Laser-produced x-ray spectra of the fluorine isoelectronic sequence for Zn, Ge, and Se †

P. G. Burkhalter; Robert D. Cowan; G. A. Doschek; U. Feldman

doi:10.1364/JOSA.67.000741

Journal of the Optical Society of America
Vol. 67,
Issue 6,
pp. 741-747
(1977)
•https://doi.org/10.1364/JOSA.67.000741

Laser-produced x-ray spectra of the fluorine isoelectronic sequence for Zn, Ge, and Se

P. G. Burkhalter, G. A. Doschek, U. Feldman, and Robert D. Cowan

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P. G. Burkhalter, Robert D. Cowan, G. A. Doschek, and U. Feldman, "Laser-produced x-ray spectra of the fluorine isoelectronic sequence for Zn, Ge, and Se †," J. Opt. Soc. Am. 67, 741-747 (1977)

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Abstract

The transitions 2p⁵-2p⁴3s and 2p⁵-2p⁴3d in fluorine-like Zn, Ge, and Se have been measured in laser-produced x-ray spectra. The experimental spectral data agree well with ab initio atomic structure calculations based on Hartree-Fock wave functions. Classifications of the F i-like lines in these spectra are based on isoelectronic extrapolations and theoretical calculations.

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LS classification		Zn xxii		Ge xxiv		Se xxvi
LS classification		λ(Å)	σ(cm⁻¹)	λ(Å)	σ(cm⁻¹)	λ(Å)	σ(cm⁻¹)
2p^{5 2}P_3/2–2p⁴(¹D)3s²D_5/2		10. 862	9 206 000	9. 252	10 808 000	7. 974b^b	12 541 000
²P_3/2–	²D_5/2	11. 093	9 015 000	9. 478	10 551 000	8. 203	12 191 000
2p^{5 2}P_3/2–2p⁴(³P)3s²P_1/2		10. 942sh^b	9 139 000	9. 314	10 736 000	8. 019	12 470 000
²P_3/2–	²P_3/2	10. 972	9 114 000	9. 336	10 711 000	8. 045	12 430 000
²P_3/2–	⁴P_3/2	11. 163	8 958 000	9. 530	10 493 000	8. 238	12 139 000
²P_3/2–	⁴P_5/2	11. 200	8 929 000	9. 561	10 459 000	8. 260	12 106 000
2p^{5 2}P_3/2–2p⁴(³P)3d²D_5/2		10.108	9 893 000	8. 637	11 578 000	7. 475	13 378 000
²P_3/2–	⁴P_5/2^a	10. 201	9 803 000	8. 734b	11 449 000	7. 571	13 208 000
²P_3/2–	⁴P_3/2	10. 264sh^b	9 746 000	8. 791	11 375 000	7. 639	13 091 000
²P_3/2–	⁴P_1/2	10. 285	9 723 000	8. 809	11 352 000	7. 666	13 045 000
²P_3/2–	⁴F_5/2	10. 250	9 756 000	8. 777	11 393 000	7. 618	13 127 000
2p^{5 2}P_3/2–2p⁴(¹D)3d²D_3/2		9. 963	10 037 000	8. 524	11 732 000
²P_3/2–	²D_5/2	10. 007	9 993 000	8. 555	11 689 000	7. 412	13 492 000
²P_3/2–	²P_3/2	10. 023	9 977 000	8. 575sh	11 662 000

Expt. wavelength (Å)	Expt. int.	Calc. λ (Å)	gf	J^a	J′^a	E′^a (cm⁻¹)	Transition and composition of upper levelb,c
Expt. wavelength (Å)	Expt. int.	Calc. λ (Å)	gf	J^a	J′^a	E′^a (cm⁻¹)	(j–j coupling)	(LS coupling)
						2p⁵–2p⁴3s
11. 200	20	11. 185	0. 026	3/2	5/2	8 874 000	0. 85(³P₂, 1/2) 0. 15(¹D₂, 1/2)	0. 85(³P)⁴P_5/2 0. 15(¹D)²D_1/2
11. 186		11. 173	0. 075	1/2	1/2	9 082 000	0. 96(³P₁, 1/2)	0. 77(³P)²P_1/2 0. 21(³P)⁴P_1/2
11. 163	35	11. 150	0. 22	3/2	3/2	8 902 000	0. 81(³P₂, 1/2) 0. 18(¹D₂, 1/2)	0. 61(³P)²P_3/2 0. 20(³P)⁴P_3/2
11. 093	25	11. 088	0. 15	1/2	3/2	9 151 000	0. 80(³D₂, 1/2) 0. 19(¹D₂, 1/2)	0. 80(¹D)²D_3/2 0. 18(³P)²P_3/2
11. 051	13	11. 040	0. 035	3/2	1/2	8 992 000	0. 64(³P₀, 1/2) 0. 032(¹S₀, 1/2)	0. 58(³P)⁴P_1/2 0. 32(¹S)²S_1/2
10. 972b^d	20	10. 959	0. 067	3/2	3/2	9 059 000	0. 99(³P₁, 1/2)	0. 79(³P)⁴P_3/2 0. 20(³P)²P_3/2
10. 942sh^d	14	10. 931	0. 057	3/2	1/2	9 082 000	0. 96(³P₁, 1/2)	0. 77(³P)²P_1/2 0. 21(³P)⁴P_1/2
10. 862	55	10. 857	0. 17	3/2	5/2	9 144 000	0. 85(¹P₂, 1/2) 0. 15(³P₂, 1/2)	0. 85(¹D)²D_5/2 0. 15(³P)⁴P_5/2
10. 790	45	10. 787	0. 063	1/2	1/2	9 403 000	0. 66(¹S₀, 1/2) 0. 34(³P₀, 1/2)	0. 66(¹S)²S_1/2 0. 21(³P)⁴P_1/2
						2p⁵–2p⁴3d
10. 472sh^d	30	10. 463	0. 030	1/2	3/2	9 689 000	0. 64(³P₂,5/2) 0. 17(¹D₂, 5/2)	0. 40(³P)⁴P_3/2 0. 29(³P)²D_3/2
10. 353	40	10. 337	0. 041	1/2	3/2	9 807 000	0. 64(³P₁,3/2) 0. 23(³P₁, 5/2)	0. 37(³P)⁴D_3/2 0. 18(³P)⁴P_3/2
		10. 295	0. 16	1/2	3/2	9 846 000	0. 53(³P₁,5/2) 0. 20(¹D₂, 5/2)	0. 43(³P)²P_3/2 0. 17(¹D)²P_3/2
10. 285	45	10. 275	0. 27	3/2	1/2	9 666 000	0. 54(³P₂,5/2) 0. 24(³P₂, 3/2)	0. 50(³P)⁴P_1/2 0. 28(³P)²P_1/2
10. 261sh^d	60	10. 250	0. 69	3/2	3/2	9 689 000	0. 64(³P₂,5/2) 0. 17(¹D₂, 5/2)	0. 40(³P)⁴P_3/2 0. 29(³P)²D_3/2
10. 250	65	10. 235	1. 33	3/2	5/2	9 704 000	0. 70(³P₂, 5/2) 0. 09(³P₂, 3/2)	0. 27(³P)²D_5/2 0. 26(³P)²P_5/2
		10. 228	0. 12	1/2	1/2	9 909 000	0. 60(¹D₂, 3/2) 0. 24(¹D₂, 5/2)	0. 76(¹D)²S_1/2 0. 15(³P)⁴P_1/2
		10. 203	0. 38	1/2	3/2	9 934 000	0. 37(¹D₂, 5/2) 0. 30(¹D₂, 3/2)	0. 65(¹D)²P_3/2 0. 14(³P)²P_3/2
10. 201	60	10. 194	0. 25	3/2	3/2	9 744 000	0. 55(³P₀, 3/2) 0. 11(³P₂, 5/2)	0. 54(³P)⁴F_3/2 0. 26(¹S)²D_3/2
		10. 182	0. 32	3/2	5/2	9 755 000	0. 55(³P₀, 5/2) 0. (¹S₀, 5/2)	0. 44(³P)⁴F_5/2 0. 26(¹S)²D_5/2
10. 162b^d	30	10. 155	1. 77	1/2	3/2	9 979 000	0. 39(¹D₂, 3/2) 0. 24(¹D₂, 5/2)	0. 62(¹D)²D_3/2 0. 27(³P)²D_3/2
10. 152	65	10. 142	1. 38	1/2	1/2	9 992 000	0. 47(¹D₂, 5/2) 0. 26(³P₂, 5/2)	0. 58(¹D)²P_1/2 0. 34(³P)²P_1/2
		10. 129	0. 074	3/2	3/2	9 807 000	0. 64(³P₁, 3/2) 0. 23(³P₁, 5/2)	0. 37(³P)⁴D_3/2 0. 18(³P)⁴P_3/2
10. 119sh^d	60	10. 104	0. 14	3/2	5/2	9 831 000	0. 88(³P₁, 5/2) 0. 07(³P₁, 3/2	0. 42(³P)⁴P_5/2 0. 25(³P)²F_5/2
10. 108	65	10. 088	1. 20	3/2	5/2	9 846 000	0. 58(³P₁, 3/2) 0. 16(¹D₂, 3/2)	0. 35(³P)²F_5/2 0. 32(³P)²D_5/2
		10. 025	0. 12	3/2	5/2	9 908 000	0. 81(¹D₂, 5/2) 0. 10(³P₂, 5/2)	0. 48(¹D)²D_5/2 0. 39(¹D)²F_5/2
		10. 024	0. 81	3/2	1/2	9 909 000	0. 60(¹D₂,3/2) 0. 24(¹D₂, 5/2)	0. 76(¹D)²S_1/2 0. 15(³P)⁴P_1/2
10. 023sh^d	70	10. 000	2. 02	3/2	3/2	9 934 000	0. 37(¹D₂, 5/2) 0. 30(¹D₂, 3/2)	0. 65(¹D)²P_3/2 0. 14(³P)²P_3/2
10. 007	80	9. 992	3. 40	3/2	5/2	9 942 000	0. 59(¹D₂, 3/2) 0. 16(³P₂, 3/2)	0. 33(¹D)²D_5/2 0. 32(¹D)²F_5/2
		9. 955	0. 54	3/2	3/2	9 979 000	0. 39(¹D₂, 3/2) 0. 24(¹D₂, 5/2)	0. 62(¹D)²D_3/2 0. 27(³P)²D_3/2
9. 963	70	9. 946	1. 85	1/2	3/2	10 186 000	0. 36(³P₀, 3/2) 0. 03(³P₁, 5/2)	0. 60(¹S)²D_3/2 0. 16(³P)²D_3/2
		9. 942	0. 25	3/2	1/2	9 992 000	0. 47(¹D₂,5/2) 0. 26(³P₂, 5/2)	0. 58(¹D)²P_1/2 0. 34(³P)²P_1/2
9. 795	70	9. 778	0. 089	3/2	5/2	10 161 000	0. 67(¹S₀,5/2) 0. 32(³P₀, 5/2)	0. 67(¹S)²D_5/2 0. 10(³P)²F_5/2

Expt. wavelength (Å)	Expt. int.		gf	J	J′	E′ (cm⁻¹)	Composition of upper level (j-j coupling)
				2p⁵-2p⁴3s
9. 561	8	9. 549	0. 029	3/2	5/2	10 383 000	0. 82(³P₂, 1/2)
		9. 542	0. 072	1/2	1/2	10 657 000	0. 98(³P₁, 1/2)
9. 530	12	9. 522	0. 221	3/2	3/2	10 414000	0. 79(³P₂, 1/2)
9. 478	8	9. 475	0. 147	1/2	3/2	10 732 000	0. 78(¹D₂, 1/2)
9. 434	5	9. 427	0. 042	3/2	1/2	10 519 000	0. 60(³P₀, 1/2)
9. 336	11	9. 327	0. 061	3/2	3/2	10 633 000	0. 98(³P₁, 1/2)
9. 314	12	9. 306	0. 051	3/2	1/2	10 657 000	0. 98(³P₁, 1/2)
9. 252	30	9. 249	0. 162	3/2	5/2	10 723 000	0. 82(¹D₂, 1/2)
		9. 199	0. 065	1/2	1/2	11 048 000	0. 60(¹S₀,1/2)
				2p⁵–2p⁴3d
8. 833	20	8. 826	0. 172	1/2	3/2	11 507 000	0. 56(³P, 5/2) 0. 20(¹D₂, 5/2)
8. 809	20	8. 809	0. 311	3/2	1/2	11 263 000	0. 55(³P₂,5/2) 0. 22(³P₂,3/2)
8. 791	25	8. 788	0. 756	3/2	3/2	11 290 000	0. 62(³P₂,5/2)
8. 777	30	8. 774	1. 49	3/2	5/2	11 309 000	0. 69(³P₂,5/2)
		8. 757	0. 354	1/2	3/2	11 596 000	0. 34(¹D₂, 5/2) 0. 32(¹D₂, 3/2)
8. 734b^a	25	8. 739	0. 363	3/2	3/2	11 354 000	0. 50(³P₀, 3/2) 0. 13(³P₂,5/2)
		8. 725	0. 622	3/2	5/2	11 372 000.	0. 53(³P₀, 5/2) 0. 33(¹S₀, 5/2)
8. 713	25	8. 715	1. 85	1/2	3/2	11 651 000	0. 36(¹D₂, 3/2) 0. 26(¹D₂, 5/2)
8. 702	20	8. 703	1. 42	1/2	1/2	11 667 000	0. 48(¹D₂, 5/2) 0. 26(³P₂, 5/2)
8. 637	35	8. 636	0. 280	3/2	5/2	11 491 000	0. 75(³P₁, 5/2)
8. 637	35	8. 628	0. 951	3/2	5/2	11 502 000	0. 55(³P₂, 3/2)
		8. 576	0. 810	3/2	1/2	11 572 000	0. 60(¹d₂, 3/2)
8. 575sh^a		8. 558	1. 92	3/2	3/2	11 596 000	0. 34(¹D₂, 5/2) 0. 32(¹D₂, 3/2)
8. 555	40	8. 551	3. 19	3/2	5/2	11 605 000	0. 60(¹D₂,3/2)
8. 524	30	8. 518	1. 86	1/2	3/2	11 919 000	0. 41(³P₀, 3/2) 0. 02(³P₁, 5/2)
8. 524	30	8. 518	0. 522	3/2	3/2	11 651 000	0. 36(¹d₂, 3/2) 0. 26(¹D₂,5/2)
		8. 507	0. 228	3/2	1/2	11 667 000	0. 48(¹D₂, 5/2) 0. 26(³P₂, 5/2)

Expt. waveLength (Å)	Expt. int.		gf	J	J′	E′(cm⁻¹)	Composition of upper level (j-j coupling)
				2p⁵–2p⁴3s
8. 260	3	8. 250	0. 033	3/2	5/2	12 005 000	0. 80(³P₂, 1/2)
		8. 244	0. 070	1/2	1/2	12 362 000	0. 99(³P₁, 1/2)
8. 238	3	8. 228	0. 219	3/2	3/2	12 037 000	0. 77(³P₂, 1/2)
8. 203	3	8. 191	0. 146	1/2	3/2	12 441 000	0. 76(³D₂, 1/2)
		8. 148	0. 046	3/2	1/2	12 157 000	0. 55(³P₀, 1/2) 0. 44(¹S₀, 1/2)
8. 045	2	8. 030	0. 057	3/2	3/2	12 336 000	0. 98(³P₁, 1/2)
8. 019	6	8. 014	0. 047	3/2	1/2	12 362 000	0. 99(³P₁, 1/2)
7. 974	2	7. 969	0. 159	3/2	5/2	12 432 000	0. 80(¹D₂, 1/2)
		7. 963	0. 018	3/2	3/2	12 441 000	0. 76(¹D₂, 1/2)
		7. 932	0. 067	1/2	1/2	12 839 000	0. 55(¹S₀, 1/2) 0. 45(³P₀, 1/2)
				2p⁵–2p⁴3d
		7. 651	0. 180	1/2	3/2	13 303 000	0. 58(³P₁, 5/2) 0. 20(¹D₂, 5/2)
		7. 637	0. 344	3/2	1/2	12 978 000	0. 56(³P₂, 5/2)
7. 639	5	7. 619	0. 806	3/2	3/2	13 009 000	0. 59(³P₂, 5/2)
7. 618	8	7. 606	1. 62	3/2	5/2	13 031 000	0. 68(³P₂, 5/2)
		7. 599	0. 322	1/2	3/2	13 393 000	0. 34(¹D₂, 3/2) 0. 30(¹D₂, 5/2)
		7. 577	0. 472	3/2	3/2	13 081 000	0. 45(³P₀,3/2) 0. 15(³P₂, 5/2)
7. 571	7	7. 563	0. 916	3/2	5/2	13 106 000	0. 50(³P₀, 5/2) 0. 39(¹S₀, 5/2)
7. 571	7	7. 561	1. 96	1/2	3/2	13 458 000	0. 33(¹D₂,3/2) 0. 27(¹D₂, 5/2)
		7. 551	1. 45	1/2	1/2	13 477 000	0. 50(¹D₂,5/2) 0. 27(³P₂, 5/2)
7. 475	10	7. 463	0. 588	3/2	5/2	13 283 000	0. 44(³P_l, 5/2) 0. 43(³P₁, 3/2)
7. 475	10	7. 457	0. 528	3/2	5/2	13 294 000	0. 55(³P₁, 5/2) 0. 35(³P₁, 3/2)
7. 427	12	7. 415	0. 810	3/2	1/2	13 369 000	0. 60(¹D_3/2)
7. 412	11	7. 402	1. 85	3/2	3/2	13 393 000	0. 34(¹D₂, 3/2) 0. 30(¹D₂, 5/2)
7. 412	11	7. 397	3. 00	3/2	5/2	13 402 000	0. 62(¹D₂, 3/2)
9. 391	12	7. 372	1. 84	1/2	3/2	13 798 000	0. 45(³P₀, 3/2) 0. 02(³P₁, 5/2)
9. 391	12	7. 367	0. 488	3/2	3/2	13 458 000	0. 32(¹D₂, 3/2) 0. 28(¹D₂, 5/2)
		7. 357	0. 209	3/2	1/2	13 477 000	0. 50(¹D₂, 5/2) 0. 27(³P₂, 5/2)

LS classification		Zn xxii		Ge xxiv		Se xxvi
LS classification		λ(Å)	σ(cm⁻¹)	λ(Å)	σ(cm⁻¹)	λ(Å)	σ(cm⁻¹)
2p^{5 2}P_3/2–2p⁴(¹D)3s²D_5/2		10. 862	9 206 000	9. 252	10 808 000	7. 974b^b	12 541 000
²P_3/2–	²D_5/2	11. 093	9 015 000	9. 478	10 551 000	8. 203	12 191 000
2p^{5 2}P_3/2–2p⁴(³P)3s²P_1/2		10. 942sh^b	9 139 000	9. 314	10 736 000	8. 019	12 470 000
²P_3/2–	²P_3/2	10. 972	9 114 000	9. 336	10 711 000	8. 045	12 430 000
²P_3/2–	⁴P_3/2	11. 163	8 958 000	9. 530	10 493 000	8. 238	12 139 000
²P_3/2–	⁴P_5/2	11. 200	8 929 000	9. 561	10 459 000	8. 260	12 106 000
2p^{5 2}P_3/2–2p⁴(³P)3d²D_5/2		10.108	9 893 000	8. 637	11 578 000	7. 475	13 378 000
²P_3/2–	⁴P_5/2^a	10. 201	9 803 000	8. 734b	11 449 000	7. 571	13 208 000
²P_3/2–	⁴P_3/2	10. 264sh^b	9 746 000	8. 791	11 375 000	7. 639	13 091 000
²P_3/2–	⁴P_1/2	10. 285	9 723 000	8. 809	11 352 000	7. 666	13 045 000
²P_3/2–	⁴F_5/2	10. 250	9 756 000	8. 777	11 393 000	7. 618	13 127 000
2p^{5 2}P_3/2–2p⁴(¹D)3d²D_3/2		9. 963	10 037 000	8. 524	11 732 000
²P_3/2–	²D_5/2	10. 007	9 993 000	8. 555	11 689 000	7. 412	13 492 000
²P_3/2–	²P_3/2	10. 023	9 977 000	8. 575sh	11 662 000

Abstract

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Figures (6)

Tables (4)

Journal of the Optical Society of America