Time-Domain Raman Tracking of Ultrafast Flattening Distortion in Organometallic Complex

S. Takeuchi; M. Iwamura; H. Watanabe; T. Tahara

doi:10.1364/UP.2010.TuE14

International Conference on Ultrafast Phenomena
OSA Technical Digest (CD) (Optica Publishing Group, 2010),
paper TuE14
•https://doi.org/10.1364/UP.2010.TuE14

Time-Domain Raman Tracking of Ultrafast Flattening Distortion in Organometallic Complex

S. Takeuchi, M. Iwamura, H. Watanabe, and T. Tahara

International Conference on Ultrafast Phenomena 2010

Snowmass, Colorado United States
18–23 July 2010
ISBN: 978-1-55752-894-0

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Poster Session II (Continued) (TuE)

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S. Takeuchi, M. Iwamura, H. Watanabe, and T. Tahara, "Time-Domain Raman Tracking of Ultrafast Flattening Distortion in Organometallic Complex," in International Conference on Ultrafast Phenomena, OSA Technical Digest (CD) (Optica Publishing Group, 2010), paper TuE14.

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Abstract

We studied vibrational structures of the metal-to-ligand-charge-transfer state of Cu(I)-diimine complexes through wavepacket motions generated impulsively at various delay-times. The obtained “instantaneous” Raman data provided firm vibrational evidences for ultrafast nature of the flattening distortion.

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