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Off-axis cavity ringdown spectroscopy: application to atmospheric nitrate radical detection

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Abstract

Atmospheric nitrate radicals (NO3) are detected using off-axis cavity ringdown spectroscopy (CRDS) for the first time to our knowledge with a room-temperature continuous-wave (cw) diode laser operating near 662 nm. A prototype instrument was constructed that achieved a 1σ absorption sensitivity of 5 × 10−10 cm−1 Hz−1/2, corresponding to a 1.4 part per trillion by volume 2σ detection limit in 4.6 s at 80°C. This sensitivity is a significant improvement over a recent implementation of off-axis cavity-enhanced absorption spectroscopy and comparable to that of the most advanced cw CRDS and pulsed CRDS applications for atmospheric detection of NO3. A comparison of measurements of ambient air in Fairbanks, Alaska, recorded with the off-axis CRDS instrument and a previously characterized conventional cw CRDS instrument showed good agreement (R2 = 0.97).

© 2005 Optical Society of America

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