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Infrared Refractive Index of Atmospheric Aerosol Substances

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Abstract

The optical constants in the ir from λ2.5 μm to 40 μm (4000–250 cm−1) of dry natural aerosol substances and of sea salt are presented. The aerosol substances were obtained from rain and snow water: dust and soot by sedimentation, and water soluble salts by evaporation. The spectra of the absorption index n′ were derived from our published transmittance measurements of potassium bromide disks. The real part n of the refractive index was calculated from the specular reflectance at near normal incidence of disks of pure aerosol substance. The observed spectral features are being related to chemical constituents, notably sulfates and alcohol soluble organics. Optical constants of composite and wet aerosol are discussed. A simple model confirms the measured transmission of a coarse dry powder of water solubles and shows that the extinction by natural aerosol should have a minimum near 8 μm and a strong maximum near 9 μm.

© 1972 Optical Society of America

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