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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 26,
  • Issue 1,
  • pp. 66-73
  • (1972)

Low-Frequency Raman Spectra of Organic Liquids at Large Angular Dispersions of a Three-Prism Spectrograph

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Abstract

A Steinheil three-prism spectrograph, used at large angular dispersions in the low-frequency Raman region (0 to 200 or 250 cm<sup>−1</sup>) has been found to give significantly better spectra, especially in the 0- to 40-cm<sup>−1</sup> region, than the previous method. Starunov's theory of the low-frequency Raman spectra of liquids is found to systematize, qualitatively and for some liquids, the observed results, especially an effect of viscosity on the orientation spectra.

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