340.8 | | | | | | | |
c2D2′ | | | | | 4379.33 (6, iii) | | 4352.34 (5 iii)d? |
| | | | | 22828.13 | | 22969.71 |
|
c2F4 | | 4443.66 (15, iii) | 4394.03 (3, iii) | | ……. ? | | |
| | 22497.69 | 22751.79 | | 22951.1 | | |
421.3 | | | | | | | |
c2F3 | | | 4476.92 (25, iii) | | 4437.32 (10, iii) | | 4409.71 (1) |
| | | 22330.55 | | 22529.83 | | 22670.91 |
Table 3
Relative terms in the Yii Spectrum
Term Symbol | Term value | | Interval | Combination |
---|
3D1 | 00.0 |
| | a3P, 3F, 3D′, b3P, 1P, 1D′, 1F |
| | 204.9 | |
3D2 | 204.9 | | |
| | 404.8 | |
3D3 | 609.7 | | |
a1D2 | 2456.4 | | | a3P, 3F, 3D′, b3P, 1D′, 1F |
3F2′ | 7163.1 |
| | 3F, 3D′, 1P, 1D′ |
| | 324.9 | |
3F3′ | 7488.0 | | |
| | 415.4 | |
3F4′ | 7903.4 | | |
3P0′ | 13043.3 |
| | 3D′, b3P, 1F |
| | 135.1 | |
3P1′ | 13178.4 | | |
| | 79.8 | |
3P2′ | 13258.2 | | |
b1D2 | 13992.7 | | | 3D′,b3P, 1P,1F |
a3P0 | 22604.8 |
| | 3D, 3P′, a1D, b3P |
| | 331.3 | |
a3P1 | 22936.0 | | |
| | 870.9 | |
a3P2 | 23806.9 | | |
1D2′ | 25307.1 | | | 3D, 3F′, a1D |
3F2 | 26387.0 |
| | 3D, 3F′, a1D |
| | 305.4 | |
1P1 | 26676.6 | | 3D, 3F′, 3P′, b1D |
3F3 | 26692.4 | | |
| | 861.6 | |
3F4 | 27554.0 | | |
3D1′ | 27755.3 |
| | 3D, 3F′, 3P′, a1D, b1D |
| | 134.7 | |
3D2′ | 27890.0 | | |
| | 484.0 | |
3D3′ | 28374.0 | | |
b3P0 | 31208.5 |
| | 3D, 3P′, a1D, b1D |
| | 75.3 | |
b3P1 | 31283.8 | | |
| | 159.5 | |
b3P2 | 31443.3 | | |
1F3 | 32496.8 | | | 3D, 3P′, a1D, b1D |
Table 4
Multiplets in the Y ii Spectrum
| 3P2′ | 79.8 | 3P1′ | 135.1 | 3P0′ |
---|
b3P2 | 5497.39 (25, ve) | | 5473.36 (10 ve) | | |
| 18185.43 | | 18265 24 | | |
159.5 | | | | | |
b3P1 | 5546.03 (3, ve) | | 5521.61 (30, ii & e) | | 5480.71 (8, ve) |
| 18025.91 | | 18105.64 | | 18240.75 |
75.3 | | | | | |
b3P0 | | | 5544.58 (25, iii & e) | | |
| | | 18030.62 | | |
|
a1D2– 1F3 | 3327.88 (150, iiie) | | | | |
| 30040.59 | | | | |
|
a1D–1P1 | ……. ? | | | | |
| 24220.2 | | | | |
|
a1D2–1D2′ | 4374.95 (300, iiie) | | | | |
| 22851.04 | | | | |
|
b1D2–1F3 | 5402.77 (20, ve) | | | | |
| 18503.88 | | | | |
|
b1D2–1P1 | 7881.90 (5, e) | | | | |
| 12683.82 | | | | |
|
| a3P2 | 870.9 | a3P1 | 331.3 | a3P0 |
a1D2 | 4682.31 (20, ve) | | 4881.45 (10 -) | | |
| 21351.01 | | 20480.01 | | |
|
| 3F4 | 861.6 | 3F3 | 305.4 | 3F2 |
a1D2 | | | 4124.95 (20, iiie) | | 4177.58 (125 iiie) |
| | | 24235.90 | | 23930.60 |
|
| 3D3′ | 484.0 | 3D2′ | 134.7 | 3D1′ |
a1D2 | ……. ? | | 3930.66 (10, ve) | | 3951.61 (8 ve) |
| 25917.6 | | 25433.84 | | 25299.03 |
|
| b3P2 | 159.5 | b3P1 | 75.3 | b3P0 |
a1D2 | 3448.85 (35, ve) | | 3467.98 (20, ve) | | |
| 28986.94 | | 28827.00 | | |
|
| 3D3 | 404.8 | 3D2 | 204.9 | 3D1 |
1P1 | | | 3776.57 (40, iiie) | | 3747.55 (20, iiie) |
| | | 26471.55 | | 26676.56 |
|
1D2′ | ……. ? | | 3982.64 (100, iiie) | | 3950.37 (150, iiie) |
| 24697.4 | | 25101.91 | | 25306.98 |
|
1F3 | 3135.17 (25, ve) | | 3095.88 (25, ve) | | |
| 31886.94 | | 32291.61 | | |
|
| 3F4′ | 415.4 | 3F3′ | 324.9 | 3F2′ |
1D2′ | | | 5610.36 (1 -) | | 5509.88 (40, ve) |
| | | 17819.25 | | 18144.18 |
|
1F3 | 4065.04(2 -) | | ……. ? | | 3946.22 (2 -) |
| 24593.11 | | 25008.6 | | 25333.58 |
|
1P1 | | | | | 5123.21 (40, ve) |
| | | | | 19513.61 |
|
| 3P2′ | 79.8 | 3P1′ | 135.1 | 3P0′ |
1P1 | 7450.35 (5 -) | | 7406.23 (2 -) | | 7332.96 (2 -) |
| 13418.50 | | 13498.42 | | 13633.31 |
|
1F3 | 5196.44 (2, ve) | | | | |
| 19238.62 | | | | |
|
| 3D3′ | 484.0 | 3D2′ | 134.7 | 3D1′ |
b1D2 | 6951.69 (3 -) | | 7193.74(1 -) | | 7264.14 (7 -) |
| 14381.04 | | 13897.15 | | 13762.46 |
|
| b3P2 | 159.5 | b3P1 | 75.3 | b3P0 |
b1D2 | 5728.90 (3, ve) | | 5781.68 (2 ve) | | |
| 17450.54 | | 17291.23 | | |
Table 5
Multiplets in the Zr i spectrum.
| 3F2 | 570.45 | 3F3 | 670.40 | 3F4 |
---|
3D3 | ……. ? | | 3766.72 | | 3864.33 (5) |
| 27111.21 | | 26540.76 | | 25870.41 |
553.90 | | | | | |
3D2 | 3764.38 (6) | | 3847.01 (5) | | |
| 26557.25 | | 25986.85 | | |
403.06 | | | | | |
3D1 | 3822.40(6) | | | | |
| 26154.19 | | | | |
|
3F4′ | | | 3791.40 (3) | | 3890.32 (7) |
| | | 26368.04 | | 25697.56 |
494.52 | | | | | |
3F3′ | 3780.53 (6) | | 3863.87 (7) | | 3966.65 (6) |
| 26443.83 | | 25873.49 | | 25203.07 |
382.17 | | | | | |
3F2′ | 3835.96 (7) | | 3921.81 (6) | | |
| 26061.76 | | 25491.22 | | |
|
3G5 | | | | | * 3601.18 (8) |
| | | | | 27760.81 |
251.78 | | | | | |
3G4 | | | * 3547.69 (8) | | 3634.14 (6) |
| | | 28179.33 | | 27509.03 |
345.54 | | | | | |
3G3 | * 3519.60 (8) | | 3591.72 (5) | | 3680.39 (3) |
| 28404.25 | | 27833.91 | | 27163.36 |
|
5D4 | | | 3353.15 (1) | | 3430.29 (3) |
| | | 29814.17 | | 29143.72 |
297.17 | | | | | |
5D3 | ……. ? | | 3386.90 (1) | | 3465.63 (4) |
| 30087.5 | | 29517.07 | | 28846.54 |
239.77 | | | | | |
5D2 | ……. ? | | 3414.64 (5) | | |
| 29847.5 | | 29277.19 | | |
170.36 | | | | | |
5D1 | 3368.64 (3) | | | | |
| 29677.11 | | | | |
|
| 5F1 152.86 | 5F2 225.66 | 5F3 291.46 | 5F4 448.43 | 5F5 |
|
5D4 | | | 3977.33 (2) | 4024.00 (5) | 4081.24 (8) |
| | | 25135.42 | 24843.92 | 24495.45 |
297.17 | | | | | |
5D3 | | 3988.69 (3) | 4024.93 (5) | 4072.71 (8) | |
| | 25063.85 | 24838.18 | 24546.75 | |
239.77 | | | | | |
5D2 | 4002.56(3) | 4027.21 (6) | 4064.17 (7) | | |
| 24976.96 | 24824.12 | 24598.37 | | |
170.36 | | | | | |
5D1 | 4030.04 (5) | 4055.04 (6) | | | |
| 24806.63 | 24653.74 | | | |
89.09 | | | | | |
5D0 | 4044.57 (5) | | | | |
| 24717.54 | | | | |
|
5F5′ | | | | 4166.37 (5) | 4227.79 (8) |
| | | | 23994.97 | 23646.36 |
412.78 | | | | | |
5F4′ | | | 4187.56 (6) | 4239.32 (6) | 4302.88 (8) |
| | | 23873.59 | 23582.06 | 23233.71 |
304.55 | | | | | |
5F3′ | | 4201.46 (5) | 4241.68 (5) | 4294.78 (8) | |
| | 23794.57 | 23568.96 | 23277.58 | |
222.98 | | | | | |
5F2′ | 4213.87 (5) | 4241.20 (5) | 4282.20 (6) | | |
| 23724.51 | 23571.62 | 23345.94 | | |
148.15 | | | | | |
5F1′ | 4240.36 (5) | 4268.01 (8) | | | |
| 23576.28 | 23423.54 | | | |
|
5G6 | | | | | 4687.81 (8) |
| | | | | 21325.96 |
449.26 | | | | | |
5G5 | | | | 4710.08 (8) | 4788.70 (7) |
| | | | 21225.16 | 20876.70 |
423.06 | | | | | |
5G4 | | | 4739.49 (8) | 4805.89 (7) | 4887.72 (1) |
| | | 21093.45 | 20802.00 | 20453.74 |
370.82 | | | | | |
5G3 | | 4772.33 (8) | 4824.30 (7) | 4893.12 (5) | |
| | 20948.29 | .20722.64 | 20431.18 | |
341.24 | | | | | |
5G2 | 4815.62 (7) | 4851.36 (6) | 4905.07 (5) | | |
| 20759.98 | 20607.04 | 20381.41 | | |
Table 6
Multiplets in the Zr ii Spectrum
| 4F2 314.69 | 4F3 448.74 | 4F4 559.37 | 4F5 |
---|
4D4 | | 3068.02 (2) | 3110.87 (6) | 3165.98 (7) |
| | 32584.87 | 32136.06 | 31576.69 |
284.70 | | | | |
4D3 | 3065.20 (2) | 3095.07 (6) | 3138.67 (7) | |
| 32614.85 | 32300.10 | 31851.43 | |
358.00 | | | | |
4D2 | 3099.22 (6) | 3129.76 (6) | | |
| 32256.85 | 31942.10 | | |
275.51 | | | | |
4D1 | 3125.92 (6) | | | |
| 31981.34 | | | |
|
4F5′ | | | 3214.19 (6) | 3273.04 (8) |
| | | 31103.08 | 30543.86 |
617.15 | | | | |
4F4′ | | 3231.69 (6) | 3279.25 (7) | 3340.55 (6) |
| | 30934.66 | 30486.02 | 29926.61 |
697.78 | | | | |
4F3′ | 3272.21 (5) | 3306.27 (7) | 3356.07 (7) | |
| 30551.61 | 30236.89 | 29788.23 | |
773.88 | | | | |
4F2′ | 3357.25 (6) | 3393.12 (5) | | |
| 29777.76 | 29462.97 | | |
|
4G6 | | | | * 3391.95 (8) |
| | | | 29473.14 |
956.05 | | | | |
4G5 | | | * 3438.22 (8) | 3505.67 (5) |
| | | 29076.51 | 28517.09 |
930.88 | | | | |
4G4 | | * 3496.18 (8) | 3551.94 (6) | 3623.97 (1) |
| | 28594.50 | 28145.62 | 27586.21 |
925.10 | | | | |
4G3 | * 3572.48 (8) | 3613.08 (6) | 3672.65 (3) | |
| 27983.80 | 27669.35 | 27220.58 | |
|
| | 2D′2 | 257.21 | 2D′3 | |
|
2P′2 | | 3157.00 (5) | | 3182.86 (7) | |
| | 31666.50 | | 31409.23 | |
−281.63 | | | | | |
2P′1 | | 3129.17 (6) | | | |
| | 31948.13 | | | |
|
2D3 | | 3714.77 (6) | | 3750.64 (5) | |
| | 26911.94 | | 26654.57 | |
724.63 | | | | | |
2D2 | | 3817.59 (6) | | 3855.43 (3) | |
| | 26187.13 | | 25930.12 | |
|
2F′4 | | | | 3836.76 (9) | |
| | | | 26056.29 | |
1056.96 | | | | | |
2F′3 | | 3958.24 (9) | | 3998.98 (8) | |
| | 25256.63 | | 24999.33 | |
|
4G4 | | | | 4096.63 (4) | |
| | | | 24403.44 | |
925.10 | | | | | |
4G3 | | 4211.88 (6) | | 4258.05 (6) | |
| | 23735.70 | | 23478.34 | |
Table 7
Multiplets in the Cb i Spectrum.
| 6D5 | 355.0 | 6D4 | 303.4 | 6D3 | 237.8 | 6D2 | 154.1 | 6D1 |
---|
b6P4 | 3580.27 (15) | 3535.28 (10) | 3497.77 (3) | | | |
| 27922.9 | | 28278.2 | | 28581.5 | | | | |
320.8 | | | | | | | | | |
b6P3 | | | 3575.85 (10) | 3537.50 (10) | 3507.93 (4) | |
| | | 27957.4 | | 28260.5 | | 28498.7 | | |
374.4 | | | | | | | | | |
b6P2 | | | | | 3584.95 (4) | 3554.59 (15d) | 3535.28 (10d?) |
| | | | | 27886.4 | | 28124.6 | | 28278.2 |
|
b6D5 | 3554.59 (15d) | 3510.25 (3) | | | | | |
| 28124.6 | | 28479.9 | | | | | | |
625.6 | | | | | | | | | |
b6D4 | 3635.44 (2) | 3589.08 (5) | 3550.43 (5) | | | |
| 27499.2 | | 27854.4 | | 28157.6 | | | | |
104.0 | | | | | | | | | |
b6D3 | | | 3602.55 (6) | 3563.56 (15d) | 3533.64 (3) | |
| | | 27750.2 | | 28053.9 | | 28291.3 | | |
237.3 | | | | | | | | | |
b6D2 | | | | | 3593.95 (6) | 3563.56 (15d) | 2544.00 (8) |
| | | | | 27816.6 | | 28053.9 | | 28208.6 |
201.7 | | | | | | | | | |
b6D1? | | | | | | | 3589.34 (5) | 3569.45 (3) |
| | | | | | | 27852.4 | | 28007.6 |
Table 8
Multiplets in the Cb ii Spectrum
| 5F5 | 603.6 | 5F4 | 512.9 | 5F3 | 401.0 | 5F2 | 272.3 | 5F1 |
---|
5D4 | 2927.83 (10) | 2876.98 (6) | 2835.14 (2) | | | |
| 34145.1 | | 34748.5 | | 35261.3 | | | | |
75.0 | | | | | | | | | |
5D3 | | | 2883.21 (6) | 2841.18 (3) | 2809.15 (1) | |
| | | 34673.5 | | 35186.4 | | 35587.4 | | |
418.8 | | | | | | | | | |
5D2 | | | | | 2875.39 (6) | 2842.67 (3) | 2820.83 (1) |
| | | | | 34767.7 | | 35167.9 | | 35440.1 |
316.8 | | | | | | | | | |
5D1 | | | | | | | 2868.52 (4) | 2846.27 (3) |
| | | | | | | 34851.0 | | 35123.5 |
182.2 | | | | | | | | | |
5D0 | | | | | | | | | 2861.22 (3) |
5D5′ | | | | | | | | | 34941.2 |
|
5F5′ | 2950.92 (10) | 2899.24 (5) | | | | | |
| 33877.9 | | 34481.7 | | | | | | |
495.7 | | | | | | | | | |
5F4′ | 2994.71 (6) | 2941.56 (8) | 2897.82 (5) | | | |
| 33382.5 | | 33985.6 | | 34498.6 | | | | |
151.7 | | | | | | | | | |
5F3′ | | | 2954.7 (1) | 2910.62 (6) | 2876.98 (6?) | |
| | | 33834.5 | | 34346.9 | | 34748.5 | | |
414.0 | | | | | | | | | |
5F2′ | | | | | 2946.13 (2) | 2911.77 (4) | 2888.82 (3) |
5F2′ | | | | | 33932.9 | | 34333.4 | | 34606.1 |
231.2 | | | | | | | | | |
5F1′ | | | | | | | 2931.48 (2) | 2908.26 (5) |
| | | | | | | 34102.5 | | 34374.8 |
|
5G6 | * 3094.20 (15) | | | | | | | |
| 32309.1 | | | | | | | | |
980.8 | | | | | | | | | |
5G5 | 3191.08 (4) | * 3130.79 (12) | | | | | |
| 31328.3 | | 31931.6 | | | | | | |
842.3 | | | | | | | | | |
5G4 | 3279.29 (1) | 3215.57 (6) | *3163.37 (10) | | | |
| 30485.7 | | 31089.7 | | 31602.8 | | | | |
713.1 | | | | | | | | | |
5G3 | | | 3291.04 (2) | 3236.43 (10) | *3194.95 (10) | |
| | | 30376.8 | | 30889.4 | | 31290.4 | | |
568.0 | | | | | | | | | |
5G2 | | | | | 3297.09 (1) | 3254.01 (6) | *3225.43 (10) |
| | | | | 30321.1 | | 30722.4 | | 30994.7 |
|
| 5D′4 | 423.6 | 5D′3 | 362.8 | 5D′2 | 279.6 | 5D′1 | 159.0 | 5D′0 |
|
5D4 | 2697.04 (8) | 2666.57 (3) | | | | | |
| 37066.7 | | 37490.2 | | | | | | |
75.0 | | | | | | | | | |
5D3 | 3702.50 (3) | 2671.91 (5) | 2646.25 (4) | | | |
| 36991.8 | | 37415.4 | | 37778.1 | | | | |
418.8 | | | | | | | | | |
5D2 | | | 2702.18 (3) | 2675.93 (3) | 2656.04 (3) | |
| | | 36996.2 | | 37359.2 | | 37638.8 | | |
316.8 | | | | | | | | | |
5D1 | | | | | 2698.85 (3) | 2678.64 (2) | 2667.27 (2) |
| | | | | 37041.8 | | 37321.4 | | 37480.4 |
182.2 | | | | | | | | | |
5D0 | | | | | | | 2691.75 (2) | |
| | | | | | | 37139.5 | | |
|
5F′5 | 2716.59 (4) | | | | | | | |
| 36800.0 | | | | | | | | |
495.7 | | | | | | | | | |
5F′4 | 2753.71 (1) | 2721.97 (5) | | | | | |
| 36303.9 | | 36727.3 | | | | | | |
151.7 | | | | | | | | | |
5F′3 | 2765.27 (2) | 3733.22 (2) | 2706.39 (3) | | | |
| 36152.1 | | 36576.0 | | 36938.6 | | | | |
414.0 | | | | | | | | | |
5F′2 | | | 2764.56 (2) | 2737.05 (3) | 2716.27 (2) | |
| | | 36161.5 | | 36524.8 | | 36804.3 | | |
231.2 | | | | | | | | | |
5F′1 | | | | | 2754.54 (2) | 2733.45 (1) | 2721.63 (2) |
| | | | | 36293.0 | | 36573.0 | | 36731.8 |
Table 9
Multiplets in the Mo i Spectrum
| 5D0 | 176.94 | 5D1 | 311.53 | 5D2 | 404.12 | 5D3 | 487.90 | 5D4 |
---|
5F5 | | | | | | | | | 3405.93 (7) |
| | | | | | | | | 29352.20 |
303.00 | | | | | | | | | |
5F4 | | | | | | | 3384.62 (8) | 3441.45 (3) |
| | | | | | | 19536.95 | | 29049.25 |
171.14 | | | | | | | | | |
5F3 | | | | | 3358.13 (9) | 3404.35 (3) | 3461.84 (1) |
| | | | | 29769.96 | | 29365.82 | | 28878.11 |
192.45 | | | | | | | | | |
5F2 | | | 3344.75 (8) | 3380.99 (7) | 3426.79 (3) | |
| | | 29889.02 | | 29577.31 | | 29173.49 | | |
20.21 | | | | | | | | | |
5F1 | 3327.31 (7) | 3347.02 (6) | 3382.29 (2) | | | |
| 30045.73 | | 29868.76 | | 29557.29 | | | | |
|
| 5P1′ | –123.30 | 5P2′ | –127.30 | 5P3′ | | | | |
|
5F4 | | | | | 4315.40 (1) | | | |
| | | | | 23166.33 | | | | |
171.14 | | | | | | | | | |
5F3 | | | ……. ? | 4347.47 (1) | | | |
| | | 22867.9 | 22995.43 | | | | |
192.45 | | | | | | | | | |
5F2 | 4432.89 (1) | 4408.81 (1) | 4384.20 (2) | | | |
| 22552.34 | | 2675.53 | | 22802.78 | | | | |
20.21 | | | | | | | | | |
6F1 | 4436.88 (3) | 4412.77 (4) | | | | | |
| 22532.06 | | 22655.14 | | | | | | |
|
| 5G2 | 51.88 | 5G3 | 54.88 | 5G4 | 36.70 | 5G5 | 43.81 | 5G6 |
|
5F5 | | | | | ……. ? | ……. ? | 4019.79 (3) |
| | | | | 24950.7 | | 24914.0 | | 24870.17 |
303.00 | | | | | | | | | |
5F4 | | | ……. ? | 4056.03 (5) | 4062.09 (6) | |
| | | 24702.6 | | 24647.72 | | 24610.96 | | |
171. 14 | | | | | | | | | |
5F3 | ……. ? | 4075.26 (3) | 4084.39 (8) | | | |
| 24583.3 | | 24531.39 | | 24476.57 | | | | |
192.45 | | | | | | | | | |
5F2 | 4098.75 (5) | 4107.48 (8) | | | | | |
| 24390.84 | | 24339.01 | | | | | | |
20.21 | | | | | | | | | |
5F1 | 4102.16 (7) | | | | | | | |
| 24370.57 | | | | | | | | |
Table 10
Multiplets in the Mo ii Spectrum
| 6D1 | 250.70 | 6D2 | 383.15 | 6D3 | 482.90 | 6D4 | 560.46 | 6D5 |
---|
6D5′ | | | | | | | 2644.36 (12) | 2684.15 (10) |
| | | | | | | 37805.02 | | 37244.64 |
402.90 | | | | | | | | | |
6D4′ | | | | | 2638.76 (10) | 2672.85 (10) | 2713.52 (5) |
| | | | | 37885.24 | | 37402.19 | | 36841.64 |
310.33 | | | | | | | | | |
6D3′ | | | ……. ? | 2660.58 (10) | 2694.19 (6) | |
| | | 37957.8 | | 37574.63 | | 37092.13 | | |
−200.00 | | | | | | | | | |
6D2′ | 2602.81 (5) | ……. ? | 2646.49 (8) | | | |
| 38408.51 | | 38157.8 | | 37774.63 | | | | |
242.47 | | | | | | | | | |
6D1′ | 2619.35 (3) | 2636.67 (8) | | | | | |
| 38166.04 | | 37915.41 | | | | | | |
|
6F6 | | | | | | | | | * 2816.16 (20) |
| | | | | | | | | 35498.89 |
960.27 | | | | | | | | | |
6F5 | | | | | | | * 2848.24 (12) | 2894.46 (5) |
| | | | | | | 35099.17 | | 34538.62 |
767.49 | | | | | | | | | |
6F4 | | | | | * 2871.52 (10) | 2911.92 (10) | 2960.24 (2) |
| | | | | 34814.57 | | 34331.58 | | 33771.23 |
617.76 | | | | | | | | | |
6F3 | | | 2891.00 (4) | 2923.40 (12) | 2965.28 (3) | |
| | | 34579.94 | | 34196.80 | | 33713.84 | | |
466.10 | | | | | | | | | |
6F2 | 2909.12 (8) | 2930.50 (4) | 2963.80 (4) | | | |
| 34364.61 | | 34113.85 | | 33730.69 | | | | |
294.90 | | | | | | | | | |
6F1 | 2934.30 (5) | 2956.96 (3) | | | | | |
| 34069.69 | 33818.97 | | | | | | |
|
| 4D1 | 287.15 | 4D2 | 453.04 | 4D3 | 701.94 | 4D4 | | |
|
4P3 | | | ……. ? | 4184.39 (2) | 4311.06 (5) | |
| | | 24344.7 | | 23891.67 | | 23189.64 | | |
981.48 | | | | | | | | | |
4P2 | 4227.07 (2) | 4279.04 (10) | 4363.65 (10) | | | |
| 23650.39 | | 23363.17 | | 22910.19 | | | | |
814.06 | | | | | | | | | |
4P1 | 4377.77 (10) | 4433.51 (8) | | | | | |
| 22836.26 | | 22549.18 | | | | | | |
|
4D4′ | | | | | 3835.35 (2) | 3941.54 (10) | | |
| | | | | 26065.87 | | 25363.64 | | |
600.80 | | | | | | | | | |
4D3′ | | | 3857.15 (3) | 3925.84 (3) | ……. ? | | |
| | | 25918.56 | | 25465.07 | | 24763.0 | | |
385.78 | | | | | | | | | |
4D2′ | 3871.87 (2) | 3915.45 (3r) | 3986.21 (6) | | | |
| 25820.02 | | 25532.65 | | 25079.42 | | | | |
242.58 | | | | | | | | | |
4D1′ | 3908.61 (3) | 3953.00 (3) | | | | | |
| 25577.35 | | 25290.15 | | | | | | |
|
4F5 | | | | | | | 3652.40 (9) | | |
| | | | | | | 27371.46 | | |
968.33 | | | | | | | | | |
4F4 | | | | | 3688.31 (15) | 3786.36 (6) | | |
| | | | | 27105.05 | | 26403.13 | | |
484.93 | | | | | | | | | |
4F3 | | | 3692.64 (10) | 3755.50 (5) | 3857.20 (3) | | |
| | | 27073.19 | | 26620.10 | | 25918.22 | | |
359.15 | | | | | | | | | |
4F2 | 3702.49 (8) | 3742.29 (6) | ……. ? | | | |
| 27001.20 | | 26714.04 | | 26261.0 | | | | |
Table 11
Multiplets in the Ru i Spectrum
| 5F5 | 1190.8 | 5F4 | 900.9 | 5F3 | 621.7 | 5F2 | 392.2 | 5F1 |
---|
5G6 | * 3498.95(50R) | | | | | | | |
| 28571.82 | | | | | | | | |
1707.9 | | | | | | | | | |
5G5 | 3301.59 (8) | * 3436.75(30R) | | | | | |
| 30279.75 | | 29089.02 | | | | | | |
−388.8 | | | | | | | | | |
5G4 | 3344.53 (3) | 3483.32 (4) | 3596.17 (20) | | | |
| 29891.04 | | 28700.06 | | 27799.45 | | | | |
646.2 | | | | | | | | | |
5G3 | | | 3406.59 (2) | 3514.50 (3) | 3593.03 (20) | |
| | | 29346.46 | | 28445.41 | | 27823.74 | | |
421.8 | | | | | | | | | |
5G2 | | | | | 3463.14 (3) | 3539.37 (4) | 3589.23 (5) |
| | | | | 28867.24 | | 28245.54 | | 27853.25 |
|
5F5′ | 3728.03 (10R) | 3901.24 (4) | | | | | |
| 26816.25 | | 25625.62 | | | | | | |
1198.7 | | | | | | | | | |
5F4′ | 3568.47 (1) | 3726.93 (10R) | 3856.39 (3) | | | |
| 28015.21 | | 26824.10 | | 25923.66 | | | | |
875.5 | | | | | | | | | |
5F3′ | | | 3609.10 (2) | 3730.44 (4) | 3819.04 (4) | |
| | | 27699.90 | | 26798.87 | | 26177.21 | | |
536.9 | | | | | | | | | |
5F2′ | | | | | 3657.17 (2) | 3742.29 (10) | 3798.06 (3) |
| | | | | 27335.79 | | 26714.04 | | 26321.78 |
266.2 | | | | | | | | | |
5F1′ | | | | | | | 3705.36 (2) | 3760.03 (4) |
| | | | | | | 26980.27 | | 26587.98 |
|
5D4 | 3799.34 (8) | 3979.44 (5) | 4127.46 (3) | | | |
| 26312.91 | | 25122.06 | | 24221.19 | | | | |
1194.0 | | | | | | | | | |
5D3 | | | 3798.90 (8) | 3933.55 (4) | 4032.21 (3) | |
| | | 26316.00 | | 25415.16 | | 24793.30 | | |
969.2 | | | | | | | | | |
5D2 | | | | | 3790.50 (10) | 3882.00 (3) | 3942.06 (3) |
| | | | | 26374.26 | | 25752.62 | | 25360.28 |
652.9 | | | | | | | | | |
5D1 | | | | | | | 3786.05 (10) | 3843.07 (3) |
| | | | | | | 26405.30 | | 26013.40 |
451.1 | | | | | | | | | |
5D0 | | | | | | | | | 3777.58 (3) |
| | | | | | | | | 26464.50 |
| | | | | | | | | |
Table 12
Multiplets in the Rh i Spectrum
| 4F5 | 1529.9 | 4F4 | 1068.2 | 4F3 | 874.7 | 4F2 |
---|
4G6 | * 3434.90(200R) | | | | | |
| 29104.62 | | | | | | |
2509.1 | | | | | | | |
4G5 | 3162.27 (1) | 3323.10 (50R) | | | |
| 31613.73 | | 30083.76 | | | | |
1430.5 | | | | | | | |
4G4 | 3025.41 (1) | 3172.26 (4) | 3283.57 (20R) | |
| 33043.78 | | 31514.18 | | 30445.92 | | |
−800.7 | | | | | | | |
4G3 | | | 3254.96 (2) | 3372.26 (8) | 3474.80 (20) |
| | | 30713.52 | | 29645.22 | | 28770.43 |
|
4F5′ | 3396.81 (100R) | 3583.09 (10) | | | |
| 29430.97 | | 27900.94 | | | | |
435.4 | | | | | | | |
4F4′ | 3347.30 (1) | 3528.03 (30) | 3666.24 (15) | |
| 29866.27 | | 28336.36 | | 27268.16 | | |
1608.2 | | | | | | | |
4F3′ | | | 3338.55 (8) | 3462.04 (30) | 3570.18 (10) |
| | | 29944.54 | | 28876.46 | | 28001.83 |
802.9 | | | | | | | |
4F2′ | | | | | 3368.38 (5) | 3470.67 (20) |
| | | | | 29679.37 | | 28804.66 |
|
4D4 | 3692.36 (50) | 3913.49 (4) | 4084.30 (2) | |
| 27075.27 | | 25545.43 | | 24477.11 | | |
1784.3 | | | | | | | |
4D3 | | | 3658.00 (50) | 3806.76 (10) | 3937.90 (1) |
| | | 27329.59 | | 26261.63 | | 25387.08 |
1537.6 | | | | | | | |
4D2 | | | | | 3596.17 (20) | 3713.03 (10) |
| | | | | 27799.46 | | 26924.55 |
749.5 | | | | | | | |
4D1 | | | | | | | 3612.47 (15) |
| | | | | | | 27674.03 |
Table 13
Interval ratios of spectral terms
Spectrum | Term | Observed ratios | Theoretical ratios |
---|
|
---|
Yi | 4D′ | 7.0 : 2.5 : 1.4 | 7 : 5 : 3 |
4F | 9.0 : 7.4 : 5.5 | 9 : 7 : 5 |
4F′ | 9.00 : 7.06 : 5.00 | 9 : 7 : 5 |
4G′ | 11.00 : 9.05 : 7.10 | 11 : 9 : 7 |
|
Yii | 3D | 3.0 : 1.5 | 3 : 2 |
3F′ | 4.00 : 3.15 | 4 : 3 |
a3P | 2.0 : 0 8 | 2 : 1 |
3F | 4.0 : 1.4 | 4 : 3 |
3D′ | 3.0 : 0.8 | 3 : 2 |
b3P | 2.00 : 0.95 | 2 : 1 |
|
Zri | 3F | 4.0 : 3.4 | 4 : 3 |
3F′ | 4.0 : 3.1 | 4 : 3 |
3D | 3.0 : 2.18 | 3 : 2 |
3G | 5.0 : 6.86 | 5 : 4 |
5F | 5.0 : 3.36 : 2.52 : 1.70 | 5 : 4 : 3 : 2 |
5F′ | 5.0 : 3.69 : 2.70 : 1.80 | 5 : 4 : 3 : 2 |
5D | 4.0 : 3.23 : 2.30 : 1.07 | 4 : 3 : 2 : 1 |
5G | 6.0 : 5.65 : 4.95 : 4.56 | 6 : 5 : 4 : 3 |
|
Zrii | 4F | 9.0 : 7.22 : 5.06 | 9 : 7 : 5 |
4F′ | 9.0 : 10.18 : 11.29 | 9 : 7 : 5 |
4D | 7.0 : 8.80 : 6.77 | 7 : 5 : 3 |
4G | 11.0 : 10.71 : 10.64 | 11 : 9 : 7 |
|
Cbii | 5D | 0.5 : 3.0 : 2.3 : 1.3 | 4 : 3 : 2 : 1 |
5F′ | 5.0 :1.5 : 4.2 : 2.3 | 5 : 4 : 3 : 2 |
5F | 5.0 : 4.2 : 3.3 : 2.3 | 5 : 4 : 3 : 2 |
5G | 6.0 : 5.2 : 4.4 : 3. | 6 : 5 : 4 : 3 |
|
Moi | 5D | 4.0 : 3.31 : 2.55 : 1.45 | 4 : 3 : 2 : 1 |
5F | 5.0 : 2.82 : 3.17 : 0.33 | 5 : 4 : 3 : 2 |
5G | 6.0 : 5.04 : 7.52 : 7.10 | 6 : 5 : 4 : 3 |
5P′ | 3.0 : 2.90 | 3 : 2 |
|
Moii | 4D | 7.0 : 4.52 : 2.86 | 7 : 5 : 3 |
4D′ | 7.0 : 4.50 : 2.83 | 7 : 5 : 3 |
4P | 5.0 : 4.15 : | 5 : 3 |
4F | 9.0 : 4.50 : 3.34 | 9 : 7 : 5 |
6D | 9.0 : 7.75 : 6.12 : 4.03 | 9 : 7 : 5 : 3 |
6D′ | 9.0 : 6.90 : −4.44 : 5.40 | 9 : 7 : 5 : 3 |
6F | 11.0 : 8.80 : 7.08 : 5.34 : 3.38 | 11 : 9 : 7 : 5 : 3 |
|
Rui | 5F | 5.0 : 3.8 : 2.6 : 1.8 | 5 : 4 : 3 : 2 |
5F′ | 5.0 : 3.8 : 2.3 : 1.2 | 5 : 4 : 3 : 2 |
5D | 4.0 : 3.2 : 2.2 : 1.5 | 4 : 3 : 2 : 1 |
5G | 10.6 :−2.4 : 4.0 : 2.6 | 6 : 5 : 4 : 3 |
Table 14
Systems of spectral structures for thirteen elements of the fourth period
(a) Arc Spectra, Neutral Atoms |
---|
|
---|
Column | I | II | III | IV | V | VI | VII | VIII | | | I | II | III |
---|
|
---|
Element | K-19 | Ca-20 | Sc-21 | Ti-22 | V-23 | Cr-24 | Mn-25 | Fe-26 | Co-27 | Ni-28 | Cu-29 | Zn-30 | Ga-3 |
Systems and | | 11 | | 1 | | | | | | 1 | | 11 | |
low term | 21 | | 23 | | 2 | | | | 2 | | 21 | | 22 |
quantum numbers | | 3 | | 34 | | 3 | | 3 | | 34 | | 3 | |
rl | | | 4 | | 44 | | 4 | | 44 | | (4) | | |
| | | | 5 | | 5 | | 53 | | 5 | | | |
| | | | | 6 | | 61 | | 6 | | | | |
| | | | | | 71 | | 7 | | | | | |
| | | | | | | 8 | | | | | | |
|
(b) Spark Spectra, ionized Atoms |
|
Column | I | II | III | IV | V | VI | VII | VIII | | | I | II | III |
|
Element | K-19 | Ca-20 | Sc-21 | Ti-22 | V-23 | Cr-24 | Mn-25 | Fe-26 | Co-27 | Ni-28 | Cu-29 | Zn-30 | Ga-31 |
Systems and | ? | | 1 | | 1? | | | | (1) | | (11)(_) | | ? |
low term | | 21 | | 2 | | 2 | | 2? | | (2) | | 21 | |
quantum numbers | | | 33 | | 3 | | 3? | | (3) | | (3) | | |
rl | | | | 44 | | 4 | | 4 | | (4) (4) | | | |
| | | | | 54 | | 5 | | (5) (4) | | | | |
| | | | | | 61 | | 63 | | | | | |
| | | | | | | 71 | | | | | | |
Table 15
Systems of spectral structures for thirteen elements of the fifth period
(a) Arc Spectra, Neutral Atoms |
---|
|
---|
Column | I | II | III | IV | V | VI | VII | VIII | | | I | II | III |
---|
|
---|
Element | Rb-37 | Sr-38 | Y-39 | Zr-40 | Cb-4 1 | Mo-42 | ?-43 | Ru-44 | Rh-45 | Pd-46 | Ag-47 | Cd-48 | In-49 |
Systems and | | 11 | | 1? | | | | | | 11 | | 11 | |
low term | 21 | | 23 | | 2? | | | | 2 | | 21 | | 22 |
quantum numbers | | 3 | | 34 | | 3? | | 3 | | 3 | | 3 | |
rl | | | 4 | | 4 | | (4) | | 44 | | (4) | | |
| | | | 5 | | 5 | | 54 | | (5) | | | |
| | | | | 63 | | (6) (3) | | (6) | | | | |
| | | | | | 71 | | (7) | | | | | |
| | | | | | | (8) | | | | | | |
|
(b) Spark Specta, Ionized Atoms |
|
Column | I | II | III | IV | V | VI | VII | VIII | | | I | II | III |
|
Element | Rb-37 | Sr-38 | Y-39 | Zr-40 | Cb-41 | Mo-42 | ?-43 | Ru-44 | Rh-45 | Pd-46 | Ag-47 | Cd-48 | In-49 |
Systems and | ? | | 1 | | (1) | | | | (1) | | (1)(1) | | ? |
low term | | 21 | | 2 | | (2) | | (2) | | (2)(3) | | 21 | |
quantum numbers | | | 33 | | (3) | | (3) | | (3) | | (3) | | |
rl | | | | 44 | | 4 | | (4) | | (4) | | | |
| | | | | 53 | | (5) | | (5)(4) | | | | |
| | | | | | 6(1) | | (6)(3) | | | | | |
| | | | | | | (7)(1) | | | | | | |