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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 20,
  • Issue 2,
  • pp. 90-100
  • (1966)

Infrared Spectra of Phenoxarsine Derivatives

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Abstract

Certain well-known infrared frequencies were studied in new derivatives of 10-substituted phenoxarsine, and the effect of arsenic on <i>v</i><sub>C=O,</sub> <i>v</i><sub>SO2(sym),</sub> <i>v</i><sub>P=O,</sub> and <i>v</i><sub>P=S</sub> are explained in terms of simple electronic theory. No explanation is given for <i>v</i><sub>C=S</sub> in the xanthate derivatives.

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