Photo-Oxidation of Tetracyanoplatinate Single Crystals

W.A. Pfab; V. Gerhardt

doi:10.1364/ICOL.1984.FD3

International Conference on Luminescence - 1984
Technical Digest Series (Optica Publishing Group, 1984),
paper FD3
•https://doi.org/10.1364/ICOL.1984.FD3

Photo-Oxidation of Tetracyanoplatinate Single Crystals

W.A. Pfab and V. Gerhardt

International Conference on Luminescence 1984

Madison, Wisconsin United States
13–17 August 1984
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W. A. Pfab and V. Gerhardt, "Photo-Oxidation of Tetracyanoplatinate Single Crystals," in International Conference on Luminescence - 1984, Technical Digest Series (Optica Publishing Group, 1984), paper FD3.

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Abstract

Me_x [Pt(CN)₄]_y nH₂O (Me = Sr, Ca, Ba, Mg, Lu, ...)-type crystals show highly anisotropic properties. The strong binding between the CN-ligands and the Pt²⁺-ion of the [pt(CN)₄]^2--complex-molecule is well preserved in the crystal (1). This is the reason for the demixing of Pt-d³-electrons (Ham-effect) and, additionally, there is formed a nearly one-dimensional dz²-valence-band for the Pt-Pt-binding within the crystal.

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